A catalyst-loaded graphene-modified polyester chip and preparation method thereof

A technology of graphene modification and catalyst loading, which is applied in the field of polyester synthesis, which can solve the problems of affecting wearing comfort, inability to improve polyester fiber wearing comfort, and high hardness. The effect of less, excellent flexibility

Active Publication Date: 2020-10-27
ZHEJIANG HENGYI HIGH TECH MATERIAL
View PDF2 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The disadvantage of this patented technical solution is that the edges of graphene particles have irregular geometric shapes and high hardness. The surface of graphene polyester fibers prepared by the blending method has a burr feeling due to the irregular geometric shapes of graphene particles, which affects its wearing comfort
However, grinding and ultrasonic dispersion can only solve the problem of graphene powder dispersion in polyester, but they cannot improve the wearing comfort of polyester fiber

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A catalyst-loaded graphene-modified polyester chip and preparation method thereof
  • A catalyst-loaded graphene-modified polyester chip and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] 1) Add 1 part of antimony trioxide and 10 parts of ethylene glycol into a three-necked flask, heat and stir in an electric heating mantle, control the reaction temperature at 190°C, condense and reflux for 4 hours, and remove the generated water in time with a water separator , After reacting for 2.5h, change to vacuum distillation at a temperature of 135°C to remove traces of water and unreacted ethylene glycol remaining in the reaction process. Until the reaction solution is clear and transparent, perform hot filtration.

[0031] 2) Add 0.3 parts of graphene powder to the above-mentioned filtrate after vacuum drying, let it stand at room temperature, filter immediately when crystals are precipitated, take the filter cake, dry it in vacuum, weigh it, and obtain a black powder.

[0032] 3) Add 2 parts of ethylene glycol to the above black powder and ultrasonically disperse for 0.5 hours to prepare an additive mixture.

[0033] 4) Slurry 90 parts of terephthalic acid an...

Embodiment 2

[0035] 1) Add 1 part of antimony trioxide and 9 parts of ethylene glycol into a three-necked flask, heat and stir in an electric heating mantle, control the reaction temperature at 195°C, condense and reflux for 4.5 hours, and remove the formed product in time with a water separator Water, after reacting for 2.5 hours, change to vacuum distillation at 140°C to remove traces of water and unreacted ethylene glycol remaining during the reaction. Until the reaction solution is clear and transparent, perform hot filtration.

[0036] 2) Add 0.2 parts of graphene oxide powder to the above-mentioned filtrate after vacuum drying, let it stand at room temperature, filter immediately when crystals are precipitated, take the filter cake, dry it in vacuum, weigh it, and obtain a black powder.

[0037] 3) Add 2.5 parts of ethylene glycol to the above black powder and ultrasonically disperse for 1 hour to prepare an additive mixture.

[0038] 4) Slurry 90 parts of terephthalic acid and 40 p...

Embodiment 3

[0040] 1) Add 1 part of antimony trioxide and 11 parts of ethylene glycol into a three-necked flask, heat and stir in an electric heating mantle, control the reaction temperature at 186°C, condense and reflux for 4 hours, and remove the generated water in time with a water separator After 2.5 hours of reaction, the reaction was changed to vacuum distillation at a temperature of 150° C. to remove traces of water and unreacted ethylene glycol remaining during the reaction. Until the reaction solution is clear and transparent, perform hot filtration.

[0041] 2) Add 0.5 parts of graphene oxide powder to the above-mentioned filtrate after vacuum drying, let it stand at room temperature, filter immediately when crystals are precipitated, take the filter cake, dry it in vacuum, weigh it, and obtain a black powder.

[0042] 3) Add 2 parts of ethylene glycol to the above black powder and ultrasonically disperse for 0.5 hours to prepare an additive mixture.

[0043] 4) Slurry 90 parts...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
sizeaaaaaaaaaa
Login to view more

Abstract

The invention relates to the field of polyester synthesis and discloses a catalyst-loaded graphene-modified polyester chip and a preperation method thereof. The polyester chip is prepared through esterification and polycondensation reaction of catalyst-loaded graphene powder, ethylene glycol and terephthalic acid. The prepared graphene-modified polyester chip is used for the production polyester fibers which are further processed into textiles. Consequently, the catalyst-loaded graphene-modified polyester chip has the advantages of enabling good comfort of the textiles, reducing processing costs, and having good anti-static and anti-ultraviolet effects.

Description

technical field [0001] The invention relates to the field of polyester synthesis, in particular to a catalyst-loaded graphene-modified polyester chip and a preparation method thereof. Background technique [0002] Graphene is often used as a functional phase and a reinforcing phase in composite materials due to its excellent properties. With the maturity of graphene preparation, chemical modification and dispersion technology, research on graphene-based polymer composites has progressed rapidly in recent years. At present, many domestic enterprises and research institutes are also actively exploring the application of graphene in the field of polyester chemical fiber, and have achieved some results. At present, there are many kinds of chemical fibers modified by graphene on the market, but the quality varies. [0003] Invention patent CN 104164707 A discloses a preparation method of graphene conductive polyester fiber with good conductivity and long-lasting antistatic. The...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/183C08G63/86C08K3/04D01F6/92D01F1/09D01F1/10
CPCC08G63/183C08G63/866C08K3/04D01F1/09D01F1/106D01F6/92
Inventor 胡舒龙胡超董海良王晓宇
Owner ZHEJIANG HENGYI HIGH TECH MATERIAL
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap