Composite sea water desalination method and system based on cold energy of liquefied natural gas

A technology for liquefied natural gas and seawater, which is applied in chemical instruments and methods, seawater treatment, frozen water/sewage treatment, etc., can solve the problems of slow internal melting speed, fast surface melting speed, opening of salt cell structure, etc., and achieve strong industrial promotion Value, time and energy savings, simple steps

Active Publication Date: 2017-09-08
BEIJING UNIV OF CIVIL ENG & ARCHITECTURE
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, gravity desalination depends directly on the melting of ice, and the melting speed of the ice surface in direct contact with the outside world is fast while the melting speed of the interior is slow, which is not conducive to opening the salt cell structure from the inside, and it is also necessary to break the ice that has undergone gravity desalination to form a uniform Ice crystal particles, and in the subsequent centrifugal desalination step, high centrifugal speed can be used to achieve sufficient removal, resulting in complex and time-consuming process
[0005] In the freezing-microwave-centrifugal desalination process adopted in the prior art, the microwave treatment process needs to consume a certain amount of electric energy

Method used

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  • Composite sea water desalination method and system based on cold energy of liquefied natural gas

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Experimental program
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Effect test

Embodiment 1

[0040] see figure 1 , a seawater desalination system based on the cold energy of liquefied natural gas, including a secondary refrigerant cooler 1, a seawater flake ice machine 2, and a filter type centrifugal desalination device 3;

[0041] The secondary refrigerant cooler 1 is a plate cooler, and a natural gas channel and a secondary refrigerant channel are arranged in the cooler. The outlet of the secondary refrigerant channel is connected to the seawater flake ice machine 2, and the secondary refrigerant cooler 1 passes through The secondary refrigerant pipeline is connected to the liquid storage tank 101, and a secondary refrigerant pump 102 and a check valve 103 are arranged on the secondary refrigerant pipeline;

[0042] The top of the seawater flake ice machine 2 is provided with a seawater distribution device 201, and the bottom of the seawater flake ice machine 2 is connected with a conical ice-water separator 6; the seawater flake ice machine 2 is connected to a con...

Embodiment 2

[0047] Adopt the system of embodiment 1, present embodiment provides a kind of specific seawater desalination operation, and corresponding process parameter:

[0048] (1) Take seawater with an original salt concentration of 3%, and its temperature is 0.1°C after being pre-cooled by the concentrated seawater recovery tank and the ice-melting tank; indirect heat exchange between liquefied natural gas and absolute ethanol to obtain gaseous natural gas and make it After the temperature of the water ethanol is lowered to -47°C, the obtained absolute ethanol is fully subjected to indirect heat exchange with the sea water, and a part of the sea water is frozen in the flake ice machine, and the thickness of the obtained ice flakes is about 1-3mm; ice water After separation, recover the remaining seawater and keep it on ice for later use;

[0049] (2) Take 501 g of ice obtained in step (1), send it to a filter type centrifugal desalination device, and add raw sea water with a temperatu...

Embodiment 4

[0061] Apply the system of embodiment 1, carry out seawater desalination according to the following steps:

[0062] (1) Take seawater with an original salt concentration of 3%; indirect heat exchange between liquefied natural gas and absolute ethanol to obtain gaseous natural gas and reduce the temperature of absolute ethanol to -47°C, then mix the absolute ethanol with pre-cooling The seawater at 0.1°C fully performs indirect heat exchange, so that part of the seawater freezes; after the ice water is separated, the remaining seawater is recovered and iced for use;

[0063] (2) Take 499g of ice gained in step (1), send it into a filter-type centrifugal desalination device, and add raw seawater with a temperature of 11°C and a quality of 30% of the ice mass;

[0064] (3) Start the filter type centrifugal desalination device, centrifuge the ice-water mixture obtained in step (2) under the condition of 3000r / min for 2min, carry out centrifugation, and separate the ice and water w...

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Abstract

The invention provides a freezing-water adding-centrifugation composite sea water desalination method and system based on cold energy of liquefied natural gas. The method comprises the following steps: (1) exchanging heat between LNG (Liquefied Natural Gas) and a second refrigerant, and freezing sea water into sheet ice and concentrated sea water through the second refrigerant via a sheet ice maker; (2) conveying the obtained sheet ice into a filtering type centrifugal desalination device, and adding raw sea water; (3) centrifugating an obtained ice-water mixture; (4) melting separated ice. The invention further provides a sea water desalination system based on the cold energy of the LNG. According to the method and the system, the low-cost cold energy of the LNG is used as a cold source for the process; by the adding of the raw sea water, the melting of part of the ice is accelerated, and the brine viscosity on the ice surface is reduced, so that salt cells can be separated under the mechanically centrifugal action; by optimization of parameters of all stages of desalination operations, high desalinization rate and high water yield are realized; furthermore, the engineering cost is reduced, the time and the energy consumption are reduced, and balancing of factors such as an implementation factor is facilitated; the method and the system have extremely high industrial popularization value.

Description

technical field [0001] The invention relates to the interdisciplinary field of oil and gas storage and transportation, engineering thermophysics and water treatment technology, and specifically relates to a freezing-water-adding-centrifugal composite seawater desalination method and device based on the cold energy of liquefied natural gas. Background technique [0002] LNG is liquefied natural gas at normal pressure and low temperature (-162°C). It needs to be gasified before being transported into pipelines and used as fuel or chemical raw materials. When LNG is gasified, it will theoretically release 830kJ / kg of cold energy. Imported LNG receiving stations are generally built near seaports, and the cold energy released by LNG gasification is usually directly discharged into seawater. With the continuous expansion of the receiving station, a large amount of cold energy will affect the ecological environment of nearby sea areas. If this part of cold energy can be used for se...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/08C02F103/08
CPCC02F1/004C02F1/22C02F2103/08Y02A20/124
Inventor 杨晖孙正阳张皓兴占中来
Owner BEIJING UNIV OF CIVIL ENG & ARCHITECTURE
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