Smelting process of low-carbon high-sulfur free cutting steel

A free-cutting steel and high-sulfur technology, which is applied in the smelting process of low-carbon high-sulfur free-cutting steel, can solve problems such as slag rolling, low-flow shutdown, affecting the quality of billets, and corrosion of refractory materials, etc., to reduce warping Defects, ensure the quality of casting slab, and improve the effect of production

Active Publication Date: 2017-10-27
NANJING IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The slagging and deoxidation process in the refining process of free-cutting steel is very important to the stable control of sulfur and oxygen content. Improper control of the oxygen level in high-sulfur steel under the high-temperature removal condition will easily cause refractory materials to corrode, resulting in poor flow control in the continuous casting production process. stable, the liquid level fluctuates frequently, which is likely to cause slag rolling and less flow stoppage, and affect the quality of the slab; low-carbon high-sulfur steel is a crack-sensitive steel type, and improper workmanship may easily cause defects such as internal cracks and surface depressions in the slab, and even appear Production accidents such as steel breakout

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] This embodiment is a smelting process of low-carbon high-sulfur free-cutting steel, comprising the following steps:

[0020] (1) Stir after the converter tapping to reduce the oxidation of molten steel. The converter tapping requires the terminal oxygen to be ≤ 600ppmm. According to the terminal oxygen, add 1.2kg / t aluminum block for deoxidation, add low-carbon ferromanganese 10kg / t, ferrosilicon alloy 0.3kg / t, Pyrite 15kg / t and lime 5kg / t alloyed;

[0021] (2) Use slag pouring first before tapping and use slag-stopping cone to block slag tapping to prevent slag dropping and converter slag from being involved in the ladle;

[0022] (3) Refining slag is Al 2 o 3 -CaO-SiO 2 , the alkalinity is controlled between 1.5-2.5;

[0023] (iv) According to the oxygen level of molten steel, calcium wire 100m is used for precipitation deoxidation during the refining process, bottom stirring is used for stirring at 100l / min, and aluminum wire 10kg, silicon barium calcium 80kg and...

Embodiment 2

[0028] This embodiment is a smelting process of low-carbon high-sulfur free-cutting steel, comprising the following steps:

[0029] (1) Stir after the converter tapping to reduce the oxidation of molten steel. The converter tapping requires the terminal oxygen to be ≤ 600ppmm. According to the terminal oxygen, add 1.6kg / t aluminum block for deoxidation, add low-carbon ferromanganese 12kg / t, ferrosilicon alloy 0.4kg / t, Pyrite 17kg / t and lime 8kg / t alloyed;

[0030] (2) Use slag pouring first before tapping and use slag-stopping cone to block slag tapping to prevent slag dropping and converter slag from being involved in the ladle;

[0031] (3) Refining slag is Al 2 o 3 -CaO-SiO 2 , the alkalinity is controlled between 1.5-2.5;

[0032] (iv) According to the oxygen level of molten steel, during the refining process, 10m of aluminum wire and 150m of calcium wire are used for precipitation deoxidation, the bottom stirring is 150l / min, and 15kg of aluminum wire, 90kg of silicon...

Embodiment 3

[0037] This embodiment is a smelting process of low-carbon high-sulfur free-cutting steel, comprising the following steps:

[0038] (1) Stir after the converter tapping to reduce the oxidation of molten steel. The converter tapping requires the terminal oxygen to be ≤ 600ppmm. According to the terminal oxygen, add 2.0kg / t aluminum block for deoxidation, add low-carbon ferromanganese 15kg / t, ferrosilicon alloy 0.6kg / t, Pyrite 20kg / t and lime 7kg / t alloyed;

[0039] (2) Use slag pouring first before tapping and use slag-stopping cone to block slag tapping to prevent slag dropping and converter slag from being involved in the ladle;

[0040] (3) Refining slag is Al 2 o 3 -CaO-SiO 2 , the alkalinity is controlled between 1.5-2.5;

[0041] (iv) According to the oxygen level of molten steel, during the refining process, 50m of aluminum wire and 200m of calcium wire are used for precipitation deoxidation, the bottom stirring is 200l / min, and 20kg of aluminum wire, 100kg of silico...

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PUM

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Abstract

The invention relates to a smelting process of low-carbon high-sulfur free cutting steel. The smelting process comprises the following steps: (1) stirring after converter tapping, wherein the content of end-point oxygen required for converter tapping is less than or equal to 600 ppmm; (2) de-slagging firstly and then tapping; (3) enabling a refining slag system to be Al2O3-CaO-SiO2 and controlling the alkalinity to be 1.5-2.5; (4) performing precipitation and deoxidization in the refining process by adopting an aluminum line and a calcium line, feeding no aluminum line to deoxidize within 10-15 minutes before ladle hanging; (5) blowing argon for 3-5 minutes after deoxidization alloying and then fixing oxygen and entering a static mixing stage after the oxygen content is 20-50 ppm; (6) adopting covering slag and a low-carbon covering agent in the continuous casting process and ensuring the quality of a casting blank, wherein the degree of superheat is 20-40 DEG C, the quantity of water in a crystallizer is 90-120 m<3>/h, and the specific water flow is 0.6-0.9 L/kg. The smelting process provided by the invention has the benefits that the difficulty of a production process of the low-carbon high-sulfur free cutting steel can be solved, the stable flow control in the pouring process is ensured, the continuous pouring time is 10 h or above, and the yield is improved while the quality of the casting blank is ensured.

Description

technical field [0001] The invention relates to a method for smelting low-carbon high-sulfur steel, in particular to a smelting process for low-carbon high-sulfur free-cutting steel with excellent billet quality. Background technique [0002] The slagging and deoxidation process in the refining process of free-cutting steel is very important to the stable control of sulfur and oxygen content. Improper control of the oxygen level in high-sulfur steel under the high-temperature removal condition will easily cause refractory materials to corrode, resulting in poor flow control in the continuous casting production process. stable, the liquid level fluctuates frequently, which is likely to cause slag rolling and less flow stoppage, and affect the quality of the slab; low-carbon high-sulfur steel is a crack-sensitive steel type, and improper workmanship may easily cause defects such as internal cracks and surface depressions in the slab, and even appear Steel breakout and other pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C33/04C22C38/60C22C38/02C21C7/06B22D11/111
CPCB22D11/111C21C7/0006C21C7/06C22C33/04C22C38/02C22C38/60
Inventor 李明陈兴华马骏翟卫江胡志勇韦士昆周士北许旭东
Owner NANJING IRON & STEEL CO LTD
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