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High-damping rubber material and preparation method thereof

A rubber material, high damping technology, applied in the field of rubber materials, can solve the problems of single damping stability performance, unable to comprehensively improve, molecular chain breakage, etc. Effect

Active Publication Date: 2017-11-10
ZHUZHOU TIMES NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to improve this technical problem, at present, it is basically improved from the synthesis of hindered phenol with macromolecular chains, which improves the problem that hindered phenol is easy to precipitate in high damping rubber. It solves the problem of single damping stability and cannot be comprehensively improved.
In the long-term use of high-damping rubber, not only will the molecular chain be broken due to the action of thermal oxygen, but also the problem of hindered phenol and operational oil precipitation will occur. This technical problem needs to be comprehensively improved.

Method used

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  • High-damping rubber material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0072] A high damping rubber material of the present invention is mainly prepared from the following raw materials:

[0073] Nitrile rubber (Nitrile content > 38%) 30kg,

[0074] Natural rubber 70kg,

[0075] Sulfur 2kg,

[0076] Anti-aging agent RD 2kg,

[0077] Antiaging agent 4010NA 3.5kg,

[0078] Zinc oxide 5kg,

[0079] Stearic acid 2kg,

[0080] Lignocellulose 20kg,

[0081] Carbon black N110 55kg,

[0082] DOP 10kg,

[0083] Accelerator CZ 1.5kg,

[0084] AO-60 30kg,

[0085] Anti-reversion agent PK900 1kg.

[0086] The preparation method of the high damping rubber material of the present embodiment comprises the following steps:

[0087] (1) Cool the internal mixer, put all the above-mentioned raw materials except sulfur and accelerators into the internal mixer for internal mixing, mix at a high temperature of 120°C, and release the sheets on the open rubber mixer, cool them, and obtain the masterbatch rubber mixing;

[0088] (2) Put the masterbatch obtai...

Embodiment 2

[0091] A high damping rubber material of the present invention is mainly prepared from the following raw materials:

[0092]

[0093] The preparation method of the high damping rubber material of the present embodiment comprises the following steps:

[0094] (1) Cool the internal mixer, put all the above-mentioned raw materials except sulfur and accelerators into the internal mixer for internal mixing, mix at a high temperature of 120°C, and release the sheets on the open rubber mixer, cool them, and obtain the masterbatch rubber mixing;

[0095] (2) Put the masterbatch obtained in step (1) into an open rubber mixing machine, add sulfur and accelerator CZ evenly for mixing, then stand for more than 24 hours, and then vulcanize at 150°C for 20 minutes to obtain high Damping rubber material.

[0096] The high-damping rubber material obtained in this example is tested according to the GB / T528 test method, and its tensile strength is 23.2 MPa, and its elongation at break is 4...

Embodiment 3

[0098] A high damping rubber material of the present invention is mainly prepared from the following raw materials:

[0099]

[0100] The preparation method of the high damping rubber material of the present embodiment comprises the following steps:

[0101] (1) Cool the internal mixer, put all the above-mentioned raw materials except sulfur and accelerators into the internal mixer for internal mixing, mix at a high temperature of 120°C, and release the sheets on the open rubber mixer, cool them, and obtain the masterbatch rubber mixing;

[0102] (2) Put the masterbatch obtained in step (1) into an open rubber mixing machine, add sulfur and accelerator CZ evenly for mixing, then stand for more than 24 hours, and then vulcanize at 150°C for 20 minutes to obtain high Damping rubber material.

[0103] According to the GB / T528 test method, the high damping rubber material obtained in this embodiment has a tensile strength of 22.3 MPa, a breaking elongation of 443%, and a maxi...

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Abstract

The invention discloses a high-damping rubber material. The high-damping rubber material is mainly prepared from raw materials in parts by mass as follows: 100 parts of rubber, 1-4 parts of sulfur, 3-8 parts of an anti-aging agent, 3-10 parts of zinc oxide, 1-5 parts of stearic acid, 20-75 parts of polar filler, 5-20 parts of a plasticizer, 1-3 parts of an accelerant CZ, 0.2-2 parts of an anti-reversion agent and 10-50 parts of hindered phenol and / or hindered amine; the rubber is polar rubber or combination of polar rubber and non-polar rubber; when the rubber is the combination of polar rubber and non-polar rubber, not less than 20 parts by mass of the polar rubber is utilized; the polar filler is lignin fiber and / or white carbon black. The preparation method comprises steps as follows: all the raw materials except sulfur and the accelerant are subjected to high-temperature mixing and cooling, and masterbatch is obtained; sulfur and the accelerant are added to the masterbatch for mixing, still standing and vulcanization, and the high-damping rubber material is obtained. The high-damping rubber material is excellent in heat stability, and thermal-oxidation acceleration based aging proves that no micromolecules are separated out, and long-term use requirement can be met.

Description

technical field [0001] The invention belongs to the field of rubber materials, and in particular relates to a high-damping rubber with good performance stability during long-term use and a preparation method thereof. Background technique [0002] With the development of modern science and technology and the continuous improvement of human living standards, people have put forward higher requirements for the comfort of working and living environments. Therefore, how to effectively control various types of vibration and noise pollution has become an important concern of scientists. one of the subjects. Due to its unique viscoelastic properties, rubber has a good damping effect, and has been widely used for shock and noise reduction in rail transit, construction, machinery and other fields. [0003] Rubber-plastic blending is a common method to improve damping. For example, CN201410128421 patent discloses a high-damping rubber bearing and its preparation method. The molding p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L7/00C08L9/02C08L97/02C08L23/28C08K13/02C08K3/06C08K3/22C08K5/09C08K3/04C08K3/34
CPCC08K2003/2296C08L7/00C08L9/02C08L2201/08C08L2205/03C08L2205/035C08L97/02C08L91/00C08K13/02C08K3/06C08K3/22C08K5/09C08K3/04C08K3/34C08K3/346C08L23/283
Inventor 张保生李斌唐军辉刘洪平王进王雪飞黄良平
Owner ZHUZHOU TIMES NEW MATERIALS TECH