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Preparation method and application method of shape memory polymer composite 4D printing line for fused deposition printing

A technology of memory polymer and fused deposition, which is applied in the direction of manufacturing tools, additive manufacturing, metal processing equipment, etc., can solve the problems of difficult to achieve three-dimensional shape memory polymer materials, difficult to meet industrial production applications, unstable performance of printing lines, etc. , to achieve large-scale repeatability, wide range of molding sizes, and suitable for process requirements

Active Publication Date: 2020-09-25
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Affected by the traditional molding process, shape memory polymer materials are usually processed into simple two-dimensional shapes such as plates, sheets, films, etc., and it is difficult to realize three-dimensional molding of shape memory polymer materials
At present, the printing lines prepared by the existing 4D printing line equipment cannot mass-produce printing lines due to their unstable performance, but the printers and printing lines of composite material printing lines with stable performance are only in the laboratory research and development stage, and cannot In mass production, the performance of the prepared printing line is unstable due to uneven mixing during the preparation process
Existing processes and solutions are still difficult to meet the requirements of industrial production applications

Method used

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  • Preparation method and application method of shape memory polymer composite 4D printing line for fused deposition printing
  • Preparation method and application method of shape memory polymer composite 4D printing line for fused deposition printing
  • Preparation method and application method of shape memory polymer composite 4D printing line for fused deposition printing

Examples

Experimental program
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Effect test

Embodiment 1

[0019] This embodiment provides a method for preparing a shape memory polymer composite 4D printing line for fused deposition printing, comprising the following steps:

[0020] (1) Blending 80 parts of polylactic acid particles as a matrix material and 20 parts of ferric oxide nanoparticles as functional nanoparticles at room temperature, so that the surface of polylactic acid particles completely covers the ferric oxide particles, and mixture A is obtained ;

[0021] (2) Preheat the twin-screw extruder and adjust the parameters of the twin-screw extruder: feeding frequency is 3, extrusion temperature is 160°C, screw speed is 50 r / pm, outlet temperature is 180°C, the twin-screw extruder The temperature control unit of the extruder was set to 160°C.

[0022] (3) Put the mixture A into the feeding port of the twin-screw extruder, and extrude a printing line with a diameter of 1.75 mm. This embodiment successfully produced a shape memory polymer composite 4D printing line appli...

Embodiment 2

[0029] The difference between this example and Example 1 is that the base material is 85 parts of polylactide-glycolide, the functional nanoparticles are 10 parts of carbon nanotubes, and the head of the twin-screw extruder The temperature was 170°C, the screw speed was 100 r / pm, the feeding frequency was 5, the outlet temperature was 185°C, and the temperature control unit of the twin-screw extruder was set at 165°C. The external excitation environment is electric excitation.

Embodiment 3

[0031] The difference between this embodiment and Example 1 is that the base material is 90 parts of polymethyl methacrylate, the functional nanoparticles are 10 parts of carbon black, and the head temperature of the twin-screw extruder is 180°C, the screw speed is 200r / pm, the outlet temperature is 182°C, and the temperature control unit of the twin-screw extruder is set to 170°C. The external excitation environment is microwave excitation.

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Abstract

The invention discloses a preparing method and application method of a shape memory polymer composite 4D printing line for fused deposition printing. The preparing method comprises following steps: firstly, 80 to 100 parts of base materials or thermoplastic material particles and 5 to 20 parts of functional nano particles are co-mixed at the room temperature, and surfaces of the base materials orthermoplastic material particles are completely covered with the nano function materials, and a mixture A is obtained; secondly, a dual-screw extruder is preheated, and parameters of the dual-screw extruder are adjusted and comprise the feeding speed, the extrusion temperature, the screw rod temperature, the outlet temperature, the traction speed and the winding speed; thirdly, the mixture A is placed in a feeding opening of the dual-screw extruder, and the printing line with the diameter being 1.70 mm to 1.80 mm is extruded out. The method is low in preparing cost, simple in preparing method,large in scale, high in repeatability and suitable for mass production. Design is achieved, preparing of 4D printing lines of various-shape memory polymer composites can be achieved, and the application range is wide.

Description

technical field [0001] The invention relates to the field of 4D printing, in particular to a preparation method and an application method of a shape memory polymer composite 4D printing line for fused deposition printing. Background technique [0002] Currently, shape memory polymers are in their infancy in the field of 4D printing. Affected by the traditional molding process, shape memory polymer materials are usually processed into simple two-dimensional shapes such as plates, sheets, and films, and it is difficult to realize three-dimensional molding of shape memory polymer materials. At present, the printing lines prepared by the existing 4D printing line equipment cannot mass-produce printing lines due to their unstable performance, but the printers and printing lines of composite material printing lines with stable performance are only in the laboratory research and development stage, and cannot In mass production, the performance of the prepared printing line is unst...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C64/118B29C64/112B29C64/379B29C48/92B33Y30/00C08L67/04C08L67/02C08L3/12C08L69/00C08L33/04C08L1/04C08L75/04C08L23/08C08K7/24C08K3/04C08K3/22
CPCB29C48/92B29C2948/92704B33Y30/00C08K3/04C08K3/22C08K7/24C08K2003/2275C08K2201/011C08L33/12C08L67/02C08L67/04C08L69/00C08L33/04C08L1/04C08L75/04C08L23/0853C08K7/06
Inventor 冷劲松刘彦菊张风华郑志超魏洪秋
Owner HARBIN INST OF TECH