4 results about "Silicon disulfide" patented technology

The application discloses a quasi-solid-state sodium battery electrolyte and a preparation method and application thereof, and belongs to the technical field of sodium metal batteries. The quasi-solid-state sodium battery electrolyte provided by the application comprises a photocuring agent, a sodium ion electrolyte and a two-dimensional material; the two-dimensional material comprises one or more of fluorinated graphene, titanium nitride, boron nitride, silicon disulfide, tungsten disulfide and silicon carbide. The quasi-solid-state sodium battery electrolyte provided by the application has good mechanical strength and mechanical stability, can reduce the resistance of the quasi-solid-state sodium battery electrolyte, and improve the ionic conductivity; when the quasi-solid-state sodium battery electrolyte is applied to a sodium metal battery, the sodium metal battery has higher specific capacity under small and large rates, and can maintain long-time cycle stability.

This invention discloses a method for preparing rare earth sulfides and colorants. The method uses rare earth oxides, molybdenum sulfide, and elemental silicon as raw materials. First, molybdenum sulfide and elemental silicon undergo a high-temperature reaction to generate silicon sulfide gas. Then, the silicon sulfide gas undergoes a reducing sulfidation reaction of the rare earth oxides to generate the corresponding rare earth sulfides. Finally, the reaction product is leached with alkali to remove soluble impurities, followed by filtration, rinsing, and drying to obtain high-purity rare earth sulfides. This process yields rare earth sulfide powder and ultrafine molybdenum silicide powder as a byproduct. Furthermore, the phase and color of the rare earth sulfides can be controlled by doping with alkali metals and alkaline earth metals. This invention is a novel method for synthesizing rare earth sulfide powder. Compared to other methods, it has the following advantages: universal applicability, low raw material cost, safe and controllable reaction process, high purity of reaction products with no solid waste generation, and ease of industrial-scale production.

The present invention provides a β-cesium cadmium silicon sulfide compound, a β-Cs2CdSi4S10 infrared nonlinear optical crystal, as well as their preparation methods and applications. The β-cesium cadmium silicon sulfide compound has a chemical formula β-Cs2CdSi4S10 and a molecular weight of 755.04. The β-Cs2CdSi4S10 infrared nonlinear optical crystal belongs to the tetragonal crystal system, its space group is I-4, and its unit cell parameters are: a=8.4233(7) Å, c=14.6136(12) Å, and the unit cell volume is 1036.86(19) Å3. The present invention adopts a vacuum packaging method to prepare a β-Cs2CdSi4S10 infrared nonlinear optical crystal. By using the kurtz-berry method, it was found that the frequency doubling effect of β-Cs2CdSi4S10 crystal is approximately 1.1-1.2 times that of AgGaS2(AGS). By using the UV-visible diffuse reflection, it was found that the β-Cs2CdSi4S10 crystal has the crystal bandgap of 4.21 eV, the UV cutoff edge of 254 nm, and the infrared transparency range greater than 13 μm. The preparation method of the β-Cs2CdSi4S10 infrared nonlinear optical crystal of the present invention is simple, with a short growth period, and avoids the leakage and contamination of raw materials. The β-Cs2CdSi4S10 infrared nonlinear optical crystal of the present invention can be used to fabricate conversion devices for high-power laser output applications and has important applications in atmospheric remote sensing and communication fields.