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Negative electrode active material used for lead carbon battery and preparation method of negative electrode active material

A negative active material and lead-carbon battery technology, applied in battery electrodes, lead-acid batteries, circuits, etc., can solve problems such as increased plate resistance, reduced battery capacity, failure, etc., to reduce weight, increase energy density, improve The effect of production efficiency

Inactive Publication Date: 2018-05-04
JIANGSU HUAFU STORAGE NEW TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Under the conditions of high-rate charge and discharge of traditional lead-acid batteries, especially under the conditions of high-rate charge-discharge in partial state of charge (HRPSoC), the negative electrode active material is easy to form larger lead sulfate crystals, resulting in a larger plate resistance. Battery capacity decreases and eventually fails

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] First, carbon materials were prepared in proportions of 15.0 parts of flying graphite, 25.0 parts of porous carbon particles, 25.0 parts of activated carbon, 5.0 parts of conductive graphite, 10.0 parts of carbon black, and 20.0 parts of acetylene black;

[0026] Secondly, put all the carbon materials into the container, stir evenly and set aside;

[0027] Thirdly, the negative electrode active material is prepared by mixing 60.0% of lead oxide powder, 5.0% of mixed carbon material, 8.0% of sulfuric acid, 1.0% of additive, and 26.0% of deionized water.

[0028] Among them, the density of sulfuric acid is 1.2g / cm 3 . The additive is lignin. Activated carbon is a high specific surface area activated carbon.

[0029] The negative electrode active material can be coated on the negative electrode grid to prepare the negative electrode plate used in the production of lead-carbon batteries.

Embodiment 2

[0031] First, carbon materials were prepared in proportions of 0.1 parts of flying graphite, 30.0 parts of porous carbon particles, 40.0 parts of activated carbon, 15.0 parts of conductive graphite, 9.9 parts of carbon black, and 15.0 parts of acetylene black;

[0032] Secondly, put all the carbon materials into the container, stir evenly and set aside;

[0033] Thirdly, the negative electrode active material is prepared by mixing 65.0% of carbon material, 6.0% of sulfuric acid, 5.0% of additive, and 24.0% of deionized water.

[0034] Among them, the density of sulfuric acid is 1.4g / cm 3 . The additive is sodium lignosulfonate. Activated carbon is a high specific surface area activated carbon.

[0035] The negative electrode active material can be coated on the negative electrode grid to prepare the negative electrode plate used in the production of lead-carbon batteries.

Embodiment 3

[0037] First, carbon materials were prepared in proportions of 12.0 parts of flying graphite, 24.0 parts of porous carbon particles, 24.0 parts of activated carbon, 7.0 parts of conductive graphite, 20.0 parts of carbon black, and 13.0 parts of acetylene black;

[0038] Secondly, put all the carbon materials into the container, stir evenly and set aside;

[0039] Thirdly, the negative electrode active material is prepared by mixing 55.0% of lead oxide powder, 10.0% of mixed carbon material, 7.0% of sulfuric acid, 3.0% of additive, and 25.0% of deionized water.

[0040] Among them, the density of sulfuric acid is 1.6g / cm 3 . The additive is a mixture of lignin and sodium lignosulfonate, wherein the weight ratio of lignin and sodium lignosulfonate is 1:1. Activated carbon is a high specific surface area activated carbon.

[0041] The negative electrode active material can be coated on the negative electrode grid to prepare the negative electrode plate used in the production o...

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Abstract

The invention discloses a negative electrode active material used for a lead carbon battery. The negative electrode active material comprises the following components based on weight percentages: 0-60% of lead oxide powder, 5-65% of carbon material, 6-8% of sulfuric acid, 1-5% of additive and the balance of deionized water. The invention also discloses a preparation method of the negative electrode active material used for the lead carbon battery. By virtue of the negative electrode active material used for the lead carbon battery, the weight of the storage battery can be reduced effectively,and the energy density of the battery can be improved; in addition, the storage battery has high high-current charging-discharging performance and partial state-of-charge high-rate charging-discharging (HRPSoC) performance; and meanwhile, the preparation method of the negative electrode active material is convenient to implement and can be widely applied to production of the lead carbon battery.

Description

technical field [0001] The invention belongs to the field of materials related to chemical power sources, and relates to a negative electrode active material for a lead-carbon battery and a preparation method thereof. Background technique [0002] Due to the outstanding charge and discharge performance of the lead-carbon battery itself, its application in the field of new energy storage and power continues to expand. Under the conditions of high-rate charge and discharge of traditional lead-acid batteries, especially under the conditions of high-rate charge-discharge in partial state of charge (HRPSoC), the negative electrode active material is easy to form larger lead sulfate crystals, resulting in increased plate resistance. The battery capacity decreases and eventually fails. In recent years, research institutions and researchers in the field of lead-acid batteries have maintained a high enthusiasm for the research and development of negative electrode materials. For ex...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/56H01M4/583H01M4/62H01M10/06
CPCH01M4/364H01M4/56H01M4/583H01M4/62H01M10/06Y02E60/10
Inventor 吴战宇周寿斌汪的华彭创顾立贞董志成王兴锋李一平马广磊于尊奎
Owner JIANGSU HUAFU STORAGE NEW TECH DEV