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Carbon cage-iron microelectrolytic particles for acidic sewage treatment and preparation method

A technology of acidic sewage and micro-electrolysis, applied in water/sewage treatment, water/sludge/sewage treatment, special treatment targets, etc. Solve the effects of easy hardening and passivation, good micro-electrolysis performance and low preparation cost

Inactive Publication Date: 2018-06-22
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] It can be seen that in the iron-carbon micro-electrolysis technology in the prior art, iron-carbon materials are prone to agglomeration of iron filings and surface passivation, and are prone to problems such as scaling, clogging, and inability to operate continuously. There is poor micro-electrolysis activity and cannot be efficiently processed. Disadvantages such as sewage

Method used

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  • Carbon cage-iron microelectrolytic particles for acidic sewage treatment and preparation method
  • Carbon cage-iron microelectrolytic particles for acidic sewage treatment and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Heat 36kg of carbonyl iron powder, 1kg of stearic acid and 63kg of glyceryl tristearate to 85°C, stir and mix for 18 minutes to form an iron powder dispersion, then spray and condense to form an average particle size fixed by stearic acid. 300μm iron powder agglomerated microspheres; add 10kg of nano-silica powder, 35kg of chitosan, and 1kg of glutaraldehyde into 54kg of deionized water, and stir at 68°C for 50 minutes to obtain a silica-chitosan composite gel; Finally, add 40kg of iron powder agglomerated microspheres into 60kg of silica-chitosan composite gel, so that the surface of the microspheres is uniformly coated with the composite gel, and then heated to 500°C in a high-temperature furnace for carbonization for 75 minutes to form a firm microporous cage , the iron powder is networked in the cage, and the micro-electrolytic particles of the iron powder networked by the carbon cage are prepared.

[0033] testing method:

[0034] After sieving the prepared electr...

Embodiment 2

[0037]Heat 32kg of carbonyl iron powder, 1kg of stearic acid and 67kg of vinyl bisstearamide to 80°C, stir and mix for 20 minutes to form an iron powder dispersion, then spray and condense to form an average particle size fixed by stearic acid. 200μm iron powder agglomerated microspheres; 8kg nano-silica powder, 30kg chitosan, and 1kg formaldehyde were added to 61kg deionized water, and stirred at 60°C for 60min to obtain a silica-chitosan composite gel; finally Add 35kg of iron powder agglomerated microspheres to 65kg of silica-chitosan composite gel, so that the surface of the microspheres is uniformly coated with the composite gel, and then heated to 400°C in a high-temperature furnace for 90 minutes of carbonization to form a firm microporous cage. The powder is networked in the cage to make micro-electrolytic particles of iron powder networked by carbon cages.

[0038] The test method is consistent with Example 1, and the obtained data are shown in Table 2.

Embodiment 3

[0040] Heat 40kg of carbonyl iron powder, 2kg of stearic acid and 58kg of stearic acid monoglyceride to 90°C, stir and mix for 15 minutes to form an iron powder dispersion, then spray and condense to form an average particle size fixed by stearic acid. 400μm iron powder agglomerated microspheres; add 12kg nano-silica powder, 40kg chitosan, 2kg methylenebisacrylamide into 46kg deionized water, stir at 75°C for 40min to prepare silica-chitosan composite Gel; finally, add 45kg of iron powder agglomerated microspheres into 55kg of silica-chitosan composite gel, so that the surface of the microspheres is evenly covered with the composite gel, and then heated to 600°C in a high-temperature furnace to carbonize for 60 minutes to form a firm gel. Microporous cage, iron powder is networked in the cage, and micro-electrolytic particles made of iron powder networked by carbon cage.

[0041] The test method is consistent with Example 1, and the obtained data are shown in Table 2.

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Abstract

The invention belongs to the technical field of sewage treatment and provides carbon cage-iron microelectrolytic particles for acidic sewage treatment and a preparation method. The method comprises steps as follows: an iron powder dispersion liquid is prepared for mist spray and condensation, iron powder agglomerated microspheres immobilized by stearic acid are prepared, then silica-chitosan composite gel is prepared, the microspheres are uniformly coated with the composite gel and then subjected to high-temperature carbonization, firm microporous cages are formed, iron powder is covered withthe cages, and the microelectrolytic particles with the iron powder covered with the carbon cages are obtained. Compared with a traditional method, the prepared carbon cage-iron microelectrolytic particles not only have good microelectrolysis performance, but also can effectively prevent the iron powder from hardening, the problem that an iron-carbon micro-electrolysis material is prone to hardening and passivating when applied to sewage treatment is solved thoroughly, the purposes of preventing scaling and blockage, realizing continuous operation and efficiently treating acidic sewage can beachieved effectively, meanwhile, the preparation process is simpler, the preparation cost is lower, and the carbon cage-iron microelectrolytic particles can be popularized for production and application.

Description

technical field [0001] The invention belongs to the technical field of sewage treatment, and provides a carbon cage-iron micro-electrolytic particle for acid sewage treatment and a preparation method. Background technique [0002] With the development of social economy, there are more and more industrial waste water and domestic sewage, which seriously pollute the water body, destroy the ecological environment, and threaten human health and survival. In order to make the sewage meet the discharge standard, people have developed a variety of treatment methods. Sewage usually includes industrial wastewater and domestic wastewater. Industrial wastewater has become the focus of social attention due to its high concentration of organic matter, high toxicity, complex components, and difficult treatment. If the direct discharge will pose a serious threat to the environment, it is necessary to choose an appropriate method for treatment to meet the emission standards. [0003] The c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/461
CPCC02F1/461C02F2303/22
Inventor 陈庆曾军堂
Owner CHENDU NEW KELI CHEM SCI CO LTD
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