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Modified molecular sieve additive for reducing CO emission in flue gas, preparation method and application thereof

A molecular sieve and additive technology, applied in the application, tobacco, e-liquid filter and other directions, can solve the problem of short time, and achieve the effects of simple preparation, reduced CO emission, and good application prospects

Active Publication Date: 2020-10-27
CHINA TOBACCO YUNNAN IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the time for the smoke to pass through the filter is very short, and at the same time the components in the smoke are mixed together and pass through the filter in the form of aerosols.

Method used

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  • Modified molecular sieve additive for reducing CO emission in flue gas, preparation method and application thereof
  • Modified molecular sieve additive for reducing CO emission in flue gas, preparation method and application thereof
  • Modified molecular sieve additive for reducing CO emission in flue gas, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Add 1g of polyvinylpyrrolidone with a molecular weight of 1,000,000 to 100g of water, stir to dissolve it into a PVP aqueous solution, adjust the pH to 4.0 with acetic acid, add 1g of sodium silicate, and react at room temperature for 1hr, then add 10g Silica-alumina molecular sieve, stirred at room temperature for 30 minutes, filtered, and the filter residue was dried to obtain a modified molecular sieve additive that reduced the amount of CO released in the flue gas;

[0028] The modified molecular sieve additive was added to the cigarette holder in an amount of 50 mg / stick, and the cigarette was made according to the conventional method. The smoke components of the prepared cigarettes were analyzed. At the same time, a blank sample and a control sample were set for comparison. The blank sample was a cigarette without any material added. The results are shown in Table 1:

[0029] Table 1 Determination results of flue gas data

[0030]

Embodiment 2

[0032] Add 10g of vinylpyrrolidone-maleic acid copolymer with a molecular weight of 1000 to 100g of water, stir to dissolve it into a PVP aqueous solution, adjust the pH to 5.5 with hydrochloric acid, add 1g of potassium silicate, and react at room temperature. After 4 hours, add 1 g of phosphorus-aluminum molecular sieve, stir at room temperature for 60 minutes, filter, and dry the filter residue to obtain a modified molecular sieve additive that reduces the amount of CO released in the flue gas;

[0033] The modified molecular sieve additive was added to the cigarette holder in an amount of 10 mg / stick, and the cigarette was made according to the conventional method. The smoke components of the prepared cigarettes were analyzed. At the same time, a blank sample and a control sample were set for comparison. The blank sample was a cigarette without any material added, and the control sample 2 was a cigarette directly added with the same weight and the same molecular sieve into ...

Embodiment 3

[0038] 3g of polyvinylpyrrolidone with a molecular weight of 5000 and 3g of vinylpyrrolidone-maleic acid copolymer with a molecular weight of 100,000 were added to 100g of water, stirred to dissolve into a PVP aqueous solution, adjusted to pH 5.0 with hydrochloric acid, and then added. 3g of sodium silicate, after reacting for 1hr at room temperature, add 6g of clinoptilolite, stir at room temperature for 30min, filter, and dry the filter residue to obtain a modified molecular sieve additive that reduces the amount of CO released in the flue gas;

[0039] The modified molecular sieve additive was added to the cigarette holder in an amount of 100 mg / stick, and cigarettes were made according to conventional methods. The smoke composition of the prepared cigarettes was analyzed. At the same time, a blank sample and a control sample were set for comparison. The blank sample was a cigarette without any material added. The results are shown in Table 3:

[0040] Table 3 Determinatio...

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Abstract

The invention relates to a modified molecular sieve additive for reducing the emission of CO in a flue gas and a preparation method and an application of the modified molecular sieve additive, and belongs to the technical field of harm reduction of cigarettes. The preparation method comprises the following steps: adding a polyvinyl pyrrolidone compound into water at the mass ratio of 1:(10-100), stirring to dissolve the polyvinyl pyrrolidone (PVP) compound, obtaining a PVP aqueous solution; regulating the PVP aqueous solution by using an acid until the pH is equal to 4.0-5.5, then adding silicate into the PVP aqueous solution, adding a molecular sieve after reacting for 1-4 hours at the room temperature, stirring for 30-60 minutes at the room temperature, filtering, drying a filter residue, and obtaining the modified molecular sieve additive for reducing the emission of CO in the flue gas. The preparation is simple, the cost is low, after the prepared modified molecular sieve additiveis added in a filter, the emission of the CO in the flue gas is obviously reduced, meanwhile, the taste of the cigarette is not obviously affected, and the modified molecular sieve additive has an excellent application prospect.

Description

technical field [0001] The invention belongs to the technical field of cigarette harm reduction, in particular to a modified molecular sieve additive for reducing CO emission in flue gas and a preparation method thereof. Meanwhile, the present invention also relates to the application of the additive. Background technique [0002] In recent years, due to the influence of the World Health Organization and the anti-smoking campaign, and consumers paying more attention to their own health, the international cigarette consumption market has also undergone some changes. In order to reduce the harm of tobacco products to consumers, the international tobacco industry has intensified research efforts in many fields including tobacco leaf production, cigarette production technology, and coke reduction technology, and the international cigarette market has also accelerated to lower tar, Trends in the development of cigarettes with low nicotine and other harmful ingredients. Domestic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A24D3/02A24D3/06
CPCA24D3/0225A24D3/061
Inventor 王晋许永黄海涛孔维松李晶刘欣杨叶昆张涛杨光宇李雪梅
Owner CHINA TOBACCO YUNNAN IND