Portable laser-induced breakdown spectroscopy analysis device

A laser-induced breakdown and spectral analysis technology, which is applied in the field of portable laser-induced breakdown spectral analysis devices, can solve the problems of reducing the utilization rate of laser plasma hemispherical emission spectrum, the high price of wide-spectrum apochromatic components, and inconsistent collection efficiency. , to increase the space angle, facilitate portability and operation, and reduce equipment cost

Pending Publication Date: 2018-03-09
NANJING INST OF ADVANCED LASER TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (1) The range of the atomic emission spectrum is generally 200-800nm. It is difficult to eliminate chromatic aberration by using a transmission element as a wide-spectrum collection element, which makes the spectral collection efficiency of each wavelength inconsistent. At the same time, the wide-spectrum apochromatic element is expensive, which greatly increases the cost;
[0006] (2) The non-coaxial setting of the excitation light path and the collection light path limits the receiving area of ​​the collected spectrum, reduces the utilization rate of the emission spectrum of the laser plasma hemisphere, so that a higher energy laser is required, which increases the cost of the instrument and reduces the safety;
[0007] (3) Most of the existing laser-induced breakdown spectroscopy analyzers are large in size and mostly desktop, which is not suitable for handling operations

Method used

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  • Portable laser-induced breakdown spectroscopy analysis device
  • Portable laser-induced breakdown spectroscopy analysis device
  • Portable laser-induced breakdown spectroscopy analysis device

Examples

Experimental program
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Embodiment 1

[0026] Such as figure 2 As shown, it is the optical path structure diagram of the portable laser-induced breakdown spectroscopy analysis device of this embodiment, including a laser 1, a beam splitting unit, a first spherical mirror 3, a second spherical mirror 4, a sample to be tested 5, an off-axis parabolic mirror 6, an optical fiber Head 7, optical fiber 8, spectrometer 9, control box 10; in this embodiment, the beam splitting unit uses a dichroic mirror 2 to split the incident collimated laser light and the signal light returned via the second spherical mirror 4 and the first spherical mirror 3 .

[0027] The control box 10 is connected to the laser 1 to provide power for the laser 1 to generate laser light. The laser light emitted by the laser 1 is transmitted parallel to the surface of the first spherical mirror 3 through the dichroic mirror 2, and reflected by the first spherical mirror 3 to the second spherical mirror 4. The laser beam passes through the The second ...

Embodiment 2

[0036] Such as Figure 4 Shown is the optical path diagram of the portable laser-induced breakdown spectroscopy analysis device of the second embodiment, and the same symbols are assigned to the same components as those of the first embodiment, and detailed descriptions are omitted.

[0037] In the second embodiment, a negative lens 16 is placed between the laser 1 and the dichroic mirror 2 to diverge the excitation light. Proper selection of the negative lens 16 , the first spherical mirror 3 and the second spherical mirror 4 keeps the excitation light focused on the surface of the test sample 5 .

[0038] A negative lens 16 is added to diverge the parallel laser beams to generate a virtual focus, and the virtual focus and the optical fiber head 7 are in an object-image conjugate relationship.

[0039] The excited signal light is respectively reflected by the second spherical mirror 4 and the first spherical mirror 3 according to the original path, transmitted to the dichroi...

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Abstract

The invention discloses a portable laser-induced breakdown spectroscopy analysis device. The portable laser-induced breakdown spectroscopy analysis device comprises a laser device, a beam splitting unit, a reflection mirror group, an off axis parabolic mirror and a spectrograph; laser rays emitted by the laser device are transmitted to the reflection mirror group in parallel through the beam splitting unit, and are focused on the surface of a sample to be tested after reflected with the reflection mirror group; signal light rays emitted by the sample to be tested are emitted to the beam splitting unit after reflected with the reflection mirror group; the laser rays and the signal light rays are in coaxial in a light path between the beam splitting unit and the sample to be tested, are reflected to the off axis parabolic mirror through the beam slitting unit, and are transmitted to the spectrograph after reflected with the off axis parabolic mirror, and are connected with a control boxfor spectral analysis and display. By adopting the portable laser-induced breakdown spectroscopy analysis device, the defects existing in a transmission-type non-coaxial spectroscopy analysis device are overcome, meanwhile numerical aperture of focused laser rays is increased, focal spot number is reduced, the energy density of the laser rays acting on the surface of an object is increased, an requirement of an instrument on the energy of the laser device is met, so that the portable laser-induced breakdown spectroscopy analysis device has considerably foreseeable industrial and commercial application value.

Description

technical field [0001] The invention relates to the technical field of element spectrum analysis, in particular to a portable laser-induced breakdown spectrum analysis device. Background technique [0002] Laser-induced breakdown spectroscopy is a detection technology based on atomic emission spectroscopy, which relies on high-energy laser pulses to heat the surface of the sample, so that the particles on the surface of the sample obtain enough energy to break away from the surface and then break down to obtain plasma, and detect atomic emission spectroscopy. . Due to its fast detection speed, the ability to analyze gases, liquids, and solids, the ability to perform full-element analysis, and remote detection, etc., laser-induced breakdown spectroscopy can be widely used in many fields such as environmental monitoring, biomedicine, and geological research. . In view of the inconvenience of sampling in archaeology, architecture, cultural relic inspection, art appraisal, etc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/71G01N21/01
CPCG01N21/01G01N21/71G01N2021/0112
Inventor 曾爱军陈国飞陈宽刘华李婧御
Owner NANJING INST OF ADVANCED LASER TECH
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