High-strength sulfur-oxygen nucleating agent

A sulfur-oxygen inoculant, high-strength technology, applied in the field of cast iron, can solve the problems of limited effect of added elements, small shrinkage tendency, unsatisfactory, etc., to inhibit the growth of dendrites, reduce deformed graphite, and prevent carbides produced effect

Inactive Publication Date: 2018-03-23
YUZHOU HENGLILAI ALLOY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the effective sulfur and oxygen in molten iron after spheroidization are greatly reduced, so the effect of adding elements in the inoculant is also limited, and the number of effective crystal nuclei that may be formed after treatment will restrict the effect of inoculation, and ferrosilicon The tensile strength of the castings obtained from the molten iron produced is below 300MPa, which cannot meet the requirements of some machine castings that require high toughness
[0003] In order to enhance the effect of inoculation, a new type of inoculant, Elkem

Method used

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  • High-strength sulfur-oxygen nucleating agent
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  • High-strength sulfur-oxygen nucleating agent

Examples

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Effect test

Embodiment 1

[0036]A high-strength sulfur-oxygen inoculant, the mass percentage of elements contained in the sulfur-oxygen inoculant is: Si: 70-76%, Ca: 0.2-1.0%, Ba: 0.3-0.5%, La: 1.5-2.0 %, Al: 0.5-1.5%, S: 0.3-0.9%, O: 0.3-0.9%, Sb: 0.5-1.5%, and the balance is iron;

[0037] The sulfur-oxygen inoculant is prepared from the following raw materials in parts by weight:

[0038] 2-4 parts of steel scrap, 130-140 parts of ferrosilicon, 1-1.4 parts of silicon barium, 1-1.8 parts of silicon calcium, 2-4 parts of pure lanthanum, 1.5-2.5 parts of antimony, 1-2 parts of FeS, 1-1.4 parts of FeO .

[0039] The preparation process of the above-mentioned high-strength sulfur-oxygen inoculant comprises the following steps:

[0040] (1) Ingredients: Weigh the steel scrap, ferrosilicon, silicon barium, silicon calcium, pure lanthanum and antimony in the above parts by weight, and mix them;

[0041] (2) Melting: Add the above raw materials into an intermediate frequency induction furnace and melt for...

Embodiment 2

[0049] A high-strength sulfur-oxygen inoculant, the mass percentage of elements contained in the sulfur-oxygen inoculant is: Si: 73%, Ca: 0.6%, Ba: 0.4%, La: 1.75%, Al: 1.0%, S : 0.6%, O: 0.6%, Sb: 1.0%, the balance is iron;

[0050] The sulfur-oxygen inoculant is prepared from the following raw materials in parts by weight:

[0051] 3 parts of steel scrap, 135 parts of ferrosilicon, 1.2 parts of silicon barium, 1.4 parts of silicon calcium, 3 parts of pure lanthanum, 2 parts of antimony, 1.5 parts of FeS, 1.2 parts of FeO.

[0052] The preparation process of the above-mentioned high-strength sulfur-oxygen inoculant comprises the following steps:

[0053] (1) Ingredients: Weigh the steel scrap, ferrosilicon, silicon barium, silicon calcium, pure lanthanum and antimony in the above parts by weight, and mix them;

[0054] (2) Melting: put the above raw materials into an intermediate frequency induction furnace and melt at 1340°C for 35 minutes, and then perform water-cooled in...

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Abstract

The invention provides a high-strength sulfur-oxygen nucleating agent. The high-strength sulfur-oxygen nucleating agent comprises the following elements in percentages by mass: 70-76% of Si, 0.2-1.0%of Ca, 0.3-0.5% of Ba, 1.5-2.0% of La, 0.5-1.5% of Al, 0.3-0.9% of S, 0.3-0.9% of O, 0.5-1.5% of Sb and the balance of iron. The sulfur-oxygen nucleating agent is prepared from the following raw materials in parts by weight: 2-4 parts of steel scrap, 130-140 parts of silicon iron, 1-1.4 parts of silicon barium, 1-1.8 parts of calcium silicon, 2-4 parts of pure lanthanum, 1.5-2.5 parts of stibonium, 1-2 parts of FeS and 1-1.4 parts of FeO. By the prepared high-strength sulfur-oxygen nucleating agent, the number of graphite nodules in nodular cast iron can be increased obviously, the strength and toughness of the nodular cast iron can be improved, the chilling tendency of the nodular cast iron is relieved obviously, the nodularity, the number of graphite nodules and the number of ferrites ofthe nodular cast iron are increased, shrinkage in a casting process is eliminated, and complicated castings with excellent quality can be formed.

Description

technical field [0001] The invention relates to the field of cast iron, in particular to a high-strength sulfur-oxygen inoculant. Background technique [0002] The inoculant can promote graphitization, reduce the whitening tendency, improve the morphology and distribution of graphite, increase the number of eutectic groups, and refine the matrix structure. In the casting process of ductile iron, the selection of inoculant is particularly important. At present, the most used inoculant is ferrosilicon, which also contains metal elements such as calcium, barium, strontium, manganese and zirconium. The above-mentioned elements that are reactive with sulfur and oxygen are added to combine with sulfur and oxygen in iron. Provides an efficient heterogeneous crystalline core for graphite. However, the effective sulfur and oxygen in molten iron after spheroidization are greatly reduced, so the effect of adding elements in the inoculant is also limited, and the number of effective cr...

Claims

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Application Information

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IPC IPC(8): C22C33/08C21C1/10C22C33/10C22C37/04C22C37/10
CPCC21C1/10C22C33/08C22C33/10C22C37/04C22C37/10
Inventor 闫启栋李建锋马宗阳朱晓朋
Owner YUZHOU HENGLILAI ALLOY CO LTD
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