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Positive pole piece of capacitance type nickel-hydrogen power battery, preparation method of positive pole piece and battery prepared by positive pole piece

A positive pole piece, power battery technology, applied in the direction of battery electrodes, nickel storage batteries, alkaline storage battery electrodes, etc., can solve the problems of short battery life, achieve the effect of reducing oxygen generation and improving oxygen evolution potential

Inactive Publication Date: 2017-11-07
淄博君行电源技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the deficiencies in the prior art, the purpose of the present invention is to provide a positive pole piece of a capacitive nickel-hydrogen power battery, which can increase the oxygen evolution potential of the positive electrode and reduce the generation of oxygen. The present invention also provides its preparation method and the battery prepared therefrom. Under normal current charging, the battery does not evolve oxygen, and can be continuously floated, realizing the maintenance-free capacitive nickel-metal hydride power battery during use; solving the historical technical problem of short battery life caused by zinc dendrites

Method used

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  • Positive pole piece of capacitance type nickel-hydrogen power battery, preparation method of positive pole piece and battery prepared by positive pole piece
  • Positive pole piece of capacitance type nickel-hydrogen power battery, preparation method of positive pole piece and battery prepared by positive pole piece
  • Positive pole piece of capacitance type nickel-hydrogen power battery, preparation method of positive pole piece and battery prepared by positive pole piece

Examples

Experimental program
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Effect test

Embodiment 1

[0068] a. Preparation of positive and negative battery slurry:

[0069] Preparation of positive electrode battery slurry: according to zinc-doped spherical nickel hydroxide 100Kg, ultrafine cobalt powder 3.5Kg, titanium oxide 0.2Kg, HPMC binder 1.3Kg, PTFE emulsion 1.2Kg, carbon-containing ultrafine nickel powder 1.8 Kg, mixed evenly with deionized water accounting for 24% of the weight of the above-mentioned positive electrode battery material, to prepare positive electrode slurry.

[0070] Preparation of negative electrode battery slurry: according to the abundance of rare earth alloy 100Kg, activated carbon 0.9Kg, zinc oxide 10Kg, HPMC binder 3Kg, PTFE emulsion 2Kg, carbon-containing ultrafine nickel powder 3Kg, zinc powder 5Kg, and account for the above negative electrode battery materials 21% by weight of deionized water was evenly mixed to prepare negative electrode slurry.

[0071] b. Preparation of positive and negative electrodes: use 270g / m 2 Continuous wet coating...

Embodiment 2

[0076] a. Preparation of positive and negative battery slurry:

[0077] Preparation of positive battery slurry: 100Kg of zinc-doped spherical nickel hydroxide, 4.5Kg of superfine cobalt powder, 0.3Kg of titanium dioxide, 1.4Kg of HPMC binder, 1.4Kg of PTFE emulsion, 2Kg of carbon-containing superfine nickel powder , mixed evenly with deionized water accounting for 25% of the weight of the positive electrode battery material to prepare positive electrode slurry.

[0078] Preparation of negative electrode battery slurry: according to the abundance of rare earth alloy 100Kg, activated carbon 1.1Kg, zinc oxide 11Kg, HPMC binder 3.2Kg, PTFE emulsion 3.2Kg, carbon-containing ultrafine nickel powder 3.5Kg, zinc powder 5.5Kg, and accounted for 22% of the weight of the negative electrode battery material was mixed with deionized water evenly to prepare the negative electrode slurry.

[0079] b. Preparation of positive and negative electrodes: 300g / m 2 Continuous wet coating of foamed...

Embodiment 3

[0084] a. Preparation of positive and negative battery slurry:

[0085] Preparation of positive electrode battery slurry: according to zinc-doped spherical nickel hydroxide 100Kg, ultrafine cobalt powder 1.2Kg, titanium oxide 0.15Kg, HPMC binder 1.0Kg, PTFE emulsion 1.1Kg, carbon-containing ultrafine nickel powder 1.2 Kg, mixed evenly with deionized water accounting for 22% of the weight of the above-mentioned positive electrode battery material, to prepare positive electrode slurry.

[0086] Preparation of negative electrode battery slurry: according to the abundance of rare earth alloy 100Kg, activated carbon 0.6Kg, zinc oxide 8Kg, HPMC binder 2.8Kg, PTFE emulsion 2.4Kg, carbon-containing ultrafine nickel powder 2.5Kg, zinc powder 4Kg, and account for the above 20% of the weight of the negative electrode battery material was mixed with deionized water evenly to prepare the negative electrode slurry.

[0087] b. Preparation of positive and negative electrodes: 350g / m 2 Cont...

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Abstract

The invention belongs to the technical field of alkaline power batteries and in particular relates to a positive pole piece of a capacitance type nickel-hydrogen power battery, a preparation method of the positive pole piece and a battery prepared by the positive pole piece. Slurry of a positive pole battery is prepared from the following raw materials: zinc ball doped nickel hydroxide, ultrafine cobalt powder, titanium dioxide, PTFE (Polytetrafluoroethylene) emulsion, carbon-containing ultrafine nickel powder and an HPMC (Hydroxy Propyl Methyl Cellulose) binding agent. According to the positive pole piece provided by the invention, an oxygen evolution potential of a positive pole can be improved and the generation of oxygen is reduced; the invention further provides the preparation method of the positive pole piece and the battery prepared by the positive pole; under a normal-current charging state, the battery has no oxygen evolution and can be continuously subjected to floating charge; free maintenance of the capacitance type nickel-hydrogen power battery in a utilization process is realized; the historical technical difficulty that the service life of the battery is short, caused by zinc dendrites, is solved.

Description

technical field [0001] The invention belongs to the technical field of alkaline power batteries, and in particular relates to a positive pole piece of a capacitive nickel-hydrogen power battery, a preparation method thereof and a battery prepared by the same. Background technique [0002] In high-latitude areas, high-altitude mountainous areas or cold winters, vehicles that use lead-acid batteries as starting power often face difficulties in starting or fail to start the fire directly, and need to be heated separately to start the power supply or not turn off the standby state; while lead-acid batteries are used as vehicles. The power supply of communication base stations is often faced with freezing in winter, and the inability to work normally leads to intermittent or even direct interruption of the signal, and frequent maintenance is required, and the maintenance cost in these areas is more than ten times that of lead-acid batteries. Therefore, it is a realistic industria...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/52H01M4/62H01M4/32H01M4/26H01M4/28H01M4/30H01M2/16H01M10/30H01M50/449
CPCH01M4/26H01M4/28H01M4/30H01M4/32H01M4/52H01M4/62H01M10/30H01M2220/20H01M50/449Y02E60/10
Inventor 韩世幸蒋志军吴锋王子冬陈全世杨裕生马紫峰杨毅夫唐有根
Owner 淄博君行电源技术有限公司
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