Composition for corrosion and scale inhibition and sterilization and application thereof

A technology of corrosion inhibition, scale inhibition and composition, which is applied in the field of corrosion inhibition, scale inhibition and sterilization composition, which can solve the problem of low dosage and achieve the best corrosion inhibition effect

Active Publication Date: 2017-10-31
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the existing low-phosphorus (or phosphorus-free) water treatment agent is difficult to simultaneously have better corrosion inhibition, scale inhibiti

Method used

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  • Composition for corrosion and scale inhibition and sterilization and application thereof
  • Composition for corrosion and scale inhibition and sterilization and application thereof
  • Composition for corrosion and scale inhibition and sterilization and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0049] Examples 1-4

[0050] Add chemicals to the test water as shown in Table 3 and conduct scale inhibition, corrosion inhibition and bactericidal performance tests. The specific test methods are as follows. *mg / L recorded in Table 3 represents the effective (dry basis) content, and the tin salts are calculated as tin ions.

[0051] Scale inhibition performance evaluation

[0052] Add chemicals to the test water, evaporate and concentrate in a constant temperature water bath at 80±1°C to a concentration of 5 times, and take samples to analyze the remaining Ca in the water. 2+ At the same time, make a blank sample, and calculate the scale inhibition rate. The formula for calculating the scale inhibition rate is: scale inhibition rate = (C-C 0 ) / (nC 1 -C 0 ) × 100%, where,

[0053] C: Ca remaining in water 2+ Concentration (mg / L)

[0054] C 0 : blank sample Ca 2+ Concentration (mg / L)

[0055] C 1 : Ca in raw water 2+ Concentration (mg / L)

[0056] n: concentration...

Example Embodiment

[0073] Example 5

[0074] In order to simulate the scene, a dynamic simulation test was carried out. The dynamic simulation test method is carried out according to the chemical industry standard of the People's Republic of China HG / T2160-91, and the control parameters are as follows.

[0075] Water quality: test raw water 1, see Table 1.

[0076] Concentration ratio: Tower A 4.0±0.2 Tower B 4.0±0.2

[0077] pH: A tower control 8.0±0.2 B tower control 8.0±0.2

[0078] Velocity: 1.0m / s

[0079] Pharmacy:

[0080] Tower A: Weigh 5 g of polyaspartic acid with a solid content of 40 wt %, 15 g of polyepoxysuccinic acid with a solid content of 40 wt %, 3 g of benzotriazole, and 26.7 g of a copolymer with a solid content of 30 wt % Compound 1, dissolved in 48.8 g of water, and finally added 1.5 g of tin tetrachloride pentahydrate to fully dissolve it, shake it up, and obtain 100 g of the desired preparation.

[0081] When the prepared agent is added to the water at a concentrati...

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Abstract

The invention relates to the field of water treatment and discloses a composition for corrosion and scale inhibition and sterilization and an application thereof. The composition contains a water-soluble tin salt, a carboxylic acid group-containing homopolymer, a nitrogen-containing heterocyclic compound and a copolymer, wherein the copolymer comprises a structural unit provided by 2-acrylamide-2-methyl propane sulfonic acid; on the basis of the gross of the copolymer, the weight percent of the structural unit provided by the 2-acrylamide-2-methyl propane sulfonic acid is greater than or equal to 20%, wherein the weight ratio of the water-soluble tin salt to the carboxylic acid group-containing homopolymer to the nitrogen-containing heterocyclic compound to the copolymer is 1:(1-20):(1-12):(1-20); and the weight of the water-soluble tin salt is calculated according to tin ions. The composition for corrosion and scale inhibition and sterilization has relatively good corrosion inhibition property, scale inhibition property and sterilization property and is relatively low in dosage in use, and furthermore, the composition does not contain phosphorus and is green and environmentally friendly.

Description

technical field [0001] The invention relates to the field of water treatment, in particular to a composition for corrosion inhibition, scale inhibition and sterilization and its application in the treatment of circulating cooling water. Background technique [0002] Long-term operation of circulating cooling water will cause problems of corrosion, scaling and bacterial growth, so corrosion inhibitors, scale inhibitors and bactericides need to be added separately. Research on non-toxic, highly efficient multifunctional water treatment agents is the direction of pharmaceutical research and development. Most petrochemical enterprises use composite corrosion and scale inhibitors. The more widely used formulas include phosphorus-based (composed of polyphosphate, polycarboxylic acid and copolymer, zinc salt, etc.), all-organic system (composed of organic phosphonic acid, polycarboxylic acid and copolymer, azole compounds with or without Zinc salt composition), etc. In the proce...

Claims

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Application Information

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IPC IPC(8): C02F5/12C02F5/10C02F5/08
CPCC02F5/10C02F5/125C02F2303/04C02F2303/08C02F2303/22
Inventor 郦和生魏新张春原张化冰
Owner CHINA PETROLEUM & CHEM CORP
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