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Production technique of novel extrusion-molding polylactic acid foaming sheet

A production technology, a technology of plastic polymerization, which is applied in the field of preparation of extruded polylactic acid micro-foamed sheets, can solve the problems of harsh production process conditions, high requirements on matrix fluidity, difficult process control, etc., and achieves simple molding equipment. Efficient, fully explainable performance, excellent comprehensive effect

Inactive Publication Date: 2018-12-07
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Polylactic acid foamed sheets can be prepared by physical or chemical foaming. The physical foaming method mainly includes the supercritical carbon dioxide foaming method, and its disadvantages are high requirements for equipment and high process costs; chemical foaming methods mainly It is formed by adding a chemical foaming agent such as AC foaming agent to the matrix. The disadvantage is that it has high requirements on the fluidity of the matrix, strict requirements on the production process conditions, and the process is difficult to control.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0023] Preparation of blowing agent masterbatch:

[0024] Content of each component:

[0025] Expandable microspheres (100 parts), ethylene-vinyl acetate copolymer (200 parts).

[0026] Preparation:

[0027] Under the conditions of 60-100°C and a rotating speed of 30r / min, use a twin-screw extruder to extrude the prepared materials into pellets.

[0028] Preparation of PLA:

[0029] Content of each component:

[0030] Polylactic acid (100 parts), maleic anhydride (2 parts), dicumyl peroxide (0.02 parts).

[0031] Preparation:

[0032] Under the conditions of 150-160°C and a rotational speed of 30r / min, use a twin-screw extruder to extrude the prepared materials into granules.

[0033] Preparation of PLA sheets:

[0034] Content of each component:

[0035] Polylactic acid (90 parts), polyglycolic acid (10 parts), foaming agent masterbatch (9 parts), bamboo powder (10 parts), starch (30 parts), talcum powder (5 parts), glycerin (5 parts) , citric acid (5 parts).

[003...

example 2

[0038] Preparation of blowing agent masterbatch:

[0039] Content of each component:

[0040] Expandable microspheres (100 parts), ethylene-vinyl acetate copolymer (200 parts).

[0041] Preparation:

[0042] Under the conditions of 60-100°C and a rotating speed of 30r / min, use a twin-screw extruder to extrude the prepared materials into pellets.

[0043] Preparation of PLA:

[0044] Content of each component:

[0045] Polylactic acid (100 parts), maleic anhydride (4 parts), dicumyl peroxide (0.04 parts).

[0046] Preparation:

[0047] Under the conditions of 150-160°C and a rotational speed of 30r / min, use a twin-screw extruder to extrude the prepared materials into granules.

[0048] Preparation of PLA sheets:

[0049] Content of each component:

[0050] Polylactic acid (90 parts), PBAT (90 parts), foaming agent masterbatch (12 parts), bamboo powder (10 parts), starch (30 parts), glycerin (5 parts), citric acid (5 parts), talc Powder (5 parts).

[0051] at temperatu...

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PUM

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Abstract

The invention relates to a production technique of a novel extrusion-molding polylactic acid foaming sheet, belonging to the machining field of high molecular materials. The production technique is characterized by comprising the steps of firstly preparing a foamed master batch, modifying polylactic acid, and carrying out extrusion molding on 3-12 parts of the foamed master batch, 100 parts of a polymer matrix, 3-20 parts of a processing aid and 10-50 parts of a filler by virtue of a single screw rod, so as to obtain the polylactic acid foaming sheet. The production technique has the beneficial effects that common physical and chemical foaming methods are replaced, the low-cost polylactic acid foaming sheet is successfully prepared, the production cost of the polylactic acid foaming sheetis lowered on the premise that the mechanical property of the sheet is guaranteed, foaming equipment is simple and efficient, the foaming rate is increased, and the production technique has relativelyhigh application values.

Description

technical field [0001] The invention relates to a novel extruded polylactic acid foamed sheet production technology, and the preparation of extruded polylactic acid micro-foamed sheet with simple and efficient molding equipment, high foaming ratio, excellent mechanical properties and low production cost. Background technique [0002] Polylactic acid foamed sheet is a new material for preparing foamed products because of its good biodegradable properties, environmental protection and pollution-free, good mechanical properties and water resistance. It can be widely used in packaging, automobiles, construction, synthetic wood and other fields. [0003] Polylactic acid foamed sheets can be prepared by physical or chemical foaming. The physical foaming method mainly includes the supercritical carbon dioxide foaming method, and its disadvantages are high requirements for equipment and high process costs; chemical foaming methods mainly It is formed by adding a chemical foaming ag...

Claims

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Application Information

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IPC IPC(8): C08L67/04C08L67/02C08L33/20C08L33/00C08L23/08C08L97/02C08L3/02C08K13/02C08K3/34C08K5/11C08K5/092C08K5/053C08K5/14C08J9/32
CPCC08J9/32C08J9/0023C08J9/0061C08J9/0066C08J2367/02C08J2367/04C08J2403/02C08J2423/08C08J2433/00C08J2433/20C08J2497/02C08K3/34C08K5/053C08K5/092C08K5/11C08K5/14C08K13/02
Inventor 李洪飞乔虎王利
Owner BEIJING UNIV OF CHEM TECH