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Curable film-forming compositions containing lithium silicates as corrosion inhibitors and multilayer coated metal substrates

A technology for corrosion-inhibiting components, metal substrates, used in silicates, anti-corrosion coatings, alkali metal silicates, etc.

Active Publication Date: 2018-02-16
PRC DE SOTO INT INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, evolving administrative regulations addressing health and environmental concerns have led to the phase-out of certain corrosion inhibitors and other additives in coating compositions, making it challenging to produce effective coating compositions

Method used

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  • Curable film-forming compositions containing lithium silicates as corrosion inhibitors and multilayer coated metal substrates
  • Curable film-forming compositions containing lithium silicates as corrosion inhibitors and multilayer coated metal substrates
  • Curable film-forming compositions containing lithium silicates as corrosion inhibitors and multilayer coated metal substrates

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0189] Coating Examples 1-4 were prepared as follows:

[0190]For Part A of each example, all materials were weighed into a suitable container and mixed thoroughly using an air motor and mixing blade. For Part B of each example, all materials except Silquest A-187 were weighed and placed into glass jars. An amount of dispersion medium equal to about twice the total weight of the component materials was then added to each tank. The jars were sealed with lids and placed in a Lau dispersion apparatus for a 3 hour dispersion period. All final dispersions had a Hegman gauge reading greater than 7. After the pigment dispersion process is complete, add Silquest A-187 to the Part B mixture. The final Part B mixture is then mixed thoroughly. Prior to coating application, the respective proportions of each Total Component A and Total Component B shown in Table 2 were mixed together, mixed well, and given an induction time of 30 to 60 minutes prior to coating.

[0191] The coatings ...

Embodiment 7-9

[0243] Coating Examples 7-9 were prepared as follows:

[0244] For Part A of each example, all materials were weighed into a suitable container and mixed thoroughly using an air motor and mixing blade. For Part B of each example, all materials except Silquest A-187 were weighed and placed in glass jars. Dispersion medium was then added to each tank in an amount approximately equal to twice the total weight of the component materials. The jars were sealed with lids and placed in a Lau dispersion apparatus for 1.5 hours of dispersion. All final dispersions had a Hegman gauge reading greater than 7. After the pigment dispersion process was complete, Silquest A-187 was added to the Part B mixture. The final Part B mixture is then mixed thoroughly. Prior to coating application, each Total Component A and Total Component B were blended together in the respective ratios shown in Table 6, mixed thoroughly, and given an induction time of 30 to 60 minutes prior to coating.

[0245]...

Embodiment 10-11

[0254] Coating Examples 10-11 were prepared as follows:

[0255] For Part A of each example, all materials were weighed and placed in glass jars. Dispersion medium was then added to each tank in an amount equal to about half the total weight of the component materials. For Part B of each example, all materials except Silquest A-187 were weighed and placed in glass jars. Dispersion medium was then added to each tank in an amount approximately equal to twice the total weight of the component materials. The jars of each component were sealed with lids and placed in a Lau dispersing apparatus for a 3.0 hour dispersion period. All final dispersions had a Hegman gauge reading greater than 7. After the pigment dispersion process was complete, Silquest A-187 was added to the Part B mixture. The final Part B mixture is then mixed thoroughly. Prior to coating application, each Total Component A, each Total Component B, and each Diluent Component were blended together in the respect...

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Abstract

A curable film-forming composition is provided, comprising: (1) a curable, organic film-forming binder component; and (2) a corrosion inhibiting component comprising a lithium silicate, present in thecurable film-forming composition in an amount of 0.1 to 4.5 percent lithium by weight. Also provided are coated metal substrates, including multilayer coated metal substrates, comprising the above composition. Also provided is a multilayer coated metal substrate comprising: (a) a metal substrate; (b) a first curable film-forming composition applied to said metal substrate; and (c) a second curable film-forming composition applied on top of at least a portion of the first curable film-forming composition. The first and second curable film-forming compositions independently comprise: (1) a curable, organic film-forming binder component; and (2) a corrosion inhibiting component comprising lithium silicate, magnesium oxide and / or an azole.

Description

technical field [0001] The present invention relates to curable film-forming compositions comprising lithium silicate. The invention also relates to substrates at least partially coated with coatings deposited from such compositions and to multilayer composite coatings wherein at least two coatings are deposited from coating compositions comprising corrosion inhibiting components. Background technique [0002] Coatings are applied to appliances, automobiles, aircraft, etc. for many reasons, most notably for aesthetic reasons, corrosion protection, and / or performance enhancements such as durability and protection from physical damage. In order to improve the corrosion resistance of metal substrates, corrosion inhibitors are often used in the coatings applied to the substrates. However, evolving administrative regulations addressing health and environmental concerns have led to the phase-out of certain corrosion inhibitors and other additives in coating compositions, making i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D175/04C09D5/12C09D7/61B05D7/14B05D7/00
CPCB05D7/14B05D7/52C09D5/12C09D163/00B05D2202/25C09D5/08C09D7/61B05D7/24B05D5/00C08K2003/2241C08K3/34C08K3/22C09D5/00C01B33/32C09D5/002C09D175/04C08K3/105B32B15/08C08L63/00C09D5/084B32B2264/102C08L27/12C08L75/04C08L87/00C08L2203/16
Inventor E·A·弗拉尔M·A·玛尤E·L·莫里斯T·G·布恩特
Owner PRC DE SOTO INT INC