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Composite hydrogel, anti-seepage membrane, preparation method and application thereof

A composite hydrogel, hydrogel technology, applied in gaskets, infrastructure engineering, protection devices, etc., can solve problems such as erosion

Active Publication Date: 2021-03-02
LIAONING BENTENAI TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problem that bentonite may have erosion risk as a buffer layer material, the present invention innovatively proposes a concept of an anti-erosion isolation layer, and provides a composite hydrogel anti-seepage membrane for nuclear waste disposal isolation layer and its preparation method , aims to improve the anti-erosion ability of the buffer material of the high-level radioactive waste repository through the introduction of the isolation layer, and further improve the safety and long-term effectiveness of the high-level radioactive waste repository

Method used

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  • Composite hydrogel, anti-seepage membrane, preparation method and application thereof
  • Composite hydrogel, anti-seepage membrane, preparation method and application thereof

Examples

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Effect test

Embodiment 1

[0086] Fully stir the carbon fiber with a mass fraction of 1% and the polyacrylamide with a mass fraction of 20% in a dry-blending mixer to form a uniform dry-blended polyacrylamide / carbon fiber and set aside. 30% diatomaceous earth, 2% gas phase silica, and 6% sodium carbonate were fully mixed in the reaction kettle, and 35% water was added, and the reaction was stirred at 60°C for 5- 6h, then sequentially add 1% mass fraction of coupling agent KH-560, and 0.5% mass fraction of antifungal agent sodium benzoate, stir in the reaction kettle for 1-2h, and mix to form a uniform slurry. Add dry-blended polyacrylamide / carbon fiber to the above-mentioned uniform slurry, and add 4.5% water, and then vigorously stir and shear to form a uniform hydrogel mud with a certain toughness and moderate hardness; the above-mentioned moderate hardness hydrogel Put the mud into the hopper of the press, adjust the gap between the two rollers of the press to make the forming thickness 5mm, press th...

Embodiment 2

[0091] The ceramic fiber with a mass fraction of 0.5% and the N-methylol polyacrylamide modified condensation polyacrylamide with a mass fraction of 22% are fully stirred in a dry blending mixer to form a uniform dry blended modified polyacrylamide / ceramic fiber, spare. In the reactor, fully mix bentonite with a mass fraction of 35% and chitosan with a mass fraction of 5%, add water with a mass fraction of 33%, stir and react at 50°C for about 8 hours, and then add 0.5% mass fraction of The coupling agent DL602 and the antifungal agent sodium pentachlorophenolate with a mass fraction of 0.5% are stirred in the reaction kettle for 1-2 hours to form a uniform slurry. Add dry-mixed modified polyacrylamide / ceramic fiber to the above-mentioned uniform slurry, and add 3.5% water, and then vigorously stir and shear to form a uniform hydrogel mud with a certain toughness and moderate hardness; Send the hydrogel mud into the hopper of the press, adjust the gap between the two press r...

Embodiment 3

[0096] The mass fraction is 1% glass fiber and mass fraction is 15% hydroxymethyl cellulose, 2% polyacryl alcohol fully stirred in a dry mixing mixer, mixed into a uniform dry mixing hydrogel / glass fiber, spare. Mix 45% diatomaceous earth and 2% chitosan in the reaction kettle, add water with a mass fraction of 30%, stir and react at room temperature for 3 hours, and then add 1% coupling Agent KH-550 and antifungal agent benzoic acid with a mass fraction of 0.5% are stirred in the reaction kettle for 1-2 hours, and mixed into a uniform slurry. Add uniform dry-mixed hydrogel / glass fiber to the above-mentioned uniform slurry, and add 3.5% water, and then vigorously stir and shear to form a uniform hydrogel mud with a certain toughness and moderate hardness; the above-mentioned moderate hardness Send the hydrogel mud into the hopper of the press, adjust the gap between the two press rollers of the press to make the forming thickness 6mm, and press the hydrogel mud tightly at a u...

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Abstract

The invention provides a composite hydrogel, impermeable coiled material as well as preparation method and application of composite hydrogel, impermeable coiled material, and specifically relates to acomposite hydrogel impermeable coiled materials which can be used for a nuclear waste disposal isolation layer. The impermeable coiled material is composed of a surface protective layer, the composite hydrogel, and a bottom support layer, the composite hydrogel is located between the surface protective layer and bottom support layer, the preparation method comprises the following steps: pressingfiber-reinforced hydrogel prepared from fiber, hydrogel, filler, a modification agent, a coupling agent, a mildew preventive and water between the surface protective layer and the bottom support layer, obtaining a composite hydrogel impermeable coiled material product. The impermeable coiled material prepared by the invention mainly used for coating the isolation layer of a waste liquid tank in anuclear waste disposal repository, and an isolation layer laid between a buffer layer and surrounding rock, the erosion of buffer layer material under the long-term action of groundwater can be effectively prevented, and further the radioactive nuclide is solidified, the safety and long-term effectiveness of nuclear waste disposal repositories are improved.

Description

technical field [0001] The invention belongs to the technical field of nuclear waste disposal and protection, and specifically relates to a composite hydrogel, an anti-seepage coil, a preparation method thereof, and an application thereof. Background technique [0002] As a clean, efficient and environmentally friendly energy, nuclear energy has been applied in more and more fields. While human beings enjoy the benefits of nuclear energy and vigorously develop nuclear application technology, the amount of nuclear waste is also increasing year by year, and the safe disposal of nuclear waste has become an urgent problem to be solved. In 2011, the tsunami triggered by the earthquake led to the Fukushima nuclear leakage accident in Japan, which once again aroused global attention to the disposal of nuclear waste. According to the classification of radioactive levels, nuclear waste is divided into low-level, medium-level and high-level waste. At present, the safe disposal techn...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L33/26C08L97/02C08L1/28C08L29/02C08L3/02C08L5/08C08K13/04C08K7/06C08K7/26C08K3/36C08K7/04C08K7/14C08J3/075E02D31/02
CPCC08J3/075C08J2301/28C08J2329/02C08J2333/26C08J2401/28C08J2403/02C08J2405/08C08J2429/02C08J2497/02C08K3/36C08K7/04C08K7/06C08K7/14C08K7/26C08K13/04E02D31/025E02D2300/0045E02D2450/106
Inventor 张艳玲袁仁勇齐文戚丁文
Owner LIAONING BENTENAI TECH DEV