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Nickel-for-cobalt hard alloy material and preparation method and application thereof

A cemented carbide and alloy composition technology, which is applied in the field of nickel-substituted cobalt cemented carbide materials and its preparation, can solve problems such as unstable product quality, many product pores, and insufficient wear resistance, and achieve rich mineral deposits and less product pores , the effect of preventing the accumulation of nickel powder

Inactive Publication Date: 2019-02-01
株洲金韦硬质合金有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invention solves the problems of low product hardness, insufficient wear resistance, low strength, many product pores and unstable product quality existing in traditional nickel-substituted cobalt cemented carbide by adjusting the composition and proportion of raw materials.

Method used

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  • Nickel-for-cobalt hard alloy material and preparation method and application thereof
  • Nickel-for-cobalt hard alloy material and preparation method and application thereof
  • Nickel-for-cobalt hard alloy material and preparation method and application thereof

Examples

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Embodiment 1

[0064] This embodiment provides a nickel-substituted cobalt hard alloy material, which is composed of the following alloy components in weight percentage: Co powder: 5%, chromium carbide: 0.4%, nickel powder: 3%, molybdenum powder: 0.3%, tungsten carbide Amount, the sum of all the above-mentioned alloy components is 100%; wherein, the nickel powder is carbonyl nickel powder, preferably FNiT04, and the nickel powder is composed of the following elements by weight percentage: Fe: 0.0005%, Co: 0.0002%, C: 0.1%, O: 0.05%, S: 0.0010%, the remainder of Ni; the molybdenum powder is preferably FMo-1 molybdenum powder; the average particle size of tungsten carbide is 1.0 μm, the average particle size of Co powder is 1.1 μm, and the average particle size of molybdenum powder 1.0 μm.

[0065] The preparation method of above-mentioned nickel-substituted cobalt hard alloy material comprises the following steps:

[0066] S1. Ingredients: mix tungsten carbide, chromium carbide, nickel powde...

Embodiment 2

[0074] This embodiment provides a nickel-substituted cobalt hard alloy material, which is composed of the following alloy components in weight percentage: Co powder: 4.5%, chromium carbide: 0.2%, nickel powder: 4%, molybdenum powder: 0.2%, tungsten carbide Amount, the sum of all the above-mentioned alloy components is 100%; wherein, the nickel powder is carbonyl nickel powder, preferably FNiT04, and the nickel powder is composed of the following elements in weight percentage: Fe: 0.0010%, Co: 0.0004%, C: 0.15%, O: 0.10%, S: 0.0005%, the remainder of Ni; the molybdenum powder is preferably FMo-1 molybdenum powder; the average particle size of tungsten carbide is 1.3 μm, the average particle size of Co powder is 1.0 μm, and the average particle size of molybdenum powder is 1.2 μm.

[0075] For the preparation method of the nickel-substituted cobalt hard alloy material, refer to the operation steps of Example 1.

Embodiment 3

[0077] This embodiment provides a nickel-cobalt substituted hard alloy material, which is composed of the following alloy components in weight percentage: Co powder: 6%, chromium carbide: 0.5%, nickel powder: 2.5%, molybdenum powder: 0.4%, tungsten carbide Amount, the sum of all the above-mentioned alloy components is 100%; wherein, the nickel powder is carbonyl nickel powder, preferably FNiT04, and the nickel powder is composed of the following elements by weight percentage: Fe: 0.0015%, Co: 0.001%, C: 0.15%, O: 0.15%, S: 0.0015%, the remainder of Ni; the molybdenum powder is preferably FMo-1 molybdenum powder; the average particle size of tungsten carbide is 1.2 μm, the average particle size of Co powder is 1.2 μm, and the average particle size of molybdenum powder 1.1 μm.

[0078] For the preparation method of the nickel-substituted cobalt hard alloy material, refer to the operation steps of Example 1.

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Abstract

The invention belongs to the technical field of hard alloy production and discloses a nickel-for-cobalt hard alloy material and a preparation method and application thereof. According to the nickel-for-cobalt hard alloy material and the preparation method and application thereof, refined paraffin is adopted as a molding agent; ball milling, drying for granulation, compression molding and sinteringare conducted, so that the novel hard alloy material low in cost and high in performance is prepared; and in the preparation process, molybdenum powder is added, and wettability of nickel powder andtungsten carbide powder is improved; low-temperature sintering and pressure sintering are adopted for sintering molding treatment; and argon gas is adopted as a carrier, and the porosity of products can be reduced while it is guaranteed that the products are small in crystal grain size.

Description

technical field [0001] The invention belongs to the technical field of hard alloy production, and more specifically relates to a nickel-substituted cobalt hard alloy material and a preparation method and application thereof. Background technique [0002] Cemented carbide consists of hard compounds of refractory metals and binder metals (mainly cobalt). Due to the increasing demand for cemented carbide and the limited cobalt resources in the world, finding and researching alternative materials for cobalt has always been a directional topic in the research and production of cemented carbide. In recent years, experts and scholars from all over the world are studying new resources of new cemented carbide materials, among which nickel substituting cobalt has become a research hotspot. [0003] However, some of the existing nickel-substituted cobalt cemented carbides will produce large-grained nickel aggregates that do not exist in fine-grained nickel powders during wet grinding,...

Claims

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Application Information

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IPC IPC(8): C22C29/08C22C1/05C22C1/10B22F9/04B22F3/02B22F3/10
CPCC22C29/08B22F3/02B22F3/101B22F3/1021B22F3/1035B22F9/04B22F2009/042B22F2009/043C22C1/051C22C29/067
Inventor 宋明普
Owner 株洲金韦硬质合金有限公司
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