A preparation method of a porous lithium ion electrode sheet with high energy density and a lithium ion battery

A technology with high energy density and lithium ions, which is applied in the field of preparation of porous lithium ion pole pieces, can solve the problems that the thickness of the energy density pole piece is not proportional, unfavorable Li+ extraction and intercalation, lithium ion capacity density is not up to standard, etc., to achieve good ionization The effect of conductivity, simple pore-forming method, and wide applicability

Active Publication Date: 2019-01-08
TIANJIN ENERGIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, through practical use, it has been found that thick electrodes also have disadvantages. The increase in the thickness of the pole piece increases the energy density of lithium ions to a certain extent, but the increase in energy density is not proportional to the increase in the thickness of the pole piece. Coated active material is not fully functioning
After research, it is found that this is because during the rolling process of the pole piece, the upper surface pole piece is stressed first to reach the design compaction density, resulting in a structure with s

Method used

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  • A preparation method of a porous lithium ion electrode sheet with high energy density and a lithium ion battery
  • A preparation method of a porous lithium ion electrode sheet with high energy density and a lithium ion battery

Examples

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Embodiment 1

[0040] Put N-methylpyrrolidone and binder (polyvinylidene fluoride) into a double planetary dynamic mixer to prepare glue, add positive active material and positive electrode conductive agent to the glue and mix evenly to obtain a uniform Stable positive electrode slurry (wherein the weight and number ratio of positive electrode active material, conductive agent and binder is 97.3:1.2:1.5), after adding negative electrode active material and negative electrode conductive agent to the glue solution and mixing evenly, a uniform and stable Negative electrode slurry, (wherein the weight and number ratio of negative electrode active material, conductive agent, and binder is 96:1.0:3.0) the prepared slurry is coated on the electrode current collector by spraying or roller coating, The surface density of positive electrode coating is 60mg / cm 2 , negative electrode surface density is 38mg / cm 2 , bake to remove the solvent and moisture absorbed in the air, after the electrode sheet is...

Embodiment 2

[0042]Put the N-methylpyrrolidone and the binder (polyvinylidene fluoride) into the double planetary power mixer to prepare the glue solution, add the positive electrode active material and the positive electrode conductive agent to the glue solution and mix them evenly to obtain a uniform solution. Stable positive electrode slurry (wherein, the weight ratio of positive electrode active material, conductive agent and binder is 97.5:1.0:1.5), after adding negative electrode active material and negative electrode conductive agent to the glue solution and mixing evenly, a uniform and stable slurry is obtained. Negative electrode slurry (wherein, the weight ratio of negative electrode active material, conductive agent, and binder is 96.5:1.2:2.3), and the prepared slurry is applied on the electrode current collector by spraying or roller coating, The surface density of positive electrode coating is 60mg / cm 2 , the negative sheet density is 38 mg / cm 2 , bake to remove the solvent ...

Embodiment 3

[0044] Put the N-methylpyrrolidone and the binder (polyvinylidene fluoride) into the double planetary power mixer to prepare the glue solution, add the positive electrode active material and the positive electrode conductive agent to the glue solution and mix them evenly to obtain a uniform solution. Stable positive electrode slurry (wherein, the weight ratio of positive electrode active material, conductive agent and binder is 97:1.5:1.5), after adding negative electrode active material and negative electrode conductive agent to the glue solution and mixing evenly, a uniform and stable slurry is obtained. Negative electrode slurry (wherein, the weight ratio of negative electrode active material, conductive agent, and binder is 97:0.75:2.25), and the prepared slurry is applied on the electrode current collector by spraying or roller coating, The surface density of positive electrode coating is 60mg / cm 2 , the negative sheet density is 38 mg / cm 2 , bake to remove the solvent a...

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Abstract

The invention provides a preparation method of a porous lithium ion electrode sheet with high energy density and a lithium ion battery. S1, A glue liquid is prepared by dissolving a binder in a N-methyl pyrrolidone solution, and the glue liquid is uniformly mixed with an active substance and a conductive agent to obtain a slurry; S2, respectively coating the mixed slurry on the current collector to obtain pole pieces; S3, cold pressing the coated pole piece, then coating the pore-forming agent on the surface of the cold-pressed pole piece, uniformly coating the pore-forming agent on the surface of the cold-pressed pole piece by means of a coating machine, drying while coating, and setting the drying temperature to be higher than the decomposition temperature of the pore-forming agent to obtain the porous lithium ion pole piece with high energy density. The invention improves the porosity of the thick electrode sheet and improves the electric performance by preparing a thick electrode with high surface density and coating a pore-forming agent on the surface of the electrode sheet after cold pressing.

Description

technical field [0001] The invention belongs to the field of lithium ion batteries, and in particular relates to a preparation method of a porous lithium ion pole piece with high energy density and a lithium ion battery. Background technique [0002] As a high-performance secondary battery, lithium-ion batteries are widely used in daily life due to their long cycle life and environmental friendliness, such as mobile phones, cameras, computers, electric bicycles, etc. [0003] In recent years, with the continuous expansion of its application range, especially in high-energy-consuming vehicles such as pure electric vehicles, plug-in hybrid vehicles, etc., the requirements for the energy density of lithium-ion batteries continue to increase. To improve the energy density of lithium-ion batteries, on the one hand, develop positive electrode materials with high capacity, such as lithium nickel manganese cobalt oxide (LiNi x CoyMn 1-x-y o 2 0.6<x<1, 0.3≤y≤1 / 3), lithium n...

Claims

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Application Information

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IPC IPC(8): H01M4/139H01M4/04H01M4/13H01M10/0525
CPCH01M4/0404H01M4/13H01M4/139H01M10/0525Y02E60/10H01M2004/021H01M2004/027H01M4/043H01M4/0471H01M4/133H01M4/1393H01M4/36H01M10/052
Inventor 卢红红高秀玲王驰伟申津静
Owner TIANJIN ENERGIES
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