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A kind of environment-friendly polyvinyl chloride cable material and preparation method thereof

A polyvinyl chloride cable and polyvinyl chloride resin technology, used in circuits, electrical components, plastic/resin/wax insulators, etc., can solve the problem of high flame retardant smoke generation, can not meet the environmental protection requirements of flame retardant products, antimony oxide dust For problems such as harm to the respiratory system, it can achieve the effects of good flame retardancy, good flame retardant and smoke suppression effect, and excellent mechanical properties.

Active Publication Date: 2021-04-13
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the antimony-chlorine flame retardant system has a high flame retardant smoke production, and antimony oxide dust is very harmful to the respiratory system, which cannot meet the environmental protection requirements for flame retardant products.

Method used

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  • A kind of environment-friendly polyvinyl chloride cable material and preparation method thereof

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preparation example Construction

[0033] The preparation method of flame retardant and smoke suppressant in embodiment 1~3 is as follows:

[0034] 1) Take 2.0 moles of melamine and 1 mole of cyanuric acid, put them into a closed reaction kettle, then add 1000 ml of water, and stir for 50 minutes at a temperature of 110°C;

[0035] 2) Open the reaction kettle, add 2800ml of 1.0 mol / liter hydrochloric acid solution, then dissolve 1.3 moles of zinc chloride and 2.4 moles of sodium hydroxystannate in 2000 ml of water, add them to the reaction kettle, stir evenly, React for 2 hours under certain conditions, cool, wash with water, filter with suction, and dry to obtain a flame retardant and smoke suppressant.

Embodiment 4

[0036] The preparation method of flame retardant and smoke suppressant in embodiment 4 is as follows:

[0037] 1) Take 2.5 moles of melamine and 1 mole of cyanuric acid, put them into a closed reaction kettle, then add 1000 ml of water, and stir for 55 minutes at a temperature of 108°C;

[0038]2) Open the reaction kettle, add 3400ml of 1.0 mol / liter hydrochloric acid solution, then dissolve 0.9 moles of zinc chloride and 3.1 moles of sodium hydroxystannate in 2000 ml of water, add them to the reaction kettle, stir evenly, React for 2 hours under certain conditions, cool, wash with water, filter with suction, and dry to obtain a flame retardant and smoke suppressant.

Embodiment 5

[0039] The preparation method of flame retardant and smoke suppressant in embodiment 5 is as follows:

[0040] 1) Take 3.0 moles of melamine and 1 mole of cyanuric acid, put them into a closed reaction kettle, then add 1000 ml of water, and stir for 40 minutes at a temperature of 110°C;

[0041] 2) Open the reaction kettle, add 2000ml of 1.0 mol / liter hydrochloric acid solution, then dissolve 1.0 mol of zinc chloride and 2.0 mol of sodium hydroxystannate in 2000 ml of water, add it to the reaction kettle, stir evenly, React for 2 hours under certain conditions, cool, wash with water, filter with suction, and dry to obtain a flame retardant and smoke suppressant.

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Abstract

An environment-friendly polyvinyl chloride cable material and a preparation method thereof belong to the technical field of cable materials. It is characterized in that the composition in parts by weight is: polyvinyl chloride resin: 100 parts, heat stabilizer: 4-6 parts, main plasticizer cyclohexane-1,2 dioctyl dicarboxylate: 18-22 parts, auxiliary plasticizer Plasticizer trioctyl phosphite: 13~17 parts, flame retardant and smoke suppressant: 8~10 parts, calcined montmorillonite: 3~5 parts, tetrakis[methyl-β-(3,5-di-tert-butyl ‑4‑hydroxyphenyl) ester] pentaerythritol ester: 0.05~0.1 part, dilauryl thiodipropionate: 0.05~0.1 part, lubricant: 0.1~0.2 part. The preparation steps are: weighing each material and mixing in a high-speed mixer, and granulating the mixed material in a twin-screw extruder. The invention provides an environment-friendly polyvinyl chloride cable material with less consumption of flame retardant, good flame retardancy, lead-free, low smoke, environmental protection, good thermal stability and excellent mechanical properties and a preparation method thereof.

Description

technical field [0001] An environment-friendly polyvinyl chloride cable material and a preparation method thereof belong to the technical field of cable materials. Background technique [0002] Polyvinyl chloride cable compound is made of polyvinyl chloride as the base resin, with the addition of stabilizers, fillers, lubricants and other appropriate additives, and is made by mixing, kneading and extruding. It is mainly used to prepare wires and cables. However, wires and cables are prone to heating and burning due to short circuit during use, which seriously threatens the safety of people's property. [0003] With the rapid development of the global economy and the enhancement of human awareness of environmental protection, the requirements for the quality and performance of wires and cables in various fields are getting higher and higher, and there are more and more fires caused by the aging of wires and cables. How to reduce the fire The incidence of fire and the death r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08K13/02C08K5/12C08K5/3492C08K3/34C08K5/524H01B3/44
CPCC08K3/346C08K5/12C08K5/34924C08K5/34928C08K5/524C08K13/02C08L2201/02C08L2201/08C08L2201/22C08L2203/202H01B3/443C08L27/06
Inventor 张桦王晶袁辉志张新华李静刘容德刘浩王晓敏桂俊杰孙培培盛梅高磊王海波
Owner CHINA PETROLEUM & CHEM CORP