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Multilayer heat-resistant ablation-resistant composite material and preparation method thereof

A composite material, anti-ablation technology, applied in chemical instruments and methods, layered products, synthetic resin layered products, etc., can solve the problems of protective material quality, heavy mechanical strength, heat insulation, etc., to improve bonding ability and firmness. , excellent mechanical properties, the effect of excellent mechanical properties

Inactive Publication Date: 2018-03-13
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to provide a multi-layer heat-resistant anti-corrosion Ablation composite material and its preparation method

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  • Multilayer heat-resistant ablation-resistant composite material and preparation method thereof

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specific Embodiment approach 1

[0016] Specific implementation mode one: as figure 1 As shown, what is described in this embodiment is a multi-layer heat-resistant and ablation-resistant composite material. The composite material is composed of an inner layer bearing layer and an outer layer heat insulation layer; An amine resin composite material layer, the outer heat insulating layer is a glass fiber reinforced methylphenyl silicone resin composite material layer; the inner bearing layer and the outer heat insulating layer are bonded by an interlayer adhesive; a The first layer is the outer heat insulation layer, that is, the glass fiber reinforced methylphenyl silicone resin composite material layer, the b layer is the inner layer bearing layer, that is, the carbon fiber reinforced polyimide resin composite material layer, and the c layer is the interlayer adhesive .

specific Embodiment approach 2

[0017] Specific embodiment two: a kind of multi-layer heat-resistant ablation-resistant composite material described in specific embodiment one, the described interlayer adhesive is silicone resin adhesive or epoxy modified silicone resin adhesive One or a mixture of both.

specific Embodiment approach 3

[0018] Embodiment 3: A method for preparing a multi-layer heat-resistant and ablation-resistant composite material described in Embodiment 1 or 2. The specific steps of the method are as follows:

[0019] Step 1: Arrange the glass fiber in an oven, keep it at 200°C-250°C for 4-6h, cool down to room temperature naturally, and then impregnate the glass fiber cloth into methyl phenyl silicone resin with a solid content of 50%. After impregnating the glass fiber cloth, dry it naturally for 24 hours by dry method to prepare a prepreg, and then put it into a mold for compression molding. 2-4 h between 130°C-150°C, 2-4 h between 130°C-150°C, 2-4h between 160°C-180°C, 4-6h between 190°C-230°C, to obtain glass fiber reinforced methyl phenyl silicone resin Composite layer;

[0020] Step 2: The glass fiber reinforced methylphenyl silicone resin composite material layer and the carbon fiber reinforced polyimide resin composite material layer obtained in step 1 are bonded together with an...

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Abstract

The invention discloses a multilayer heat-resistant ablation-resistant composite material and a preparation method thereof, and belongs to the field of protective materials. The composite material consists of an inner bearing layer and an outer heat insulation layer, wherein the inner bearing layer is a carbon fiber reinforced polyimide resin composite material layer, and the outer heat insulationlayer is a glass fiber reinforced methyl phenyl silicone resin composite material layer; and the inner bearing layer and the outer heat insulation layer are adhered by an interlayer adhesive. The multilayer heat-resistant ablation-resistant composite material provided by the invention has the following advantages: the inner carbon fiber reinforced polyimide resin composite material layer serves as a bearing layer, has good chemical corrosion resistance, excellent high temperature resistance, high strength and large bearing capacity, can be effectively used for protection under a high pressure, and overcomes the defects of mechanical properties of protective materials for motor vehicle shells, aircraft shells and the like; and the outer glass fiber reinforced methyl phenyl silicone resin composite material layer has excellent high temperature resistance, erosion resistance and ablation resistance, and also has excellent mechanical property and good dielectric property.

Description

technical field [0001] The invention belongs to the field of protective materials, and in particular relates to a multi-layer heat-resistant and anti-ablation composite material and a preparation method thereof. Background technique [0002] With the rapid development of high-tech industries and the improvement of national living standards, higher and higher requirements are put forward for the structural control and functional design of resin-based composite materials in daily life. For example, the shell of a motor vehicle and the shell of an aircraft can reach 300°C. As a heat protection material for heat insulation protection, resin-based composites should not only have excellent mechanical properties and dielectric properties, but also have excellent heat resistance properties. Existing protective materials still have many deficiencies in terms of mechanical properties and heat insulation. [0003] Carbon fiber reinforced resin matrix composite material is a high-perf...

Claims

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Application Information

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IPC IPC(8): B32B27/04B32B9/00B32B9/04B32B17/04B32B17/12B32B7/12B29C65/48B29C70/50
CPCB32B9/047B29C65/48B29C70/50B29L2009/00B32B5/26B32B7/12B32B17/067B32B2250/20B32B2260/021B32B2260/046B32B2262/101B32B2262/106B32B2307/202B32B2307/306B32B2307/3065B32B2307/50B32B2307/714B32B2605/00
Inventor 姜波张亮黄玉东刘丽巩桂芬关胜杰陈一帆丁磊
Owner HARBIN INST OF TECH