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A kind of preparation method of red mud foamed glass-ceramics

A technology of foamed glass-ceramics and red mud, which is applied in glass manufacturing equipment, glass molding, manufacturing tools, etc., and can solve problems such as application limitations, high melting temperature, and low porosity

Active Publication Date: 2021-04-30
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The glass-ceramic prepared by this method is not foamed, so it is very limited in application, and there are various ores in the raw materials besides red mud, which increases the cost; patent CN106892565A discloses a The method for preparing foamed glass-ceramic from red mud and fly ash, its raw material composition and process are as follows, composition: red mud, fly ash, foaming agent and foam stabilizer (sodium phosphate dodecahydrate), etc., process: mixing Homogenized, screened, shaped, melted, etc., foamed glass-ceramics
The foamed glass-ceramic prepared by this method has high melting temperature and low porosity

Method used

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  • A kind of preparation method of red mud foamed glass-ceramics

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Experimental program
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Effect test

Embodiment 1

[0033]The red mud raw material and 150g / L sodium hydroxide solution were added to the high-temperature reactor for reaction at a liquid-solid ratio of 5mL / g. The reaction temperature was 300°C, the stirring rate was 300r / min, and the reaction time was 3h. After the reaction was completed, the red mud was dried at 100° C. for 10 h for use. Add 75 parts of red mud pretreated by alkali activation, 15 parts of sodium borate, and 10 parts of starch into a ball mill for ball milling and pulverization. After mixing, sieve through 300 mesh. Add the mixture to the mold and shape it. The molding size is 55mmX6mmX6mm. Melt the mixture together with the mold at 1000°C for 1.5 hours to obtain a uniform foamed glass liquid. Lower the furnace temperature to 700°C and keep it for 1 hour to foam the glass liquid. Crystal nuclei are formed at high temperature again, and then the temperature of the furnace is raised to 850°C for 1 hour to keep the crystal nuclei growing and forming crystals, and...

Embodiment 2

[0035] The red mud raw material and 180g / L sodium hydroxide solution were added to the high-temperature reactor for reaction at a liquid-solid ratio of 7mL / g. The reaction temperature was 300°C, the stirring rate was 300r / min, and the reaction time was 3h. After the reaction was completed, the red mud was dried at 100° C. for 10 h for use. Add 80 parts of red mud pretreated by alkali activation, 15 parts of sodium borate, and 5 parts of starch into a ball mill to pulverize, mix and sieve through 300 mesh. Add the mixture to the mold and shape it. The molding size is 55mm X 6mm X6mm. Melt the mixture together with the mold at 1100°C for 1.5 hours to obtain a uniform foaming glass liquid. Lower the furnace temperature to 750°C and keep it for 1 hour. Soak the glass liquid at high temperature again to form crystal nuclei, and then raise the furnace temperature to 900°C for 1 hour to keep the crystal nuclei growing and form crystals, and then cool down to room temperature with the...

Embodiment 3

[0037] The red mud raw material and 180g / L sodium hydroxide solution were added to the high-temperature reactor for reaction at a liquid-solid ratio of 7mL / g. The reaction temperature was 300°C, the stirring rate was 300r / min, and the reaction time was 3h. After the reaction was completed, the red mud was dried at 100° C. for 10 h for use. Add 75 parts of red mud pretreated by alkali activation, 15 parts of sodium borate, and 10 parts of starch into a ball mill for ball milling and pulverization. After mixing, sieve through 300 mesh. Add the mixture to the mold and shape it. The molding size is 55mm X 6mm X6mm. Melt the mixture together with the mold at 1000°C for 1 hour to obtain a uniform foaming glass liquid. Lower the temperature of the kiln to 700°C and keep it for 0.5h. Soak the glass liquid at high temperature again to form crystal nuclei, and then raise the furnace temperature to 850°C for 1 hour to keep the crystal nuclei growing and form crystals, and then cool down ...

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Abstract

The invention uses starch as a foaming agent and uses alkali activation to pretreat red mud, and provides a preparation method of red mud foamed glass-ceramics. Its main raw materials include red mud, flux, foaming agent and alkali solution; wherein the flux is sodium borate; the foaming agent is starch; the alkali solution is sodium hydroxide solution. The main steps are: (1) Alkali-activated pretreatment of the red mud raw material after ball milling; (2) Mixing the processed red mud raw material with other raw materials; (4) The sample is subjected to heat treatment processes such as sintering to obtain foamed glass-ceramic. The method for preparing red mud foamed glass-ceramics provided by the invention has the effect of encapsulating heavy metal ions in red mud, solves the problem of tailings pollution, and the product is safer and more environmentally friendly; and has self-foaming characteristics during the sintering process, and the preparation process is simple and easy .

Description

technical field [0001] The invention belongs to the field of solid waste reuse and construction engineering materials, and relates to a method for preparing foamed glass-ceramics by using red mud from industrial waste, in particular to a method of using starch as a foaming agent and pretreating red mud by alkali activation. Prepare a safe and environmentally friendly material that is superior to the national safety standard (GB / T 5071-2013). Background technique [0002] Over the past few decades, the development of China's industry has consumed a large amount of mineral resources, and has also produced a large amount of industrial solid waste, especially metallurgy, thermal power generation and other industries with the largest emissions, and there are various types, complex components, and difficult disposal. . According to reports, my country's industrial solid waste exceeded 5 billion tons in 2017. Since these solid wastes contain soluble heavy metal ions, such as lead,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C10/00C03C11/00C03B19/08C03B32/02
CPCC03B19/08C03B32/02C03C10/0063C03C11/007
Inventor 万向荣岳云龙康俊峰
Owner UNIV OF JINAN