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A kind of cohesion-enhanced butyl rubber hot-melt pressure-sensitive adhesive and preparation method thereof

A technology of hot-melt pressure-sensitive adhesive and butyl rubber, which is applied in the direction of adhesives, non-polymer adhesive additives, adhesive additives, etc., can solve the problems of poor bonding strength, inability to peel and rebond, etc., and achieve increased Cohesive strength, favorable coating adhesion processing, excellent weather resistance effect

Active Publication Date: 2018-10-12
成都微熵科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the problem of poor bonding strength or irreversible vulcanization in the prior art that cannot be peeled and rebonded

Method used

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  • A kind of cohesion-enhanced butyl rubber hot-melt pressure-sensitive adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A cohesive reinforced butyl rubber hot-melt pressure-sensitive adhesive, the components and parts by weight are: butyl rubber 10%, bromobutyl rubber 9%, polyisobutylene resin with a molecular weight of 40,000 5%, N-vinyl Imidazole 0.8%, hydrogenated C5 petroleum resin 20%, 2000 low molecular weight polyisobutylene oil 10%, kaolin 45%, 1076 antioxidant 0.2%;

[0028] First, the bromobutyl rubber and butyl rubber were separately kneaded on the open mill; then the kneaded bromobutyl rubber and N-vinylimidazole were added to the kneader at 190 °C; after kneading for 5 minutes, the open kneader was added After kneading for 5 minutes, add plasticizer polyisobutylene oil mixed with antioxidant 1076 and hydrogenated C5 petroleum resin; finally add kaolin, mix under vacuum for 2 hours and then discharge.

Embodiment 2

[0030] A cohesive reinforced butyl rubber hot-melt pressure-sensitive adhesive, the components and parts by weight are: butyl rubber 17%, bromobutyl rubber 10%, SIS resin 10%, 2-ethylimidazole 0.5%, Terpene resin 18%, white oil 15%, calcium carbonate 29%, antioxidant 1010, 168 0.25% each;

[0031] First, the bromobutyl rubber and butyl rubber were separately kneaded on the open mill; then the kneaded bromobutyl rubber and 2-ethylimidazole were added to the kneader at 180 °C; after kneading for 10 minutes, the open kneader was added After kneading for 2 minutes, add plasticizer white oil and terpene resin mixed with antioxidants 1010 and 168; finally add calcium carbonate, mix under vacuum for 1 hour and then discharge.

Embodiment 3

[0033] A cohesive reinforced butyl rubber hot-melt pressure-sensitive adhesive, the components and parts by weight are: butyl rubber 19%, bromobutyl rubber 13%, SBS resin 3%, 2-ethylimidazole 0.1%, Hydrogenated C5 petroleum resin 24%, naphthenic oil 20%, calcium carbonate 10.5%, silica 10%, antioxidant 1010, 168 0.2% each;

[0034] First, the bromobutyl rubber and butyl rubber were separately kneaded on the open mill; then the kneaded bromobutyl rubber and 2-ethylimidazole were added to the kneader at 170 °C; after 10 minutes of kneading, the open kneading was added After kneading for 3 minutes, add plasticizer naphthenic oil and hydrogenated C5 petroleum resin mixed with antioxidants 1010 and 168; finally add calcium carbonate and silica, and mix under vacuum for 1 hour Discharge later.

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Abstract

The invention discloses a cohesion-enhanced butyl rubber hot-melt pressure-sensitive adhesive. Its components and parts by weight are: 10-35% of butyl rubber, 3-20% of bromobutyl rubber, and 3-20% of other matrix resins. 18%, imidazole derivatives 0.05-1%, tackifying resin 10-35%, plasticizer 5-35%, reinforcing filler 18-55%, antioxidant 0.1-0.6%. The invention also discloses a preparation method. The butyl rubber hot-melt pressure-sensitive adhesive of the present invention has reversible thermal processability, and has the ability to recoat and bond in a heated state.

Description

technical field [0001] The invention relates to the field of butyl rubber hot-melt pressure-sensitive adhesive, in particular to a cohesive-reinforced butyl rubber hot-melt pressure-sensitive adhesive and a preparation method thereof. Background technique [0002] Pressure-sensitive adhesive is a material that implements interfacial bonding by pressure. According to the main resin composition, it can be divided into two types: rubber type and resin type. In addition to the main component of rubber, rubber pressure-sensitive adhesives should be added with tackifying resin, plasticizer, filler, antioxidant, anti-aging agent and even vulcanizing agent, etc. Auxiliary. Among the rubber pressure-sensitive adhesives, butyl rubber pressure-sensitive adhesives have very good weather resistance and water tightness due to their less unsaturated double bonds and the presence of methyl groups. Therefore, it is mostly used in construction, medical and industrial fields as waterproof, s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J123/22C09J11/04C09J11/06C09J11/08C08F8/30
CPCC08F8/30C08K2003/265C08L2205/02C08L2205/025C08L2205/035C09J11/04C09J11/06C09J11/08C09J123/22C08L15/02C08L23/20C08L57/02C08K3/346C08K5/1345C08L53/02C08L45/00C08L91/00C08K3/26C08K5/526C08K13/02C08K3/36C08K3/34C08K3/04C08F210/12
Inventor 何波兵
Owner 成都微熵科技有限公司
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