Method for synthesizing Al-SBA-15 high-efficiency anthraquinone hydrogenation catalyst carrier from FCC waste catalyst
A hydrogenation catalyst, al-sba-15 technology, applied in molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., to achieve excellent catalytic performance, reduce raw material costs, and reduce emissions
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0040] Weigh 3.0g of dried FCC spent catalyst and 3.0g of sodium hydroxide solid into the crucible and stir evenly, then add 1.8mL of deionized water and stir evenly, then place the mixture in a muffle furnace and heat up at 2°C / min Raise the rate from room temperature to 400°C, activate for 2 hours, wait for natural cooling to room temperature, and grind with a mortar to obtain aluminosilicate mixture powder; add 5.0 g of the above powder to 60 mL, 2mol / L hydrochloric acid, and heat Under magnetic stirring for 3 hours, the prehydrolyzed turbid solution was obtained; at the same time, 2.0g of P123 was dissolved in 60mL, 2mol / L hydrochloric acid, and magnetically stirred at 35°C for 3h; then the prehydrolyzed turbid solution was added dropwise to the In the dissolved P123 solution, continue to stir magnetically at 35°C for 24 hours to obtain a light yellow suspension; Water heating at 90°C for 24 hours; then the hydrothermal solution was separated by suction filtration, washed ...
Embodiment 2
[0044] Weigh 3.0g of FCC spent catalyst, 3.6g of sodium hydroxide solid into the crucible and stir evenly, then add 1.8mL of deionized water and stir evenly, then put the mixture in the muffle furnace from room temperature to 2°C / min. Raise to 400°C, activate for 2 hours, wait for natural cooling to room temperature, and grind with a mortar to obtain aluminosilicate mixture powder; Magnetically stirred for 3 hours to obtain the pre-hydrolyzed turbid solution; at the same time, dissolve 2.0g of P123 in 60mL, 2mol / L hydrochloric acid, and magnetically stir at 35°C for 3h; then add the pre-hydrolyzed turbid solution to the dissolved In the P123 solution, continue to stir magnetically at 35°C for 24h to obtain a light yellow suspension; Submerged in water for 24 hours; then the hydrothermal solution was separated by suction filtration, washed with deionized water until neutral, and then the neutral filter cake was dried at 60°C for 10 hours, and finally the dried filter cake was p...
Embodiment 3
[0048] Weigh 4.0g of FCC spent catalyst and 3.2g of sodium hydroxide solid in sequence, add them into the crucible and stir evenly, then add 1.8mL of deionized water and stir evenly, then place the mixture in a muffle furnace at a heating rate of 2°C / min Raise from room temperature to 500°C, activate for 2 hours, wait for natural cooling to room temperature, and grind with a mortar to obtain aluminosilicate mixture powder; at room temperature, add 5.0g of the above powder to 60mL, 2mol / L hydrochloric acid, and Stir magnetically at 25°C for 3 hours to obtain the prehydrolyzed turbid solution; at the same time, dissolve 2.0g of P123 in 60mL, 1mol / L hydrochloric acid, and stir magnetically at 35°C for 3h; then prehydrolyzed turbidly 2-3 drops per second Add it to the dissolved P123 solution, and continue magnetic stirring at 35°C for 24 hours to obtain a light yellow suspension; then transfer the obtained light yellow suspension to two 100mL polytetrafluoroethylene-lined hydrother...
PUM
| Property | Measurement | Unit |
|---|---|---|
| specific surface area | aaaaa | aaaaa |
| pore size | aaaaa | aaaaa |
| specific surface area | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More