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A kind of method for making nano silver wire transparent conductive film have the function of eliminating shadow

A transparent conductive film and nano-silver wire technology, applied to conductive layers, circuits, electrical components and other directions on insulating carriers, can solve the problem of inability to completely eliminate etching marks, difficult to control etching yield, and failure to achieve the purpose of erasing and other problems, to achieve the effect of high reliability, improved weather resistance and convenient operation

Active Publication Date: 2019-12-27
合肥微晶材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The vanishing etching of the above four patents all use the half-etching method, and there are still nanometer metal ions in the non-electrode area, and the functional reliability needs to be verified by the market. Excessive etching will lead to the appearance of etching marks, which will not achieve the purpose of erasing; at the same time, the etching paste needs to be screen printed, and the printing accuracy of screen printing is low for fine wire diameters
Patent US 20150362822 A1 proposes a method of using nano-ZnO to coat the surface of the silver wire layer. Through the high light transmittance and low diffuse reflection of nano-ZnO, the light transmittance of the electrode area is improved and the haze of the electrode area is reduced, thereby reducing the electrode area. The contrast between the electrode area and the non-electrode area is used to achieve the purpose of erasing, but this method cannot improve the optical performance of the electrode area to be similar to that of the substrate, so this method can only reduce the contrast, but cannot completely eliminate the etching mark. ;

Method used

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  • A kind of method for making nano silver wire transparent conductive film have the function of eliminating shadow
  • A kind of method for making nano silver wire transparent conductive film have the function of eliminating shadow
  • A kind of method for making nano silver wire transparent conductive film have the function of eliminating shadow

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] (1) Functional layer preparation: 0.4kg polyether polyol HSH360, 0.3kg curing agent Bayhydur 305, 0.4kg water-based nano-zirconia VK-R30W (Xuancheng Jingrui new material, particle size 30nm), 8.8kg water, 0.1kg ten two Sodium alkylbenzene sulfonate is added to the dispersion cylinder in turn, and dispersed for 2 minutes using a planetary gravity disperser to obtain a functional layer slurry; Dry at 100°C for 15 minutes to obtain a functional layer;

[0048] (2) Conductive layer preparation: Nano silver wire (selected from Hefei Microcrystalline Material Technology Co., Ltd., model WJAG1, available in the market), Bayhydrol xp 2470, sodium polyacrylate, water in a mass ratio of 1:2:2:995 The conductive ink is prepared by mixing uniformly, and the ink is coated on the surface of the functional layer by a dimple coating process, and dried in a tunnel oven at 90°C for 20s to form a transparent conductive layer of silver nanowires, that is, to obtain a transparent conducti...

Embodiment 2

[0053] (1) Functional layer preparation: 0.4kg polyether polyol HSH360, 0.3kg curing agent Bayhydur 305, 0.4kg water-based nano-cuprous oxide DK407-1 (Beijing Deke Island gold, particle size 40nm), 8.8kg water, 0.1 kg of sodium dodecylbenzene sulfonate was added to the dispersion tank in turn, and dispersed for 2 minutes using a planetary gravity disperser to obtain a functional layer slurry; The functional layer was obtained by drying in a tunnel furnace at 100°C for 15 minutes;

[0054] (2) Conductive layer preparation: nano-silver wire (selected from Hefei Microcrystalline Material Technology Co., Ltd., model WJAG1, available in the market), Bayhydrol xp 2470, sodium polyacrylate, and water are mixed uniformly in the same ratio as in Example 1 The conductive ink is prepared, and the ink is coated on the surface of the functional layer by a dimple coating process, and dried in a tunnel oven at 90° C. for 20 s to form a transparent conductive layer of silver nanowires, that i...

Embodiment 3

[0057] (1) Functional layer preparation: 0.4kg polyether polyol HSH360, 0.3kg curing agent Bayhydur 305, 0.2kg water-based nano-alumina VK-L20W (Xuancheng Jingrui new material, particle size 20nm), 0.2kg water-based nano-alumina Zirconia VK-R30W (Xuancheng Jingrui new material, particle size 30nm), 8.8kg water, 0.1kg sodium dodecylbenzene sulfonate were added to the dispersion tank in turn, and dispersed for 2 minutes using a planetary gravity disperser to obtain a functional layer Slurry; then use the dimple coating equipment to uniformly coat the slurry on the PET substrate, and dry it in a tunnel oven at 100°C for 15 minutes to obtain a functional layer;

[0058] (2) Conductive layer preparation: nano-silver wire (selected from Hefei Microcrystalline Material Technology Co., Ltd., model WJAG1, available in the market), Bayhydrol xp 2470, sodium polyacrylate, and water are mixed uniformly in the same ratio as in Example 1 The conductive ink is prepared, and the ink is coated...

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Abstract

The invention discloses a method for making a silver nanowire transparent conductive film have a shadow elimination function. The method includes the step of setting a functional layer between a substrate and a silver nanowire transparent conductive layer, wherein the functional layer is obtained by coating a functional layer paste on the surface of the substrate and performing film formation, andthe haze difference between the functional layer and the silver nanowire transparent conductive layer is less than 0.1, so that the purpose of shadow elimination can be achieved. According to the scheme of the invention, through the mode of adding the functional layer between the substrate and the conductive layer, the silver nanowire transparent conductive film can have the shadow elimination function, etching marks on the edges of an electrode region and a non-electrode region completely disappear, and the method is simple and convenient to operate, has the advantages of high yield and highreliability, is suitable for industrial production, and also has universality.

Description

technical field [0001] The invention relates to the field of display, in particular to a method for making a nano-silver wire transparent conductive film have an erasing function, and the nano-silver wire transparent conductive film prepared by the method is particularly suitable for use on optical glass, transparent flexible substrates and solar panels. Background technique [0002] Transparent conductive film is an important optical device in the display field, and ITO transparent conductive film is currently the most widely used. However, the ITO transparent conductive film has disadvantages such as poor bending performance and cannot be used for highly flexible devices, high square resistance cannot prepare large-scale display devices with high sensitivity, and complex vacuum sputtering process for film preparation. Therefore, in recent years, relevant scientific researchers have successively developed nanometer Metal conductive film, carbon nanotube conductive film, gra...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B13/00G06F3/041H01B5/14
CPCG06F3/041H01B5/14H01B13/00
Inventor 张梓晗吕鹏杨锦张运奇聂彪
Owner 合肥微晶材料科技有限公司
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