A kind of drilling fluid treatment agent and its preparation method and drilling fluid
A technology of drilling fluid treatment agent and compound, which is applied in the field of drilling to achieve good inhibition performance, simple operation steps and high product yield
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[0038] The invention provides a kind of preparation method of drilling fluid treatment agent, comprises the following steps:
[0039] (1) reacting chitosan, water, alkaline compound and alcohol compound to obtain the first intermediate product;
[0040] (2) reacting the first intermediate product with chlorocarboxylic acid to obtain the second intermediate product;
[0041] (3) reacting the second intermediate product, protonic acid and 2,3-epoxypropyltrialkylammonium chloride to obtain the drilling fluid treatment agent;
[0042] In the step (1) of the present invention, the chitosan is subjected to alkaline and gelatinization reactions under the action of the basic compound and the alcohol compound to activate the chitosan, which is beneficial to the modification of the chitosan in the subsequent process. In the present invention, the reaction temperature in the step (1) is preferably 50-80°C, more preferably 55-75°C, most preferably 60-70°C. In the present invention, the ...
Embodiment 1
[0098] By weight, 16 parts of chitosan (number average molecular weight is 200000), 150 parts of water, 20 parts of sodium hydroxide and 40 parts of methanol are stirred and mixed uniformly, and the reaction is carried out at 50 ° C for 0.5 hour to obtain the first Intermediate product; the first intermediate product and 24 parts of chloroacetic acid were stirred and reacted at 55°C for 2 hours to obtain the second intermediate product; after adding 2 parts of sulfamic acid to the second intermediate product to dissolve completely, add 15 parts Parts of 2,3-epoxypropyltrimethylammonium chloride were reacted at 60°C for 2 hours to obtain a reddish-brown viscous liquid; the pH value of the above liquid was adjusted to be neutral, and the solid was obtained by filtration, and 20 parts of methanol After washing the solid, suction filter, then wash the solid with 40 parts of propanol, and finally wash the solid with 100 parts of water, filter with suction, and dry to obtain a drilli...
Embodiment 2
[0101] By weight, 16 parts of chitosan (the number average molecular weight is 240000), 170 parts of water, 25 parts of sodium carbonate and 45 parts of ethanol are mixed uniformly, and the reaction is carried out at 60 ° C for 1 hour to obtain the first intermediate product; the first intermediate product and 30 parts of chloropropionic acid were stirred and reacted at 60°C for 2.5 hours to obtain the second intermediate product; after adding 3 parts of p-toluenesulfonic acid to the second intermediate product to completely dissolve, then add 18 parts of 2,3-epoxypropyltriethylammonium chloride were reacted at 70°C for 2.5 hours to obtain a reddish-brown viscous liquid; the pH value of the above liquid was adjusted to neutral, and the solid was obtained by filtration; the The solid was washed with 25 parts of methanol and then suction-filtered, then washed with 50 parts of isopropanol and then suction-filtered, and finally washed with 120 parts of water and dried by suction-fi...
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