High-shading-performance polycarbonate wire suitable for fused deposition and preparation method thereof

A polycarbonate, fused deposition technology, applied in the field of additive manufacturing, can solve the problems of difficult to meet the toughness of the wire, melting temperature, viscosity, mechanical properties, complicated processes, low impact resistance, etc., to shorten the research and development cycle and Production cost, simple operation process, and the effect of improving toughness

Active Publication Date: 2017-09-29
GUANGDONG SILVER AGE SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional preparation of high light-shielding PC material parts uses pellets and is molded by mold. This method has a long forming cycle, cumbersome and complicated process, low impact resistance and high cost.
In addition, at this stage, it is generally used to fill a large amount of titanium dioxide to realize the shading of PC materials, and the addition amount exceeds 18%. However, the i

Method used

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  • High-shading-performance polycarbonate wire suitable for fused deposition and preparation method thereof

Examples

Experimental program
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Effect test

Example Embodiment

[0024] see figure 1 , the preparation method of the high light-shielding polycarbonate filament material suitable for fusion deposition provided by the preferred embodiment of the present invention, the preparation method mainly includes the following steps:

[0025] Step 1, ball milling polycarbonate powder, titanium dioxide, flow aid, toughening agent, lubricant, antioxidant and ultraviolet absorber according to a predetermined mass percentage to obtain a mixed powder. Specifically, the polycarbonate powder, the titanium dioxide, the flow aid, the toughening agent, the lubricant, the antioxidant and the ultraviolet absorber are weighed according to a predetermined mass percentage and pour it into a ball mill jar, and then add a certain amount of balls into the ball mill jar to perform ball milling to obtain a uniformly dispersed mixed powder. In this embodiment, the mass percentage of the polycarbonate powder is 49-78%; the mass percentage of the titanium dioxide is 9-13%; ...

Example Embodiment

[0030] Example 1

[0031] The preparation method of the highly light-shielding polycarbonate filament material suitable for fusion deposition provided by embodiment 1 comprises the following steps:

[0032] (11) Preparation of high light-shielding PC powder: Weigh 780g PC powder, 90g titanium dioxide, 100g PBT flow aid, 20g A-662R toughening agent, 1g stearyl stearate and paraffin mixed lubricant, 5g antioxidant 168 and the ultraviolet absorber of 5g UV-5411 type are prepared into 1000g composite powder altogether, then described composite powder is poured in the ball mill jar, and in described ball mill jar, add 800g ball, on ball mill with Ball mill at a speed of 200r / min for 120min to obtain a uniformly dispersed mixed powder.

[0033] (12) Wire forming: the mixed powder obtained in step (11) is heated to a molten state and then passed through a single-screw extruder with a solid delivery zone temperature of 120°C, a plasticizing zone temperature of 210°C, and a barrel vac...

Example Embodiment

[0034] Example 2

[0035] The preparation method of the highly light-shielding polycarbonate filament material suitable for fusion deposition provided by embodiment 2 comprises the following steps:

[0036] (21) Preparation of high light-shielding PC powder: Weigh 700g PC powder, 120g titanium dioxide, 120g PET flow aid, 40g HHB-E009 toughening agent for toughened polyester, 5g montan wax acid soap ester lubricant, The ultraviolet absorber of 10g antioxidant TPPI and 5gUV-1577 type, to be prepared into 1000g composite powder, then described composite powder is poured in the ball mill jar, and in described ball mill jar, add 700g ball, on the ball mill with rotating speed 150r / min ball milling for 240min to obtain a uniformly dispersed mixed powder.

[0037] (22) Wire forming: the mixed powder obtained in step (21) is heated to a molten state and then passed through a single-screw extruder with a temperature of 130°C in the solid conveying zone, a temperature of 220°C in the p...

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Abstract

The invention belongs to the technical field of additive manufacturing, and discloses a high-shielding-performance polycarbonate wire suitable for fused deposition and a preparation method thereof. The method comprises the following steps: (1) performing ball milling on polycarbonate powder, titanium dioxide, a flow promotor, a toughening agent, a lubricating agent, an antioxidant and an ultraviolet absorbent according to a predetermined mass percentage to obtain mixed powder; (2) heating the mixed powder to a fused state in order to prepare the high-shielding-performance polycarbonate wire. The invention further relates to a high-shielding-performance polycarbonate wire prepared by the preparation method of the high-shielding-performance polycarbonate wire suitable for fused deposition. The preparation method is simple in preparation process, and has higher flexibility; the prepared high-shielding-performance polycarbonate wire has higher toughness and higher impact resistance.

Description

technical field [0001] The invention belongs to the technical field related to additive manufacturing, and more specifically relates to a high light-shielding polycarbonate wire suitable for fusion deposition and a preparation method thereof. Background technique [0002] Fusion Deposition Modeling (FDM) is an additive manufacturing technology. It uses computer-aided design, based on the principle of layer-by-layer superposition, to heat and melt the wire through the nozzle, and then extrude it from the nozzle with a certain pressure to form a three-dimensional solid part. . Compared with the traditional process, FDM technology has the advantages of no need for molds, short preparation cycle, further simplification of the process, high utilization rate of raw materials, and not being restricted by the complex structure of the workpiece, so it has extremely broad application prospects. Polycarbonate (Polycarbonate, PC) is an amorphous thermoplastic resin with excellent compr...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08L33/04C08L67/02C08L67/00C08L55/02C08L91/06C08K13/02C08K3/22B29C64/118B33Y70/00
CPCB33Y70/00C08K2003/2241C08L69/00C08L2203/12C08L2205/025C08L2205/035C08L33/04C08L67/02C08L91/06C08K13/02C08K3/22C08L67/00C08L55/02
Inventor 闫春泽傅华史玉升傅轶汪艳魏青松刘洁
Owner GUANGDONG SILVER AGE SCI & TECH CO LTD
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