A configuration and method for recovering oxidation liquid in a transformed oxidation line and protecting a single-nickel-salt coloring tank
An oxidizing liquid and oxidizing wire technology, applied in anodizing, electrolytic coating, surface reaction electrolytic coating, etc., can solve the problems of affecting coloring, ammonium ion entry, etc., so as to reduce the cost of treatment and discharge, and reduce the total amount of solid-liquid separation. , the effect of saving resources
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[0074] In order to have a clearer understanding of the technical features, purposes and beneficial effects of the present invention, the technical solution of the present invention is described in detail below, but it should not be construed as limiting the scope of implementation of the present invention.
[0075] 1. Theoretical basis for the recovery of aluminum ions and sulfuric acid in the anodizing solution
[0076] When the aluminum alloy is oxidized, according to formula (3), part of the oxide film is dissolved, about 4Kg / T (400m 2 ) of aluminum is dissolved into the sulfuric acid oxidation solution, so that the oxidation solution contains Al 3+ 、H + and SO 4 2- , add ammonium sulfate, ammonium nitrate, ammonium chloride, potassium sulfate, potassium nitrate, potassium chloride to this oxidation solution, then the following reaction occurs:
[0077] Add ammonium sulfate to the oxidizing solution:
[0078] Al 2 (SO 4 ) 3 +(NH 4 ) 2 SO 4 +12H 2 O=2NH 4 Al(SO ...
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