One-component room temperature vulcanized silicone rubber and preparation method

A room temperature vulcanization and silicone rubber technology, which is applied in the field of silicone rubber, can solve the problems of complex vulcanized silicone rubber preparation process, water, electricity, heat consumption, poor storage stability, etc., and achieve shortened production process and production process time, mechanical Improved performance and stable storage

Inactive Publication Date: 2019-04-16
HUBEI HUITIAN NEW MATERIALS STOCK CO LTD +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] For a long time, the preparation process of one-component room temperature vulcanized silicone rubber has been relatively complicated, and it must be dehydrated under high-temperature vacuum for 3 hours to remove the moisture in the powder and ensure the storage stability of the sealant. However, this process has a long process cycle and high temperature. After heating, the base material is obtained, and the high temperature needs to be lowered to room temperature through cooling water before the next step of preparation can be carried out, which is time-consuming and laborious, and consumes energy such as water, electricity, and heat
[0004] Related solutions of room temperature vulcanized silicone rubber have also appeared in the prior art. Its flexibility and elongation are better than ordinary vulcanized silicone rubber, but it generally has the problem of low tensile strength due to its small cohesive force; at the same time, its The storage stability is much lower than that of vulcanized silicone rubber treated at high temperature. Generally, after the product is stored at room temperature for several months, the performance of the product will decline significantly.

Method used

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  • One-component room temperature vulcanized silicone rubber and preparation method
  • One-component room temperature vulcanized silicone rubber and preparation method
  • One-component room temperature vulcanized silicone rubber and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The embodiment of the present invention provides a one-component room temperature vulcanized silicone rubber, which uses polyorganosiloxane with a functionality of 80,000 terminal hydroxyl groups. The one-component room temperature vulcanized silicone rubber includes the following components in parts by mass:

[0035]

[0036]

[0037] A preparation method of simple room temperature vulcanized silicone rubber, characterized in that it comprises the following steps:

[0038] In terms of parts by mass, add 100 parts of hydroxyl-terminated polyorganosiloxane, 25 parts of silicone oil 100cps, 70 parts of heavy filler, and 5 parts of fumed silica into a planetary stirring tank, stir and mix for about 40 minutes, and then add vinyl trimethoxy 0.1 part of base silane; 9 parts of cross-linking agent; 2 parts of silane coupling agent; 0.05 part of dibutyltin dilaurate Continue mixing, stirring for 30 minutes under the condition of vacuum greater than -0.095MPa, and discharg...

Embodiment 2

[0040] The one-component room temperature vulcanizing silicone rubber provided in this example is polyorganosiloxane with a functionality of 50,000 terminal hydroxyl groups. The one-component room temperature vulcanizing silicone rubber includes the following components in parts by mass:

[0041]

[0042] In above-mentioned embodiment, the preparation method of room temperature vulcanized silicone rubber comprises the following steps:

[0043] In terms of parts by mass, add 100 parts of hydroxyl-terminated polyorganosiloxane, 30 parts of silicone oil 100cps, 80 parts of heavy filler, and 10 parts of fumed silica into a planetary stirring tank and stir for about 40 minutes, then add vinyl trimethoxy 0.2 parts of base silane; 10 parts of crosslinking agent; 3 parts of silane coupling agent; 0.05 parts of dibutyltin dilaurate Continue mixing, stirring for 30 minutes under the condition of vacuum greater than -0.095MPa, and discharging.

Embodiment 3

[0045] The one-component room temperature vulcanizing silicone rubber provided in this example is a polyorganosiloxane with a functionality of 120,000 terminal hydroxyl groups. The one-component room temperature vulcanizing silicone rubber includes the following components in parts by mass:

[0046]

[0047]The preparation method of the room temperature vulcanized silicone rubber in the above-mentioned embodiment comprises the following steps: in parts by mass, 100 parts of hydroxyl-terminated polyorganosiloxane, 35 parts of silicone oil 100 cps, 100 parts of heavy filler, and 5 parts of fumed silica are added Stir and mix in the planetary stirring tank for about 40 minutes, then add 0.3 parts of vinyltrimethoxysilane; 12 parts of crosslinking agent phenyltributanoneximosilane; 4 parts of silane coupling agent; 0.1 part of dibutyltin dilaurate and continue mixing , Stir for 30 minutes under the condition that the vacuum degree is greater than -0.095MPa, and discharge.

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Abstract

The invention discloses one-component room temperature vulcanization silicone rubber with a simple process and a preparation method thereof, and relates to the field of room temperature vulcanized silicone rubber. The one-component room temperature vulcanized silicone rubber is prepared from, by mass, 100 parts of hydroxyl terminated polyorganosiloxane alkane, 25-35 parts of silicone oil, 70-100 parts of a heavy filler, 5-15 parts of fumed silica, 0.1-0.3 part of a water remover, 6-14 parts of a cross-linking agent, 1.7-4 parts of a silane coupling agent and 0.01-0.09 part of dibutyl tin dilaurate. The preparation method of the one-component room temperature vulcanized silicone rubber adopts a formula design and raw material selection, uses powder with a low water content rate to interactwith the low-active cross-linking agent, and achieves high-temperature dehydration, the whole production process time is greatly shortened, the process is very simple, large-scale production is easilyachieved, and the storage stability is equal to a high temperature dehydration process.

Description

technical field [0001] The invention relates to the field of silicone rubber, in particular to a one-component room temperature vulcanized silicone rubber and a preparation method thereof. Background technique [0002] Silicone rubber has excellent weather resistance, high and low temperature resistance, high hydrophobicity and good air permeability, etc., and can be used for a long time in the range of -60 ~ 260 ° C, safe and reliable, and has a long service life, so it is widely used in construction , electronics, machinery manufacturing, automobiles and other industrial fields. [0003] For a long time, the preparation process of one-component room temperature vulcanized silicone rubber has been relatively complicated, and it must be dehydrated under high-temperature vacuum for 3 hours to remove the moisture in the powder and ensure the storage stability of the sealant. However, this process has a long process cycle and high temperature. After heating, the base material ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08K3/36C08K9/04C08K3/26C08K5/5425C08K5/544C08K13/06
CPCC08K2003/265C08L83/04C08L2205/025C08K3/36C08K9/04C08K3/26C08K5/5425C08K5/544C08K13/06
Inventor 赵瑞王翠花赵勇刚刘鹏章锋
Owner HUBEI HUITIAN NEW MATERIALS STOCK CO LTD
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