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A low-odor polyvinyl chloride cable material composition for automobile wiring harness and its preparation method

A polyvinyl chloride cable, low-odor technology, applied in the processing and application of polymer materials, can solve the problems of formula design difficulties, reduce PVC cable materials, etc.

Active Publication Date: 2021-04-13
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The present invention finds in the test that the odor grade of the cable material for PVC automobile wiring harness developed by the aforementioned invention patent formula can reach between 2.5 and 3, and the formula design for the odor grade to be below 2.5 is very difficult. Low-molecular-weight plasticizers have not been completely replaced, and the use of additive molecular sieves, deodorants, and odor-masking agents has limited effect in reducing the irritating odor in PVC cable materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0022] The present invention will be further described below in conjunction with embodiment, wherein embodiment 1 is the best embodiment.

[0023] The composition weight ratio of each embodiment is shown in Table 1

[0024] The weight ratio of table 1 embodiment

[0025] .

[0026] The adipic acid polyester type weight average molecular weight is 1300 in embodiment 1~3, and viscosity is 1.2Pa.s, and the adipic acid polyester type weight average molecular weight is 1250 in embodiment 4,5, and viscosity is 1.13Pa.s, The weight average molecular weight of the adipic acid polyester type in Examples 6 and 7 is 1200, and the viscosity is 1.1 Pa.s. The weight average molecular weight of the adipic acid polyester type in Examples 8 and 9 is 1400, and the viscosity is 1.3 Pa.s.

[0027] Polycarbonate 1~3 is the polymkeric substance of carbon dioxide base, and the massfraction that carbonate chain link accounts for in the polycarbonate 1 in embodiment 1 is 93.5%, and weight average ...

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PUM

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Abstract

The invention discloses a low-odor polyvinyl chloride cable material composition and a preparation method for automobile wiring harness, which belong to the processing and application fields of polymer materials. It is characterized in that, the parts by weight are composed of: 100 parts of high polymerization degree PVC resin, 45 to 50 parts of composite plasticizer, 5 to 8 parts of silicon dioxide, 4.0 to 5.0 parts of calcium zinc stabilizer, and 0.15 to 0.25 parts of polyethylene wax. , 0.15~0.25 parts of oxidized polyethylene wax, 0.20~0.30 parts of antioxidant DLDTP; the composite plasticizer is polyester plasticizer and low polymerization degree polycarbonate plasticizer by mass ratio of 8~10:37 ~40 compound plasticizer. The preparation steps are as follows: after mixing the PVC resin, the composite plasticizer and the calcium-zinc stabilizer, the remaining materials are added according to the formula; the mixed materials are put into a twin-screw extruder for extrusion and granulation. The invention provides a low odor polyvinyl chloride cable material composition for automobile wiring harness with low volatility and low odor and a preparation method thereof.

Description

technical field [0001] The invention discloses a low-odor polyvinyl chloride cable material composition for automobile wire harnesses and a preparation method thereof, which belong to the field of processing and application of polymer materials. Background technique [0002] Polyvinyl chloride is currently the plastic material with the largest output and the cheapest price in China. Since polyvinyl chloride can be used for hard products, it can also be used for soft products after adding plasticizers. It has excellent comprehensive properties and is widely used; therefore In the fields of automobiles, household appliances, computers and communication equipment, various electronic instruments and meters, soft polyvinyl chloride is still the main material. Soft polyvinyl chloride is co-extruded with metal conductors and then made into a special automotive wiring harness together with the connecting plug-in for installation. However, there are still many defects in the use of ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08L23/06C08L23/30C08L69/00C08L67/00C08K5/372C08K3/36
CPCC08K2201/011C08L27/06C08L2203/202C08L2205/02C08L2205/035C08L23/06C08L23/30C08L69/00C08L67/00C08K5/372C08K3/36
Inventor 王晶李静张荣召侯斌张新华刘浩张桦刘容德王晓敏桂俊杰苏建华
Owner CHINA PETROLEUM & CHEM CORP
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