Multi-ingredient oxide enhanced silver-based electric contact material and preparation method thereof

An electrical contact material, oxide technology, applied in the direction of contacts, circuits, electrical switches, etc., can solve the problems of weak arc erosion resistance, few types of oxides, short electrical life, etc., to achieve good arc erosion resistance, oxidation resistance, etc. The effect of fine particle size and long electrical life

Inactive Publication Date: 2018-06-29
KUNMING INST OF PRECIOUS METALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Commonly used at home and abroad single or two oxide reinforced silver-based electrical contact materials (such as AgSnO 2 , AgCuO, AgSnO 2 In 2 o 3 , AgSnO 2 La 2 o 3 etc.) Because of the few types of oxides in the silver matrix and the poor synergistic strengthening effect, the strength of the material is not high, the arc erosion resistance is weak, and the electrical life is short, which limits the promotion of silver-based electrical contact materials in many fields and harsh service conditions application

Method used

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  • Multi-ingredient oxide enhanced silver-based electric contact material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0013] 1. According to the ratio of 8Sn, 3In, 1.5La, 0.5Bi, 0.3Sm, and the balance is Ag, the metal raw materials are weighed and put into a zirconia crucible for vacuum induction melting and casting to obtain an alloy ingot. Before induction melting, the melting chamber Vacuum until the vacuum degree is greater than 10 -2 Pa;

[0014] 2. The alloy ingot is turned into a billet with a diameter of 50mm;

[0015] 3. Put the alloy ingot into a special internal oxidation furnace for pressurized internal oxidation. The oxidation temperature of the pressurized internal oxidation is 800°C, the oxidation time is 28h, and the oxygen partial pressure is 6MPa to obtain multi-component oxide reinforced silver-based electrical contact materials;

[0016] 4. The multi-component oxide-reinforced silver-based electrical contact material is hot-extruded, the hot-extrusion temperature is 800°C, the extrusion ratio is 150, and then drawn at room temperature to form a multi-component oxide rein...

Embodiment 2

[0018] 1. According to the weight percentage of 6Sn, 4In, 0.5Bi, 1.3Zn, 0.2Hf, and the balance is Ag, the metal raw materials are weighed and put into a zirconia crucible for vacuum induction melting and casting to obtain an alloy ingot. Before induction melting, the melting chamber Vacuum until the vacuum degree is greater than 10 -2 Pa;

[0019] 2. The alloy ingot is turned into a billet with a diameter of 85mm;

[0020] 3. Put the alloy ingot into a special internal oxidation furnace for pressurized internal oxidation. The oxidation temperature of the pressurized internal oxidation is 820°C, the oxidation time is 28h, and the oxygen partial pressure is 8MPa to obtain multi-component oxide reinforced silver-based electrical contact materials;

[0021] 4. The multi-component oxide-reinforced silver-based electrical contact material is hot-extruded, the hot-extrusion temperature is 840°C, the extrusion ratio is 120, and then drawn at room temperature to form a multi-componen...

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Abstract

The invention discloses a multi-ingredient oxide enhanced silver-based electric contact material and a preparation method thereof. The material is prepared from the following chemical ingredients in percentage by mass: 6 to 10 percent of Sn, 2 to 6 percent of In,0 to 5 percent of La, 0 to 5 percent of Bi, 0 to 3 percent of Zn, 0 to 3 percent of Sm, 0 to 3 percent of Hf and the balance of Ag. The method comprises the following process steps of proportionally weighing metal with the ingredient proportion; putting the metal into a zirconium oxide crucible; performing vacuum sensing melting and casting to obtain an alloy ingot blank; performing turning processing on the alloy ingot blank to obtain a rod blank; putting the rod blank into a special inner oxidization furnace for pressurization inner oxidization to obtain the multi-ingredient oxide enhanced silver-based electric contact material; performing heat extrusion, room temperature pulling processing to obtain the multi-ingredient oxide enhanced silver-based electric contact material. The multi-ingredient oxide enhanced silver-based electric contact material prepared by using the method has the advantages that the pulling resistantintensity reaches 280 to 340 MPa; the electric life reaches 150 thousand times under the test conditions of AC / 220V / 15A.

Description

technical field [0001] The invention relates to a silver-based electrical contact material, in particular to a pressurized internal oxidation preparation method of a multi-component oxide reinforced silver-based electrical contact material. Background technique [0002] The oxide-reinforced silver-based electrical contact material is a metal-based composite material in which the second-phase oxide particles are dispersed in the silver matrix. It is a kind of electrical contact material for low-voltage electrical appliances that has developed rapidly in recent years. Commonly used at home and abroad single or two oxide reinforced silver-based electrical contact materials (such as AgSnO 2 , AgCuO, AgSnO 2 In 2 o 3 , AgSnO 2 La 2 o 3 etc.) Because of the few types of oxides in the silver matrix and the poor synergistic strengthening effect, the strength of the material is not high, the arc erosion resistance is weak, and the electrical life is short, which limits the prom...

Claims

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Application Information

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IPC IPC(8): C22C1/10C22C1/02C22C5/06C22C32/00H01H1/0237
CPCC22C1/1078C22C1/02C22C5/06C22C32/001H01H1/0237
Inventor 王松张吉明陈永泰谢明王塞北李爱坤胡洁琼
Owner KUNMING INST OF PRECIOUS METALS
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