Microcapsule capable of improving heat storage properties and composition molded body thereof

A technology of microcapsules and moldings, applied in the field of microcapsules and their composition moldings, can solve the problems of ignoring phase change microcapsule research, decline, etc., and achieve the effect of improving heat storage capacity and improving heat storage performance

Inactive Publication Date: 2018-03-09
YUTIAN ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As the polymerization degree of PEG increases, its molecular weight increases continuously, and the physical state under normal temperature and pressure gradually changes from colorless liquid to white liquid, no longer viscous liquid, translucent solid, until waxy solid ; However, after its molecular weight reaches more than 50,000, the increase in phase transition enthalpy is extremely limited, and even declines.
[0018] However, so far, efforts to improve the heat storage performance of phase change microcapsules are based on the above two methods, but neglect the research on another important component of phase change microcapsules—the shell material.

Method used

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  • Microcapsule capable of improving heat storage properties and composition molded body thereof
  • Microcapsule capable of improving heat storage properties and composition molded body thereof
  • Microcapsule capable of improving heat storage properties and composition molded body thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] The first type of phase change microcapsules provided in this example to improve heat storage performance is numbered S1-1, its core material is industrial grade 30# phase change paraffin, and its shell material is polyoctadecyl methacrylate; the second type The number of phase-change microcapsules to improve heat storage performance is S1-2, its core material is industrial grade 30# phase-change paraffin, and its shell material is polymethyl methacrylate and polyoctadecyl methacrylate (two polymers The mass ratio is 1:1); compared with phase-change microcapsules (number S1-0), the core material is industrial grade 30# phase-change paraffin, and the shell material is polymethyl methacrylate. The difference in the preparation methods of the above three microcapsules is only in the type of shell material, and the other conditions are completely the same. The SEM photos of the three phase change microcapsules are attached figure 1 . In the figure, a is the traditional ph...

Embodiment 2

[0063] A phase-change microcapsule provided in this example to improve heat storage performance is numbered S2-1, its core material is industrial grade 30# phase-change paraffin, and its shell material is polyoctadecyl methacrylate; one of this example A comparative phase-change microcapsule (numbered S2-0), whose core material is industrial-grade 30# phase-change paraffin, and whose shell material is polymethyl methacrylate. The difference in the preparation methods of the above two microcapsules is only in the type of shell material, and the other conditions are completely the same.

[0064] In this example, microcapsules S1-1 and S1-0 described in Example 1 are used. After 4 kinds of microcapsules are tested by laser particle size analyzer, the particle size distribution curve is obtained as Figure 5 Shown; DSC curve see Figure 6 . The particle size analysis data and DSC data are summarized in Table 2.

[0065] Since the above-mentioned preparation methods of microcaps...

Embodiment 3

[0075] In this example, a phase-change microcapsule with improved heat storage performance is provided, the core material of which is a gallium-based metal alloy with a melting point of 29°C. The shell material is a block polymer with solid-solid phase transition, the soft segment is polyethylene glycol, the hard segment is polyurethane (MDI), and the phase transition temperature is 65°C.

[0076] In this example, the core material and the shell material have different phase transition temperatures, which can store heat at different temperatures, or adjust the temperature in sections.

[0077] The microcapsules obtained in this example are blended with polymers and used for foaming materials or mold making to obtain a molded microcapsule composition with improved heat storage performance according to the present invention.

[0078] This example product can be used in healthcare, electronics, storage and transportation, containers, and other products.

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Abstract

The invention discloses a microcapsule capable of improving heat storage properties and a composition molded body thereof. The microcapsule capable of improving heat storage properties is generally composed of shell materials and core materials. In aspect of improving heat storage properties of phase-change microcapsules, traditional methods do a large number of researches on core materials. The microcapsule capable of improving heat storage properties focuses on endowing or improving phase-change energy storage properties of the shell materials. Therefore, under the condition of identical coating rate or identical phase-change materials as the core materials, the microcapsule capable of improving heat storage properties can effectively improve the heat storage properties. The microcapsuleand the composition molded body thereof can be applied to textile products, clothes, shoes, medical products, masks, cosmetics, warehousing and transportation products, containers and wrapping materials, electronic devices, building materials, devices and other products.

Description

technical field [0001] The invention relates to a microcapsule capable of effectively improving heat storage performance and a composite molded body thereof. Background technique [0002] In order to use energy efficiently, energy-saving technologies for energy storage and recycling through the phase-change latent heat of phase-change materials have received increasing attention. Generally, phase change materials can be classified into solid-solid phase change materials, solid-liquid phase change materials, and solid-gas phase change materials. Among them, solid-liquid phase change materials are most widely used because of their abundant sources, stable phase change behavior, and small volume change. [0003] The phase-change energy storage material absorbs and releases heat to keep the ambient temperature relatively constant. It has two-way temperature regulation and adaptability, and can be used repeatedly in a temperature-oscillating environment. Phase change materials ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/02
Inventor 沈轲李春乔磊冯欢黄晓义杜兔平
Owner YUTIAN ENERGY CO LTD
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