Method for recycling metallic lithium from waste lithium ion batteries
A lithium-ion battery and metal lithium technology, applied in the field of selective recovery of valuable metal lithium, can solve the problems of poor selectivity of waste acid and waste alkali, complex element content testing, increased cost and difficulty, etc., to overcome difficult separation and good application Prospect, effect of reducing dissolution loss
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[0017] Example 1
[0018] The cathode material in the recovered waste lithium ion battery is mixed with 2wt% H 2 O 2 The 2M sulfuric acid solution was mixed at a solid-liquid ratio of 50g / L, stirred at 80°C for 3h, and filtered to obtain the leachate.
[0019] Table 1 Composition of extract
[0020] Ion species
[0021] As a comparative example, an appropriate amount of the above-mentioned extract was adjusted to pH 1, 2, 3, and 4, respectively, and mixed with pure tributyl phosphate at a ratio (O / A) = 1:1, stirred at room temperature for 30 minutes, and then centrifuged at 6000 rpm for 10 minutes. Analyzing the separated organic phase, it is calculated that the extraction rates of metallic lithium are 2.43%, 2.38%, 2.51%, and 2.49%, respectively.
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[0022] Example 2
[0023] The extraction system is composed of 1-carboxymethyl-3-methylimidazole bistrifluoromethanesulfonimide salt and tributyl phosphate in a volume ratio of 1:9.
[0024] Take an appropriate amount of the above extract to adjust the pH to 3, mix with the above extraction system according to the ratio (O / A)=1:1, stir at room temperature for 30 minutes, and then centrifuge at 6000 rpm for 10 minutes. After analyzing the separated organic phase and raffinate, it is calculated that the extraction rate of metallic lithium can reach more than 85%.
[0025] As a comparative example, the pH of the leaching solution was adjusted to 1, 2 and 4, and after extraction using the same method described above, the extraction rates of metallic lithium were calculated to be 79.54%, 83.29%, and 80.1%, respectively.
Example Embodiment
[0026] Example 3
[0027] The extraction system is composed of 1-carboxyethyl-3-methylimidazole bistrifluoromethanesulfonimide salt and tributyl phosphate in a volume ratio of 1:9.
[0028] Adjust the pH of the above-mentioned extract to 3, mix with the above-mentioned extraction system according to the ratio (O / A)=1:1, stir at room temperature for 30 minutes, and then centrifuge at 6000 rpm for 10 minutes. After analyzing the separated organic phase and raffinate, it is calculated that the extraction rate of metallic lithium can reach more than 85%.
[0029] As a comparative example, the volume ratio of 1-carboxyethyl-3-methylimidazole bistrifluoromethanesulfonimide salt and tributyl phosphate was adjusted to 1:4, 3:7, and 2:3 to form an extraction system. After extraction using the same method as above, the extraction rates of metallic lithium are calculated to be 80.75%, 81.2% and 70.17%, respectively.
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