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Method for removing sulfur dioxide in flue gas and used sulfur-dioxide absorbent

A sulfur dioxide and absorbent technology, applied in chemical instruments and methods, separation methods, dispersed particle separation, etc., can solve the problems of sulfur dioxide pollution, high flue gas temperature, limited space, etc., to achieve low investment and operating costs, wide temperature, Small footprint effect

Inactive Publication Date: 2018-07-13
江苏天诺环境工程技术开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for small-scale enterprises or small-scale flue gas, such as small industrial boilers, calciners or kilns, on the one hand, the space is limited, on the other hand, funds for environmental protection are insufficient, and there is no heat recovery facility resulting in high flue gas temperature, so it is impossible to Use the above four calcium-based desulfurization technologies and other non-calcium-based wet desulfurization technologies to solve the problem of sulfur dioxide pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A method for removing sulfur dioxide in flue gas, comprising the following steps:

[0023] Step 1, deployment of sulfur dioxide absorbent. Mix clay, hard asphalt with a needle penetration of less than 50 at 25°C, and water at a mass ratio of 5:15:28 at room temperature to make a slurry forming agent; in terms of mass percentage, mix 75% quicklime and 25% of the paste forming agent was mixed to obtain a mixture.

[0024] Step 2, molding the sulfur dioxide absorbent. Pour the mixture into a mold for shape forming, which can be spherical, columnar, irregular solid, honeycomb, plate-and-frame, etc., and then put the mold containing the mixture into a high-temperature box for anaerobic molding at 450°C , The molding time is 60 minutes, the hard asphalt decomposes at high temperature to form a solid, porous structure of sulfur dioxide absorbent.

[0025] Step 3, place the sulfur dioxide absorbent. Put the formed sulfur dioxide absorbent in the movable body, which can be d...

Embodiment 2

[0029] A method for removing sulfur dioxide in flue gas, comprising the following steps:

[0030] Step 1, deployment of sulfur dioxide absorbent. Mix diatomite, rock asphalt, and water at room temperature in a mass ratio of 5:10:18 to make a slurry forming agent; in terms of mass percentage, mix 50% of limestone and slaked lime, and 50% of slurry The shape forming agent is mixed to obtain a mixture.

[0031] Step 2, molding the sulfur dioxide absorbent. Pour the mixture into a mold for shape forming, which can be spherical, columnar, irregular solid, honeycomb, plate-frame, etc., and then put the mold containing the mixture into a high-temperature box for anaerobic molding at 410°C , Molding time 60min, rock asphalt decomposes at high temperature, forming a solid, porous structure of sulfur dioxide absorbent.

[0032] Step 3, place the sulfur dioxide absorbent. Put the formed sulfur dioxide absorbent in the movable body, which can be drawer type or plug-in type, with airfl...

Embodiment 3

[0036] A method for removing sulfur dioxide in flue gas, comprising the following steps:

[0037] Step 1, deployment of sulfur dioxide absorbent. Mix kaolin, lake asphalt, and water at normal temperature in a mass ratio of 8:15:25 to make a slurry forming agent; in terms of mass percentage, add 75% quicklime and 25% slurry forming agent Mix to obtain a mixture.

[0038] Step 2, molding the sulfur dioxide absorbent. Pour the mixture into a mold for shape forming, which can be spherical, columnar, irregular solid, honeycomb, plate-and-frame, etc., and then put the mold containing the mixture into a high-temperature box for anaerobic molding at 480°C , The molding time is 60 minutes, the lake asphalt decomposes at high temperature to form a solid, porous structure of sulfur dioxide absorbent.

[0039] Step 3, place the sulfur dioxide absorbent. Put the formed sulfur dioxide absorbent in the movable body, which can be drawer type or plug-in type, with airflow channels, and then ...

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PUM

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Abstract

The invention discloses a method for removing sulfur dioxide in flue gas. The method comprises the following steps: a solid sulfur-dioxide absorbent is arranged at a circulation area from a reactor outlet to a flue inlet in a covering manner; flue-gas flow in a reactor is discharged by a flue after passing through the sulfur-dioxide absorbent, and when the discharge of the flue gas is not up to the standard, the sulfur-dioxide absorbent is updated, wherein the sulfur-dioxide absorbent is prepared by mixing 50-80% of powdery calcium-containing substance and the balance of pasty forming agent inpercent by mass and carrying out high-temperature forming; the pasty forming agent is prepared by mixing an adhesive, granular asphalt and water according to the mass ratio of (5-10):(10-20):(15-30).The method disclosed by the invention has the beneficial effects that standard discharge of sulfur dioxide can be realized, and water is not needed, so that the problems of waste water treatment andwater-evaporation energy consumption are avoided; dust-removing facilities for collecting desulfurized products are not needed, the applicable flue-gas temperature range is wide, and the method is applicable to flue gas with the temperature being lower than calcium-sulfate decomposition temperature; the setting mode is flexible, the replacement and the operation are convenient, and a desulfurizingsystem is small in area occupation and low in investment and operation cost.

Description

technical field [0001] The invention relates to flue gas treatment, in particular to a method for removing sulfur dioxide in flue gas and a sulfur dioxide absorbent used. Background technique [0002] my country's increasingly serious air pollution and increasingly stringent emission standards have promoted the full implementation of smoke pollution emission control. According to the type of fuel, the flue gas is divided into flue gas such as coal, fuel oil, gas, etc., and according to the combustion equipment and source of flue gas, it is divided into flue gas such as power plant boilers, various industrial boilers, calciners, kilns, etc. So far, the flue gas pollution of power plant boilers has been effectively controlled, but the flue gas pollution of small industrial boilers, calciners, and kilns has not been effectively controlled, especially the sulfur dioxide pollution of small-volume flue gas. [0003] Flue gas desulfurization has been developed for more than 60 yea...

Claims

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Application Information

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IPC IPC(8): B01D53/81B01D53/50
CPCB01D53/81B01D53/50
Inventor 刘清雅郭兆民刘振宇权栋张玉贞
Owner 江苏天诺环境工程技术开发有限公司
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