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Antifouling paint for ocean, and preparation method thereof

A marine antifouling and coating technology, which is applied in the direction of antifouling/underwater coatings, coatings, paints containing biocide, etc., can solve the problems of high preparation cost, poor antifouling durability, and large environmental hazards, and achieves the preparation method Simple, strong antifouling ability, reasonable cost effect

Active Publication Date: 2018-07-27
NANTONG GAOMENG NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the above problems, the present invention provides a marine antifouling coating and a preparation method thereof, which overcomes the disadvantages of existing ship antifouling coatings such as high preparation cost, great harm to the environment, and poor antifouling durability, and provides a brand-new environment-friendly coating. , Marine antifouling coating with strong antifouling ability

Method used

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  • Antifouling paint for ocean, and preparation method thereof

Examples

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Embodiment 1

[0029] Preparation of 500g one-component acrylic resin marine antifouling coatings containing capsaicin derivatives: weigh the components as follows: 250g acrylic resins containing eugenol capsaicin derivatives, 25g iron oxide red, 25g BYK-P104, 10g Fumed silica, 30g combined antifouling agent, 60g xylene, 100g butyl acetate.

[0030] Preparation process: fully disperse 10g of fumed silica, 25g of iron oxide red, and 25g of BYK-P104 on a high-speed coating disperser (1500 / min) for no less than 30min, and grind until the particle size is less than 50μm to obtain a solid mixture; The ground solid dispersion was added to the mixed liquid containing eugenol capsaicin derivative acrylic resin 250g, combined antifouling agent 30g (A component 6g, B component 24g), xylene 30g and butyl acetate 50g, and then Stir the mixture evenly under high-shear (1500 / min) stirring, and add the remaining xylene and 80 g of butyl acetate at the same time to adjust the viscosity to 60 s.

Embodiment 2

[0032] Preparation of 1kg single-component acrylic resin marine antifouling paint containing capsaicin derivatives: weigh the components as follows: 400g acrylic resin containing eugenol capsaicin derivatives, 100g iron oxide red, 50g zeolite, 50g BYK- 163. 80g combined antifouling agent, 170g n-butanol, 150g butyl acetate.

[0033] Preparation process: fully disperse 50g of zeolite, 100g of iron oxide red, and 50g of BYK-163 on a high-speed paint disperser (1500 / min) for no less than 30min, and grind until the particle size is less than 50μm to obtain a solid mixture; grind the above-mentioned The solid dispersion was added to the mixed liquid containing eugenol capsaicin derivative acrylic resin 400g, combined antifouling agent 80g (A component 8g, B component 72g), n-butanol 100g and butyl acetate 50g, and then the mixture Stir evenly under high-shear (1500 / min) stirring, and add the remaining n-butanol and 170g of butyl acetate at the same time, and adjust the viscosity to...

Embodiment 3

[0035] The preparation of the one-component capsaicin derivative acrylic resin marine antifouling coating of 1kg: each component is weighed as follows by formula: 400g contains eugenol capsaicin derivative acrylic resin, 50g iron oxide red, 50g zinc oxide, 50g flow Leveling agent 3033, 80g combined antifouling agent, 170g n-butanol, 200g butyl acetate.

[0036] Preparation process: fully disperse 50g of zinc oxide, 50g of iron oxide red, and 50g of leveling agent 3033 on a high-speed coating disperser (1500 / min) for no less than 30 minutes, and grind until the particle size is less than 50 μm to obtain a solid mixture; grind the above Add the processed solid dispersion into the mixed liquid containing eugenol capsaicin derivative acrylic resin 400g, combined antifouling agent 80g, (A component 20g, B component 60g) n-butanol 60g and butyl acetate 100g, and then Stir the mixture evenly under high-shear (1500 / min) stirring, and add the remaining n-butanol and 210 g of butyl acetat...

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Abstract

The invention discloses an antifouling paint for ocean. The antifouling paint is prepared from the following ingredients in percentage by weight: 30-50% of film forming substrate, 1-10% of combined antifoulant, 2-10% of pigment, 1-5% of filler, 15-40% of solvent and 2-5% of auxiliary agent, wherein the combined antifoulant is prepared from a component A and a component B at a weight ratio of (1 to3) to (1 to 10); the component A is 4-5dichloro-2-octyl-4-isothiazolin-3-one, the component B is capsaicin derivative biocide, and the film forming substrate is acrylic resin containing the capsaicinderivative. The coating does not contain harmful substances, including tin or copper and the like, which have larger environmental harm, and the 4-5dichloro-2-octyl-4-isothiazolin-3-one is taken as the combined antifoulant. The antifouling paint has small pollution, is combined with a sterilization effect of the resin, and has the advantages of efficient and enduring antifouling effect, low antifoulant adding amount and environmental protection. The preparation method has the advantages of simpleness and reasonable cost.

Description

technical field [0001] The invention relates to the technical field of antifouling paint, in particular to a marine antifouling paint and a preparation method thereof. Background technique [0002] Marine pollution refers to the process of attaching and accumulating marine polluting organisms on the surface of artificial facilities immersed in the seabed. Seriously affect the marine industry. Especially marine ship pollution is particularly serious. Marine fouling organisms attach to the bottom of the boat, which will increase navigation resistance, reduce ship speed, increase fuel consumption, and increase pollution emissions. The pollution attached to marine working equipment will reduce the performance of marine working equipment, etc.; serious constraints development of the marine economy. The world's annual economic loss due to marine pollution is about 1.5 billion US dollars. Therefore, marine antifouling is a major scientific research problem. [0003] The tradit...

Claims

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Application Information

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IPC IPC(8): C09D133/08C09D143/04C09D133/24C09D139/06C09D5/16C09D7/61C09D7/63
CPCC08K3/34C08K3/36C08K5/0058C08K5/47C08K13/02C08K2003/2241C08K2003/2272C08K2003/2296C09D5/14C09D5/1625C09D5/1668C09D5/1687C09D143/04
Inventor 张雷冯正朱立新李向东
Owner NANTONG GAOMENG NEW MATERIAL