Phase-change-material-based thermal management material, preparation method and applications thereof

A phase-change material and thermal management technology, applied in the field of phase-change material-based thermal management materials and their preparation, can solve the problems of poor shape stability and cycle stability of components, decreased output power of battery packs, and poor flame retardant performance, etc. Achieve good thermal conductivity and temperature control function, stable temperature adjustment and control, and ensure the effect of temperature uniformity

Active Publication Date: 2018-06-22
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the phase-change composite material of this patent has a large volume and poor thermal conductivity because it contains porous inorganic fillers, so it is only suitable for use as building materials such as wall insulation materials.
[0007] At present, although there are reports of phase change materials used for battery thermal management, these battery thermal management materials have low thermal conductivity and poor thermal conductivity, which are likely to cause the following problems:
[0008] 1) When a single battery is overheated, the heat cannot be effectively removed, and it is easy to cause uneven temperature among the single batteries in the battery pack;
[0009] 2) When the temperature of the battery pack continues to rise, it will also cause the temperature of the entire battery pack to exceed the tolerance temperature, which will accelerate the deterioration of the battery module, thereby reducing the service life, and some battery packs may even catch fire or explode, bringing greater safety Hidden danger;
[0010] 3) If the battery pack works at high temperature for a long time, the output power of the battery pack will drop significantly with the increase of temperature, so that the battery pack cannot fully exert its maximum performance
[0011] In addition, these thermal management materials also have problems such as poor flame retardancy, easy combustion, poor shape stability and cycle stability of the components made, and easy leakage on the surface of the components.

Method used

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  • Phase-change-material-based thermal management material, preparation method and applications thereof
  • Phase-change-material-based thermal management material, preparation method and applications thereof
  • Phase-change-material-based thermal management material, preparation method and applications thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] ① Weigh 80g of alkane-type paraffin wax with a melting point of 45°C and heat it to melt, add 5g of oil absorbent and stir evenly; the oil absorbent is made of SEBS and HDPE at a mass ratio of 1:2.

[0062] ②Add 6g of graphene and 3g of chopped glass fiber to the material in step ① and stir and mix evenly; wherein the diameter of the chopped glass fiber is 10 μm and the length is 3mm.

[0063] ③ Add 6g of flame retardant to the material in step ② and stir evenly; the flame retardant is prepared from decabromodiphenyl ether, antimony trioxide and terpene resin in a mass ratio of 3:1:1.

[0064] ④ Cool to normal temperature after discharge, and then use a screen to dry out larger agglomerates to obtain the heat management material.

Embodiment 2 to 30

[0066] Examples 2 to 30 were performed in the same manner as in Example 1 except for the contents shown in Table 1 below. The enthalpy value, phase transition temperature and thermal conductivity of the thermal management material were detected, and the detection results are shown in Table 1.

[0067]

[0068]

[0069] In Table 1: A1 represents alkane type paraffin wax with a melting point of 45°C, A2 represents alkane type paraffin wax with a melting point of 55°C, A3 represents a higher aliphatic hydrocarbon with 18 carbon atoms, and A4 represents a higher aliphatic hydrocarbon with a carbon number of 22, A5 represents a higher aliphatic hydrocarbon with 26 carbon atoms, A6 represents a higher aliphatic alcohol with a carbon number of 12, A7 represents a higher aliphatic alcohol with a carbon number of 18, A8 represents polyethylene glycol with a molecular weight of 10,000, and A9 represents a molecular weight 20,000 polyethylene glycol, A10 represents higher fatty aci...

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Abstract

The invention relates to a phase-change-material-based thermal management material, a preparation method and applications thereof, wherein the thermal management material comprises, by mass, 55-90% ofa phase change material, 4-20% of a thermal conduction filler, 4-20% of a flame retardant, and 2-10% of chopped fiber. According to the present invention, by adding an appropriate amount of the chopped fibers, the deformation of the phase change material due to volume expansion or contraction can be effectively prevented, such that the content of the phase change material in the thermal management material can be substantially increased so as to improve the heat storage capacity of the thermal management material and stably regulate and control the temperature.

Description

technical field [0001] The invention relates to the technical field of battery heat management, in particular to a heat management material based on a phase change material, a preparation method and application thereof. Background technique [0002] Batteries such as secondary batteries have been widely used as energy sources for wireless mobile devices, such as power sources for electric vehicles, hybrid electric vehicles, and plug-in hybrid electric vehicles, etc., thereby solving problems caused by vehicles using petroleum fuels. issues such as air pollution. Small wireless mobile devices may use one or more battery cells, while medium or large wireless devices such as vehicles may use medium or large battery modules that include multiple battery cells that are electrically connected to each other. Such medium or large battery modules typically Manufactured to have the smallest possible size and weight, the battery cells stacked in these battery modules are therefore hig...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/613H01M10/615H01M10/653H01M10/659C09K5/14
CPCC09K5/14H01M10/613H01M10/615H01M10/653H01M10/659H01M2200/00Y02E60/10
Inventor 金兆国党广洲张雅倩张靖驰王瑞杰刘斌
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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