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Catalytic cracking oil slurry solid-removing agent and preparation method thereof

A technology for catalytic cracking oil slurry and catalyst, which is applied in the petroleum industry, refining hydrocarbon oil, etc., can solve the problems of the adverse effect of the deep utilization of oil slurry, affecting the quality of oil slurry, affecting the removal efficiency, etc., to promote coalescence, fast speed , the effect of less dosage

Active Publication Date: 2018-05-29
CNOOC TIANJIN CHEM RES & DESIGN INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, due to the use of water-soluble agents in the above methods, and the catalyst powder is in the oil phase, the effect of this type of catalyst powder removal is heterogeneous, and the catalyst powder needs to undergo a removal process from the oil phase to the water phase. , will inevitably affect the removal efficiency; on the other hand, the above methods also need to add a water phase to the catalytic cracking oil slurry. Although a demulsifier is used for oil-water separation, it will definitely leave moisture in the oil slurry, thus affecting the oil slurry. quality; the last point, most of the flocculants used in the above methods contain metal ions (polyaluminum chloride, etc.), and residues in the oil slurry will also have an adverse effect on the deep utilization of the oil slurry (such as increasing the ash value, making the catalyst poisoning, etc.)

Method used

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  • Catalytic cracking oil slurry solid-removing agent and preparation method thereof
  • Catalytic cracking oil slurry solid-removing agent and preparation method thereof
  • Catalytic cracking oil slurry solid-removing agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Embodiment 1: the preparation of oil slurry desolidifying agent A

[0028] (1) Preparation of solid release agent main agent:

[0029] a. In a 250mL four-neck flask equipped with a thermometer, water separator and reflux condenser, add 20g of polyoxyethylene polyoxypropylene block copolymer (molecular weight about 2000), 2g of maleic anhydride (polyoxyethylene polyoxypropylene The molar ratio of block copolymer to maleic anhydride is 1:2), 0.3g p-toluenesulfonic acid (p-toluenesulfonic acid accounts for 1.5% of the total mass of the reactant) and 150mL toluene, and the temperature is raised to 140°C for reaction. The water output in the water separator judges the progress of the reaction, the total reaction time is 6 hours, and polyoxyethylene polyoxypropylene ether maleate is obtained.

[0030] b. In a 250mL four-necked flask equipped with a thermometer, a water separator and a reflux condenser, add 20g of polytetrahydrofuran (molecular weight is about 2000), 2g of ma...

Embodiment 2

[0034] Embodiment 2: the preparation of oil slurry desolidifying agent B

[0035] (1) Preparation of solid release agent main agent:

[0036] a. In a 250mL four-neck flask equipped with a thermometer, water separator and reflux condenser, add 20g of polyoxyethylene polyoxypropylene block copolymer (molecular weight about 2000), 1g of maleic anhydride (polyoxyethylene polyoxypropylene The molar ratio of block copolymer to maleic anhydride is 1:1), 0.2g p-toluenesulfonic acid (p-toluenesulfonic acid accounts for 1% of the total mass of the reactant) and 150mL toluene, and the temperature is raised to 130°C for reaction. The water output in the water separator judges the progress of the reaction, the total reaction time is 4 hours, and polyoxyethylene polyoxypropylene ether maleate is obtained.

[0037] b. In a 250mL four-necked flask equipped with a thermometer, a water separator and a reflux condenser, add 20g of polytetrahydrofuran (molecular weight is about 2000), 1g of male...

Embodiment 3

[0041] Embodiment 3: the preparation of oil slurry desolidification agent C

[0042] (1) Preparation of solid release agent main agent:

[0043] a. In a 250mL four-necked flask equipped with a thermometer, water separator and reflux condenser, add 20g of polyoxyethylene polyoxypropylene block copolymer (molecular weight about 2000), 3g of maleic anhydride (polyoxyethylene polyoxypropylene The molar ratio of block copolymer to maleic anhydride is 1:3), 0.5g p-toluenesulfonic acid (p-toluenesulfonic acid accounts for 2% of the total mass of the reactant) and 150mL toluene, and the temperature is raised to 160°C for reaction. The water output in the water separator judges the progress of the reaction, the total reaction time is 8 hours, and polyoxyethylene polyoxypropylene ether maleate is obtained.

[0044] b. In a 250mL four-necked flask equipped with a thermometer, a water separator and a reflux condenser, add 20g of polytetrahydrofuran (molecular weight is about 2000), 3g of...

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Abstract

The invention relates to a catalytic cracking oil slurry solid-removing agent and a preparation method thereof. The catalytic cracking oil slurry solid-removing agent comprises the following components in percentage by weight: 30-50% of a solid-removing main agent adopting a structural formula (I), 5-10% of a gel breaker, 5-10% of a synergist and 30-50% of a solvent. The catalytic cracking oil slurry solid-removing agent is an oil-soluble product, so that the catalytic cracking oil slurry solid-removing agent can directly act on an oil phase; the catalytic cracking oil slurry solid-removing agent is low in using amount, quick in action and simple in method; the catalytic cracking oil slurry solid-removing agent can efficiently remove catalyst powder from a catalytic cracking oil slurry, sothat significant economic benefits are increased for an oil refining enterprise.

Description

Technical field: [0001] The invention relates to the technical field of petroleum refining and processing, and more specifically relates to a desolidifying agent for catalytic cracking oil slurry and a preparation method thereof. Background technique: [0002] Catalytic cracking oil slurry is a heavy oil product from the bottom of the main fractionation tower of the refinery's fluid catalytic cracking (FCC) unit. It is rich in colloids and asphaltenes, and has the characteristics of high viscosity and high density. FCC oil slurry usually contains a certain amount of solid catalyst powder with a relatively high ash content, generally 0.2-0.9 wt%. These catalyst powders will affect the quality of downstream products. For example, when used as carbon black and needle coke raw materials, the ash content must be <0.05wt%, and high-grade products must be <0.02wt%. In addition, when the oil slurry with high catalyst powder content is used as a fuel oil component, it will acc...

Claims

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Application Information

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IPC IPC(8): C10G29/20
CPCC10G29/20
Inventor 丁秋炜王艺林王素芳于晓微李志元滕厚开
Owner CNOOC TIANJIN CHEM RES & DESIGN INST