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Femtosecond laser instant color development and regulation method

A femtosecond laser, reddish-brown technology, applied in the field of glass color development, can solve the problems of difficult to maintain chemical stability, color development is difficult to maintain for a long time, complex preparation process, etc., to achieve considerable application prospects, wide range of glass formation, The effect of simple process

Active Publication Date: 2019-03-29
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, to achieve color development, not only external conditions such as post-illumination or heating are required, but also the preparation process is more complicated than the general glass preparation process because of the need for coating or filling.
More importantly, the currently used color-changing compounds are mainly organic compounds or nanoparticles, which are difficult to maintain their long-term chemical stability, and their color development is also difficult to maintain for a long time.

Method used

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  • Femtosecond laser instant color development and regulation method
  • Femtosecond laser instant color development and regulation method
  • Femtosecond laser instant color development and regulation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Select silicon dioxide, boric acid, lead oxide, bismuth trioxide and antimony trioxide as starting compound raw materials, and weigh five compound raw materials respectively according to the molar ratio of each element, and the proportions are as follows:

[0034] B:Pb:Si:Bi:Sb=108:15:11:36:4, corresponding to x=58, y=15, z=11;

[0035] The total weight of the control mixture is 60g. After grinding and mixing 60g of the mixture, put it into a corundum crucible, then put the crucible into a muffle furnace at a temperature of 500°C, pretreat for 60 minutes, and then transfer the crucible to a high-temperature electric furnace at 1200°C.

[0036] The samples were melted at 1200 °C for 30 min. Take out the corundum crucible at high temperature, and quickly pour the melt on a stainless steel plate at room temperature. In order to accelerate cooling, press quickly with another stainless steel plate to obtain the required sample, and select the appropriate size of the sample ...

Embodiment 2

[0040] Select silicon dioxide, boric acid, lead oxide, bismuth trioxide and antimony trioxide as starting compound raw materials, weigh five compound raw materials respectively according to the molar ratio of each element, and divide them into four groups of ingredients, and four groups of ingredients For example:

[0041] (1) B:Pb:Si:Bi:Sb=132:0:14:36:4, corresponding to x=66, y=0, z=14;

[0042] (2) B:Pb:Si:Bi:Sb=116:10:12:36:4, corresponding to x=58, y=10, z=12;

[0043] (3) B:Pb:Si:Bi:Sb=100:20:10:36:4, corresponding to x=50, y=20, z=20;

[0044] (4) B:Pb:Si:Bi:Sb=82:30:9:36:4, corresponding to x=41, y=30, z=9;

[0045] The mixture gross weight of control four groups is 60g.

[0046] After each group of 60g mixture was ground and mixed, it was put into a corundum crucible, and then the crucible was placed in a muffle furnace at a temperature of 500°C for pretreatment for 60 minutes, and then the crucible was transferred to a high-temperature electric furnace at a temperat...

Embodiment 3

[0049] Select silicon dioxide, boric acid, lead oxide, bismuth trioxide and antimony trioxide as starting compound raw materials, and weigh five compound raw materials respectively according to the molar ratio of each element, and the proportions are as follows:

[0050] B:Pb:Si:Bi:Sb=132:0:14:36:4, corresponding to x=66, y=0, z=14;

[0051] The total weight of the control mixture is 60g. After grinding and mixing 60g of the mixture, put it into a corundum crucible, then put the crucible into a muffle furnace at a temperature of 400°C, pretreat for 2 hours, and then transfer the crucible to a high-temperature electric furnace at 1250°C. The sample was melted at 1250 °C for 60 min. Take out the corundum crucible at high temperature, and quickly pour the melt on a stainless steel plate at room temperature. In order to accelerate cooling, press quickly with another stainless steel plate to obtain the required sample, and select the appropriate size of the sample for cutting, gri...

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Abstract

The invention discloses a femtosecond laser instant color development and regulation method. The method comprises the following steps: weighing corresponding content values of the raw materials according to the components of glass, and fully grinding the raw materials to form a mixture; preprocessing the mixture at 400-500 DEG C, melting the preprocessed mixture in a 1200-1250 DEG C high-temperature smelting furnace, cooling the melted mixture to obtain a glass sample, cutting and polishing the glass sample, and moving a precise processing platform in a three-dimensional manner to control a distance between the surface of the sample and a focus in order to make a laser beam perpendicularly irradiate the internal of the glass sample; and carrying out heat treatment on the femtosecond laserirradiated glass for different time periods to obtain a pattern which can erased to different degrees and until completely, wherein the heat treatment temperature is selected near the transition temperature of the glass. The color of the processed area of the glass can be controlled by changing the content of lead, the femtosecond pulsed laser energy and the heat treatment time period after femtosecond processing; and the erasing of the developed color can be realized under a suitable heat treatment time period.

Description

technical field [0001] The invention relates to a glass color development technology, in particular to a femtosecond laser instant color development and control method. Background technique [0002] In the prior art glass color rendering process, there are generally three types of implementation methods. The first type is to use the laser to interact with the glass to induce a microstructure inside the transparent glass. After heat treatment, gold or silver nanoparticles are reduced and precipitated in the microstructure area to obtain a color pattern. This method must undergo post-stage heat treatment to provide migration and diffusion energy for gold and silver atoms. When the heat energy is higher than the free energy required for the nucleation of gold and silver nanoparticles, the gold and silver atoms will aggregate and deposit, showing light yellow or purple, etc. color. [0003] The second type is to dope rare earth ions inside the glass, and use femtoseconds to pe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/072C03C4/02C03C23/00
CPCC03C3/072C03C4/02C03C23/0025
Inventor 彭明营王丽平李晓曼
Owner SOUTH CHINA UNIV OF TECH
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