Silicon carbide coating and preparation method thereof

A silicon carbide coating and coating technology, applied in the field of silicon carbide coating and its preparation, can solve the problems of high preparation cost, increase of coating cycle, anti-oxidation coating damage, etc., achieve reduction of preparation cycle and simplification of preparation process , the effect of rapid preparation

Active Publication Date: 2017-08-22
AEROSPACE RES INST OF MATERIAL & PROCESSING TECH +1
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AI Technical Summary

Problems solved by technology

[0004] When the silicon carbide coating is prepared by the coating and sintering method, it is necessary to repeat the coating and sintering process many times to achieve the continuity of the coating and reach a certain thickness requirement, and form an effective coating with good quality. The process is complicated and the preparation cycle is long. The corresponding preparation cost is also higher
In addition, due to the complex process, the prepared anti-oxidation coating is easily damaged during the process, which increases the cycle of further improvement of the coating.

Method used

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  • Silicon carbide coating and preparation method thereof
  • Silicon carbide coating and preparation method thereof
  • Silicon carbide coating and preparation method thereof

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preparation example Construction

[0030] The embodiment of the present invention provides a method for preparing a silicon carbide coating, comprising the following steps:

[0031] Step (1): Prepare the first coating slurry and the second coating slurry respectively, wherein the raw material of the first coating slurry includes phenolic aldehyde with a mass ratio of 3:(3-5):(0.5-1.5) Resin, Si powder and SiC powder, the second coating slurry is siliconized slurry;

[0032] Specifically, the silicidation slurry can be the coating slurry used in the traditional coating and sintering silicon carbide coating preparation process; in the embodiment of the present invention, the raw material of the silicidation slurry includes a mass ratio of 3:(2 ~4): (1~3) silicone resin, Si powder and SiC powder. The silicidation slurry formula provided by the embodiment of the present invention can form a coupled coating layer in combination with the first coating slurry formula, and provide an additional silicon source for the ...

Embodiment 1

[0052](1) Take each material according to the mass ratio of phenolic resin: Si powder: SiC powder: ethanol=3:4:0.5:3.5, mix the weighed phenolic resin, Si powder and SiC powder, and use the weighed ethanol Regulate its viscosity to the degree suitable for coating to form the main layer slurry; take each material according to the mass ratio of silicone resin: Si powder: SiC powder: toluene=3:3:1:3, and the silicone resin that has been weighed , Si powder and SiC powder are mixed evenly, and the viscosity is adjusted to a level suitable for coating with toluene weighed to form a siliconized slurry.

[0053] (2) With a density of 1.8g / cm 3 The carbon / carbon composite material is used as the substrate, the main layer slurry is coated on the surface of the substrate, and then cured to form an inner coating layer with a thickness of about 100 μm; the siliconized slurry is coated and cured on the surface of the inner coating layer twice to form An outer cladding with a thickness of ...

Embodiment 2

[0060] (1) Take each material according to the mass ratio of phenolic resin: Si powder: SiC powder: acetone=3:3:1:4, mix the weighed phenolic resin, Si powder and SiC powder, and use the weighed acetone Regulate its viscosity to the degree suitable for coating to obtain the main layer slurry; take each material according to the mass ratio of silicone resin: Si powder: SiC powder: ethanol = 3:2:1:2, and weigh the silicone resin , Si powder and SiC powder are mixed evenly, and the viscosity is adjusted to a level suitable for coating with weighed ethanol to obtain the main slurry.

[0061] (2) With a density of 1.5g / cm 3 The carbon / silicon carbide composite material is used as the substrate, and the main layer slurry is coated and cured on the surface of the substrate twice to form an inner coating layer with a thickness of about 200 μm; the siliconized slurry is coated and cured on the inner coating layer twice On the surface, an outer cladding layer with a thickness of about ...

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Abstract

The invention relates to a silicon carbide coating and a preparation method thereof, and belongs to the technical field of inorganic functional coating materials. The preparation method of silicon carbide comprises the following steps: respectively preparing a first coating sizing agent and a second coating sizing agent, wherein the first coating sizing agent is prepared from phenolic resin, Si powder and SiC powder with a weight ratio of 3:(3 to 5):(0.5 to 1.5), and the second coating sizing agent is a silicified sizing agent; coating the surface of a carbon-containing material with the prepared first coating sizing agent, curing to obtain an inner coating layer, then coating the surface of the inner coating layer with the prepared silicified coating sizing agent, and curing to obtain an outer coating layer; performing high temperature vacuum sintering on the carbon-containing material on which the outer coating layer is formed, thus obtaining the silicon carbide coating. According to the silicon carbide coating provided by the embodiment of the invention, the inner coating layer and the outer coating layer can be formed by high temperature sintering for once, quick formation of the high-quality silicon carbide coating is realized, the preparation process is greatly simplified, and a preparation period is shortened by 50 percent or more; the method adapts to quick preparation of carbon-containing materials with different structures, different sizes and special shape and component coatings thereof.

Description

technical field [0001] The invention relates to a silicon carbide coating and a preparation method thereof, belonging to the field of inorganic functional coating materials. Background technique [0002] Anti-oxidation coating technology is the key to realize the service of carbon-containing materials (including carbon / carbon composite materials, graphite materials, carbon / silicon carbide composite materials, etc.) The coating can effectively block the contact between ambient oxygen and internal carbonaceous materials, thereby exerting the high-temperature performance of carbonaceous materials. [0003] There are many methods for preparing anti-oxidation coatings, including solid phase embedding method, brushing method, plasma spraying method, chemical vapor deposition method, coating and sintering method, etc. Among them, the coating and sintering method was developed in recent years and has different characteristics. The advantages of good substrate process adaptability, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/87C04B41/89
CPCC04B41/009C04B41/5059C04B41/52C04B41/87C04B41/89C04B41/4535C04B41/0072C04B35/83C04B35/52C04B35/565C04B35/522C04B41/5022
Inventor 李同起焦星剑李钰梅张大海
Owner AEROSPACE RES INST OF MATERIAL & PROCESSING TECH
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