Compound, colorant composition containing the compound and resin composition containing the compound
A compound and composition technology, applied in the field of new compounds, can solve the problems of low heat resistance and reduced chemical corrosion resistance, and achieve the effect of improving chemical corrosion resistance, excellent chemical corrosion resistance and high brightness
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manufacture example 1
[0208] [Production Example 1] Production of Compound A
[0209]
[0210] To 0.55 g (0.38 mmol, 1.2 eq) of naphthalene-1-amine, 1 mL of AcOH, 0.3 g (0.31 mmol, 1 eq) of cyclohexanone, and 1 mL of dichloromethane were added, followed by stirring for about 30 minutes. Thereafter, slowly add NaBH(OAC) 3 1.0 g (4.7 mmol, 1.5 eq). After stirring at room temperature for about 16 hours, distilled water was added, extracted with dichloromethane, and the organic layer was dried over sodium sulfate and dried under reduced pressure. The obtained product was purified with a column (ethyl acetate:hexane=1:9 ratio) to obtain 0.74 g of Compound A. (yield 86%)
manufacture example 2
[0211] [Production Example 2] Production of Compound B
[0212]
[0213] 50 ml of dimethylformamide (DMF) was added to 3.7 g (0.026 mol, 1 eq) of naphthalene-1-amine, and 17.85 g (0.13 mol, 5 eq) of potassium carbonate was slowly added at room temperature, followed by stirring for 30 minutes. Then, 7.8 g (0.065 mol, 2.5 eq) of allyl bromide was added, and it stirred at room temperature for 4 hours. After completion of the reaction, distilled water was added, extracted with ether, and the organic layer was dried over sodium sulfate and dried under reduced pressure. The obtained product was purified by column (ethyl acetate:hexane=1:100-1:80 ratio), and 1.5 g of compound B was obtained in 34% yield.
manufacture example 3
[0214] [Production Example 3] Production of Compound C
[0215]
[0216] To 3.0 g (0.021 mol, 1 eq) of naphthalene-1-amine was added 30 mL of dichloromethane, and 2.75 g (0.027 mol, 1.3 eq) of triethylamine was slowly added at room temperature. Then, methacrylic acid 4.8g (0.056mol, 2.7eq) was added, and it stirred at normal temperature for 16 hours. After completion of the reaction, distilled water was added, extracted with dichloromethane, and the organic layer was dried over sodium sulfate and dried under reduced pressure. The obtained product was purified by column (ethyl acetate:hexane=1:10-1:15 ratio), and 0.9 g of compound C was obtained in 20% yield.
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