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Physical purification method for recycling positive powder from lithium ion battery

A lithium-ion battery and physical purification technology, which is applied in the field of physical purification of lithium-ion battery recovery positive electrode powder, can solve the problem of the reduction of the effective recovery rate of aluminum purity positive electrode powder, increasing the difficulty of separating positive electrode powder by physical methods, and the recycling of waste batteries The rate is less than 2%, and achieve the effect of low cost, improved recovery rate, and less investment in equipment

Inactive Publication Date: 2018-01-05
CHINA AVIATION LITHIUM BATTERY LUOYANG
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  • Summary
  • Abstract
  • Description
  • Claims
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Problems solved by technology

[0002] With the country's vigorous promotion of electric vehicles, a large number of power lithium batteries will be scrapped in the future. According to the prediction of China Automotive Technology Research Center, the recovery rate of waste batteries in my country will be less than 2% in the future.
If you want to obtain a higher purity positive electrode powder, you need to use a finer screen for sieving. In this case, the purity of the positive electrode powder can also reach more than 98%, but the finer the screen for the positive electrode powder The material is sieved, and a large number of positive electrode powder particles with larger particle sizes are mixed into the aluminum particles, which greatly reduces the purity of the recovered aluminum and the effective recovery rate of the positive electrode powder.
In addition, in the process of recycling the positive electrode powder, it is inevitable that the iron that has been worn off by the equipment will be brought into the positive electrode powder, which further increases the difficulty of separating the positive electrode powder by physical methods. How to ensure the effective use of the positive electrode powder In the case of low recovery rate, further improving the purity of the positive electrode powder recovered by physical methods has become an urgent problem to be solved.

Method used

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  • Physical purification method for recycling positive powder from lithium ion battery

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Embodiment 1

[0020] The physical purification method of lithium ion battery recovery positive electrode powder of the present embodiment comprises the following steps:

[0021] 1) Dry the recovered positive electrode powder of lithium iron phosphate lithium ion battery at 120°C for 30 minutes; then ball mill it at a speed of 300r / min for 0.5h to obtain positive electrode powder with a particle size of 50-100μm;

[0022] 2) The positive electrode powder after ball milling in step 1) is subjected to the first magnetic separation with a magnetic field whose magnetic induction intensity is 3000Gs, and the selected matter is removed to obtain the remaining powder;

[0023] 3) Use a magnetic field with a magnetic induction intensity of 8000Gs to perform a second magnetic separation on the remaining powder, and collect the selected material to obtain the product.

[0024] The purity of the positive electrode powder obtained by using the physical purification method for recovering the positive ele...

Embodiment 2

[0026] The physical purification method of lithium ion battery recovery positive electrode powder of the present embodiment comprises the following steps:

[0027] 1) Dry the recovered lithium manganate lithium ion battery positive electrode powder at 150°C for 30 minutes; then ball mill it at a speed of 200r / min for 1 hour to obtain positive electrode powder with a particle size of 50-100 μm;

[0028] 2) The positive electrode powder after ball milling in step 1) is subjected to magnetic separation for the first time using a magnetic field with a magnetic induction intensity of 2500Gs, and the selected material is removed to obtain the remaining powder;

[0029] 3) Use a magnetic field with a magnetic induction intensity of 8000Gs to perform a second magnetic separation on the remaining powder to collect the selected material;

[0030] 4) Carry out magnetic separation to the residue after the second magnetic separation by using a magnetic field whose magnetic induction intens...

Embodiment 3

[0034] The physical purification method of lithium ion battery recovery positive electrode powder of the present embodiment comprises the following steps:

[0035] 1) Dry the recovered lithium cobaltate lithium-ion battery cathode powder at 135°C for 30 minutes; then ball mill it at a speed of 300r / min for 0.2h to obtain the cathode powder with a particle size of 50-100μm;

[0036] 2) The positive electrode powder after ball milling in step 1) is subjected to the first magnetic separation using a magnetic field with a magnetic induction intensity of 3500Gs, and the selected material is removed to obtain the remaining powder;

[0037] 3) Use a magnetic field with a magnetic induction intensity of 10000Gs to perform a second magnetic separation on the remaining powder, and collect the selected material;

[0038] 4) Using a magnetic field with a magnetic induction intensity of 12000Gs to perform magnetic separation on the positive electrode powder selected in step 3), the selecte...

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Abstract

The invention relates to a physical purification method for recycling a positive powder from a lithium ion battery, and belongs to the technical field of recycling of lithium ion batteries. The physical purification method for recycling the positive powder from the lithium ion battery comprises the steps of performing first magnetic separation on the positive powder obtained by recycling by employing a magnetic field with magnetic induction intensity being 2,500-3,500Gs, removing a selected substance, performing second magnetic separation on remaining powder by employing a magnetic field withmagnetic induction intensity larger than 7,000Gs, and electing a separated substance, thereby obtaining the positive powder, wherein the positive material of the lithium ion battery contains at leastone element of cobalt, manganese, iron and nickel. The purification method is simple in process, low in equipment investment, low in cost and wide in adaptability, the positive powder with purity reaching 96% or above can be obtained by magnetic separation of a weak magnetic field in one time, and meanwhile, the aluminum recycle rate also can be improved.

Description

technical field [0001] The invention relates to a physical purification method for recovering positive electrode powder from a lithium ion battery, and belongs to the technical field of lithium ion battery recovery. Background technique [0002] With the country's vigorous promotion of electric vehicles, a large number of power lithium batteries will be scrapped in the future. According to the prediction of China Automotive Technology Research Center, the recycling rate of waste batteries in my country will be less than 2% in the future. Waste lithium-ion batteries contain reusable resources, such as valuable metals such as aluminum and copper, graphite, and positive electrode materials, as well as a large amount of electrolyte solution; if these waste lithium batteries are not handled properly, it will cause a great waste of resources. and serious environmental pollution. Therefore, the recycling of used lithium-ion batteries is of great significance. [0003] Since more ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/54B03C1/00
CPCY02W30/84
Inventor 齐彬伟李新旺王楠
Owner CHINA AVIATION LITHIUM BATTERY LUOYANG
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