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A kind of polyethersulfone wear-resistant and antifouling coating

A technology of polyethersulfone and coatings, which is applied in the direction of antifouling/underwater coatings, coatings, paints containing biocide, etc., and can solve the problems of low surface energy weather resistance, heat resistance, chemical stability, poor wear resistance, polymerization problems such as high surface tension

Active Publication Date: 2019-09-20
FOSHAN POLIMA ADVANCED TECH & SUPPLIES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] Polyethersulfone has the characteristics of easy availability of raw materials and low cost, but the surface tension of the polymer is large, and it has low surface energy, good hydrophobicity and oil repellency, weather resistance, heat resistance, chemical stability, etc., but its wear resistance poor

Method used

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  • A kind of polyethersulfone wear-resistant and antifouling coating
  • A kind of polyethersulfone wear-resistant and antifouling coating
  • A kind of polyethersulfone wear-resistant and antifouling coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0080] (1) In the reaction vessel, add compound 1 (300mmol) and concentrated sulfuric acid (300ml), stir, add NBS (1mol) in batches, and react in the dark until the end of the reaction, slowly pour the reactant into ice water, and filter with suction , and the filter residue was washed successively with aqueous sodium bicarbonate solution, water and methanol. After the filter residue was dried, it was recrystallized with DMSO to obtain compound 2 as a yellow solid, yield: 15%. 1 HNMR(DMSO): δ7.71(d, J=6.0Hz, 1H), 7.36-7.38(m, 5H), 7.29(d, J=6.0Hz, 1H), 5.84(s, 1H).

[0081]

[0082] (2) In the reaction vessel, add compound 2 (100mmol), add 200mL ethanol to dissolve it, dissolve (200mmol) sodium borohydride in 20mL ethanol solution under stirring, add it dropwise to the reaction flask under ice bath, drop for 60min Finish. React at room temperature until the reaction is complete, filter, wash the solid with water 3 times, dissolve the filter cake with the water used to was...

Embodiment 2

[0102]

[0103] m w =2.1×10 6 ,M n =3.6×10 5 , the molecular weight distribution coefficient is 5.8

[0104] 1 HNMR (DMSO):

[0105] 1 HNMR(DMSO): δ8.74(d, J=7.2Hz, 2H), 8.06(d, J=7.2Hz, 2H), 7.76(d, J=7.2Hz, 1H), 7.65(d, J=7.2 Hz, 1H), 7.29-7.40(m, 5H), 7.12(d, J=6.4Hz, 1H), 6.88(d, J=6.4Hz, 1H), 6.29(s, 1H), 2.51-2.60(m , 4H), 1.53-1.61(m, 4H), 1.30-1.25(m, 12H), 0.85-0.90(m, 6H).

Embodiment 3

[0107]

[0108] m w =3.0×10 6 ,M n =4.1×10 5 , the molecular weight distribution coefficient is 7.3

[0109] 1 HNMR(DMSO): δ8.76(d, J=7.2Hz, 2H), 8.09(d, J=7.2Hz, 2H), 7.61(d, J=7.2Hz, 2H), 7.23-7.40(m, 6H ), 7.12-7.18(m, 4H), 6.86(d, J=6.4Hz, 1H), 6.25(s, 1H), 2.51-2.60(m, 4H), 1.52-1.61(m, 4H), 1.35- 1.28(m, 14H), 0.85-0.91(m, 6H).

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Abstract

The invention relates to a novel polyether sulfone wear-resistant anti-fouling coating. The anti-fouling coating includes a component A and polyether sulfone B, wherein the component A is shown in thedescription, and the polyether sulfone B is shown in the description. The wear-resistant anti-fouling coating provided by the invention has good anti-fouling performance and good wear resistant properties at the same time.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular, the invention relates to a novel polyethersulfone wear-resistant and antifouling coating and its synthesis method as well as the industrial application of the resin. Background technique [0002] High-performance engineering plastics are a large category of special engineering plastics. In a broad sense, high-performance engineering plastic resins include polyarylethersulfone, polyaryletherketone, polyarylethersulfoneketone, polyetherphthalimide, etc. Its structural feature is that the main chain hardly contains aliphatic groups, but is formed by connecting benzene rings, naphthalene rings, and nitrogen heterocycles through ether groups, sulfone groups, and carbonyl groups. This structural feature makes this type of high Molecular materials have a series of excellent comprehensive properties such as high heat resistance, good thermal stability, strong mechanical properties, and goo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D165/00C09D181/06C09D5/16
Inventor 梁文波曾志玲
Owner FOSHAN POLIMA ADVANCED TECH & SUPPLIES CO LTD
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