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Method for coloring aluminum pigment by 5-sulfosalicylic acid dihydrate-iron ion complexes

A technology of sulfosalicylic acid and complexes, which is applied in the treatment of low-molecular-weight organic compounds in dyeing, pigment slurry, and inorganic pigments. It can solve the problems of unstable color aluminum pigments and achieve brilliant colors and good dispersibility. , good corrosion resistance

Active Publication Date: 2018-02-02
ANHUI UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It solves the defect that the color aluminum pigments prepared by physical coating or physical deposition methods are unstable in solvents

Method used

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  • Method for coloring aluminum pigment by 5-sulfosalicylic acid dihydrate-iron ion complexes
  • Method for coloring aluminum pigment by 5-sulfosalicylic acid dihydrate-iron ion complexes
  • Method for coloring aluminum pigment by 5-sulfosalicylic acid dihydrate-iron ion complexes

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] In the present embodiment, the method of utilizing 5-sulfosalicylic acid iron ion complex to color the aluminum pigment is as follows:

[0044] 1. Modification of aluminum pigment

[0045] 1a. Weigh 20 parts by mass of oily aluminum pigment, disperse evenly in 400 parts by mass of absolute ethanol, add 4 parts by mass of polyethylene glycol dropwise as a dispersant, and then ultrasonically treat for 40 minutes. After ultrasonic treatment, filter the aluminum pigment solution and use Rinse with absolute ethanol for 2 times to obtain alcohol-washed aluminum powder;

[0046] 1b. Add 12 parts by mass of tetraethyl orthosilicate and 18 parts by mass of aminopropyltriethoxysilane coupling agent to 250 parts by mass of absolute ethanol to obtain mixed solution A; add 30 parts by mass of ammonia water (mass concentration 25%) Add 60 parts by mass of deionized water to 250 parts by mass of absolute ethanol to obtain mixed solution B;

[0047] 1c. Add the alcohol-washed aluminu...

Embodiment 2

[0060] In the present embodiment, the method of utilizing 5-sulfosalicylic acid iron ion complex to color the aluminum pigment is as follows:

[0061] 1. Modification of aluminum pigment

[0062] 1a. Weigh 20 parts by mass of oily aluminum pigment, disperse evenly in 400 parts by mass of absolute ethanol, add 4 parts by mass of polyethylene glycol dropwise as a dispersant, and then ultrasonically treat for 40 minutes. After ultrasonic treatment, filter the aluminum pigment solution and use Rinse with absolute ethanol for 2 times to obtain alcohol-washed aluminum powder;

[0063] 1b. Add 12 parts by mass of tetraethyl orthosilicate and 18 parts by mass of aminopropyltriethoxysilane coupling agent to 250 parts by mass of absolute ethanol to obtain mixed solution A; add 30 parts by mass of ammonia water (mass concentration 25%) Add 60 parts by mass of deionized water to 250 parts by mass of absolute ethanol to obtain mixed solution B;

[0064] 1c. Add the alcohol-washed aluminu...

Embodiment 3

[0076] In the present embodiment, the method of utilizing 5-sulfosalicylic acid iron ion complex to color the aluminum pigment is as follows:

[0077] 1. Modification of aluminum pigment

[0078] 1a. Weigh 20 parts by mass of oily aluminum pigment, disperse evenly in 400 parts by mass of absolute ethanol, add 4 parts by mass of polyethylene glycol dropwise as a dispersant, and then ultrasonically treat for 40 minutes. After ultrasonic treatment, filter the aluminum pigment solution and use Rinse with absolute ethanol for 2 times to obtain alcohol-washed aluminum powder;

[0079] 1b. Add 12 parts by mass of tetraethyl orthosilicate and 18 parts by mass of aminopropyltriethoxysilane coupling agent to 250 parts by mass of absolute ethanol to obtain mixed solution A; add 30 parts by mass of ammonia water (mass concentration 25%) Add 60 parts by mass of deionized water to 250 parts by mass of absolute ethanol to obtain mixed solution B;

[0080] 1c. Add the alcohol-washed aluminu...

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Abstract

The invention discloses a method for coloring aluminum pigment by 5-sulfosalicylic acid dihydrate-iron ion complexes. The method mainly includes the two steps of firstly, using a silane coupling agentand ethyl orthosilicate as precursors in an alcohol system to synergistically hydrolyze the aluminum pigment by coating modification, so that the surface of the modified aluminum pigment contains a great quantity of exposed aminos; then, subjecting the synthesized 5-sulfosalicylic acid dihydrate-iron ion complexes to acylating chlorination, and making the synthesized 5-sulfosalicylic acid dihydrate-iron ion complexes subjected to acylating chlorination react with the aminos exposed on the surface of the aluminum pigment, so that the aluminum pigment is colored. The aluminum pigment prepared by the method is gorgeous in color, highly resistant to corrosion, high in glossiness and good in dispersity and can be widely applied to coating, printing ink and free spraying.

Description

technical field [0001] The invention relates to a method of using 5-sulfosalicylic acid iron ion complex to color aluminum pigments. The synthesized 5-sulfosalicylic acid iron ion complex organic dye is grafted on APTES / TEOS by chemical reaction. Aluminum pigment surface after synergistic hydrolysis modification. Background technique [0002] Aluminum pigment is an aluminum powder with a smooth and extremely thin flake structure. Because it can reflect visible light, it has a silver-white metallic effect. It is commonly known as aluminum silver powder or aluminum silver paste. It is one of the most widely used metal effect pigments. [0003] With the development of society, the advancement of science and technology and culture, people's requirements for beautification of commodities have also increased accordingly. Colored aluminum powder has the characteristics of bright color, strong corrosion resistance, high insulation, not easy to fade, strong metallic luster, and low ...

Claims

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Application Information

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IPC IPC(8): C09C1/64C09C3/06C09C3/08C09C3/12C09B57/10C09D17/00C09D155/02C09D133/00C09D7/00
CPCC01P2006/22C01P2006/60C08K9/02C08K9/04C08K9/06C08K9/10C08K2003/0812C09B57/10C09C1/644C09C3/006C09C3/08C09D17/003C09D17/006C09D133/00C09D155/02
Inventor 夏茹聂树平陈鹏曹明钱家盛杨斌苗继斌苏丽芬郑争志
Owner ANHUI UNIVERSITY
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