Electrolyte compositions for lithium-sulfur batteries
A lithium-sulfur battery and electrolyte technology, applied in battery electrodes, lithium batteries, organic electrolytes, etc., can solve the problems of improved cycle stability and low cycle stability of lithium-sulfur batteries
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[0064] figure 1 A schematic structure of a primary cell of a lithium-sulfur battery is shown. The galvanic cell 1 has an anode 3 , a cathode 5 and an electrolyte composition 7 . The anode 3 can be formed as a metal lithium anode, a silicon anode or a silicon-carbon composite anode. The anode 5 has porous carbon 9 as structural element, in which sulfur 11 is stored as active substance. also, figure 1 The chemical and physical processes during discharge of a primary cell in a lithium-sulfur battery are shown. During the discharge, the sulfur molecules 11 are reduced to polysulfides 13 and the lithium intercalated in the anode 3 or present as metal rods is oxidized to lithium ions, thereby forming lithium sulfide and / or lithium polysulfide. At the cathode, long-chain polysulfides 13 are first produced, which are further reduced to short-chain lithium sulfides 15 at the anode 3, such as Li 2 S and Li 2 S 2 . The polysulfides move from the cathode 5 , preferably by diffusio...
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