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Method for treating desulfurization wastewater in power plant

A desulfurization wastewater and treatment method technology, applied in the field of environmental engineering, can solve the problems of easy scaling of membranes and evaporators, high hardness of desulfurization wastewater, cumbersome operation, etc., to solve scaling problems, reduce scale, and reduce concentrated water volume Effect

Active Publication Date: 2017-08-25
ZHEJIANG DOWAY ADVANCED TECH CO LTD
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Problems solved by technology

[0005] In order to solve this technical problem, the present invention provides a treatment method for power plant desulfurization wastewater, which is used to solve the problems of high hardness of desulfurization wastewater, easy fouling of membrane and evaporator, high cost and cumbersome operation in the prior art

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  • Method for treating desulfurization wastewater in power plant

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Embodiment Construction

[0031] The above and other technical features and advantages of the present invention will be clearly and completely described below in conjunction with the accompanying drawings. Apparently, the described embodiments are only some of the embodiments of the present invention, not all of them.

[0032] The invention provides a method for treating desulfurization wastewater of a power plant, which uses the world's first electric-driven ion combination process to realize the separation and recombination of calcium and sulfate radicals in calcium sulfate. Solve the scaling problem of calcium sulfate on the membrane and evaporator by recombining the scaling calcium sulfate ion, then use the electrodialysis process to concentrate the wastewater to 20%, and then realize the purification of the wastewater by mechanical evaporation crystallization or flue spraying process Ultimately zero emissions. Next, the method for treating desulfurization wastewater of a power plant according to t...

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Abstract

The invention provides a method for treating desulfurization wastewater in a power plant. The method comprises the following steps: pretreating the desulfurization wastewater to obtain primary clarified liquor; enabling the primary clarified liquor to enter a filtering device to be filtered; providing a four-compartment electrodialyzer to perform ion recombination on ions in each water flow channel unit through an electric drive effect; further enabling produced water of each water flow channel unit to pass through a nanofiltration system to perform salt separation treatment, concentrating by utilizing an electrodialysis system, and desalinating the wastewater by utilizing a reverse osmosis system. According to the method disclosed by the invention, salts in the wastewater which are easy to scale are subjected to ion recombination so as to form soluble salts which are difficult to scale, so that the problem of scale formation in subsequent electrodialysis equipment or a high-pressure reverse osmosis system is solved. Moreover, according to the nanofiltration system for concentration, the electrodialysis system or the high-pressure reverse osmosis system, the content of total soluble solids in the wastewater is 8-16%, and the recovery rate of 80-90% of the wastewater is realized.

Description

technical field [0001] The invention relates to the technical field of environmental engineering, in particular to a treatment method for desulfurization wastewater of a power plant. Background technique [0002] The limestone-gypsum wet desulfurization process is currently the mainstream flue gas desulfurization process accounting for up to 85%. During the wet desulfurization process, the absorption tower slurry continuously accumulates heavy metal elements, Cl - And some suspended particles, etc., need to regularly discharge a part of the desulfurization wastewater. Although the amount of this part of desulfurization wastewater is small, it is highly toxic and difficult to discharge in a stable manner through conventional treatment. Therefore, desulfurization wastewater from power plants is the most difficult wastewater to treat. [0003] At present, the common treatment method for desulfurization wastewater in China is to use the triple-box process. Although the effluent...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/10C02F103/18C02F101/20
Inventor 施小东刘泽宇施秦峰汤宣林
Owner ZHEJIANG DOWAY ADVANCED TECH CO LTD
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