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Preparation method of Fe2B intermetallic compound wear-resistant coating

A technology of intermetallic compound and wear-resistant coating, which is applied in the field of surface coating and its preparation, can solve the problems of cumbersome process, high energy consumption, and easy formation of teardrop-shaped surface features, so as to avoid energy accumulation and coating composition Uniform, clear heat effect

Inactive Publication Date: 2019-04-16
HUNAN UNIV OF HUMANITIES SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, due to the limitations of the boronizing process itself, at present, boronizing has encountered many unavoidable problems in actual production: (1) The high temperature of boronizing damages the properties of the substrate, which is easy to cause grain growth and workpiece deformation; ( 2) High energy consumption, a lot of waste, difficult to handle, pollute the environment, and cumbersome process; (3) Not suitable for effective boronizing treatment of large-sized workpieces or parts of workpieces; (4) Generally coarse tissue, preferred orientation , no equiaxed crystals; (6) The workpiece needs to be reheated after boronizing
Because these technologies all have the characteristics of powder presetting, they all have the following problems: (1) It is difficult to prepare coatings on parts with highly complex structures and their local areas, and it is not easy to realize automatic production; (2) It is difficult to ensure coating Uniform composition; (3) easy to form teardrop-shaped surface features; (4) obvious thermal effect on the base material, large dilution rate
However, in the multi-layer cladding process, if the laser cladding process is not properly controlled, as the number of layers increases, along with energy accumulation, the physical and chemical reactions of each layer of cladding process are different, and the coating structure is difficult to control , leading to significant differences in material properties

Method used

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  • Preparation method of Fe2B intermetallic compound wear-resistant coating
  • Preparation method of Fe2B intermetallic compound wear-resistant coating

Examples

Experimental program
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Effect test

Embodiment 1

[0020] The mixed powder of Fe-B alloy: 45% by mass and Fe: 55% by mass is used as the raw material of the coating, and the powder particle size is 48-80 μm. Synchronous powder feeding laser cladding is used to prepare three-layer cladding coatings: (1) The surface of the substrate to be cladding is polished and smooth, and the oil and rust on the surface are removed, and stored in a dry state; (2) The fiber laser is used for cladding and melting. Argon gas is used for protection during the cladding process. The specific process parameters of the cladding: the laser power of the first layer is set to 120W, starting from the second layer, the laser power of each layer is set to 94% of the previous layer, and the scanning rate is 4mm / s, the laser spot diameter is 0.1mm, the offset is 0.16mm, the defocus is 5mm, and the shielding gas flow rate is 6L / min. The final coating structure is Fe 2 B and Fe, the coating has a good metallurgical bond with the substrate. After micro Vickers...

Embodiment 2

[0022] The mixed powder of Fe-B alloy: 60% by mass and Fe: 40% by mass is used as the raw material of the coating, and the powder particle size is 48-80 μm. The 4-layer cladding coating is prepared by synchronous powder feeding laser cladding: (1) The surface of the substrate to be cladding is polished and smooth, and the oil and rust on the surface are removed, and stored in dry; (2) The fiber laser is used for cladding and melting. Argon gas is used for protection during the cladding process. The specific process parameters of the cladding: the laser power of the first layer is set to 150W, starting from the second layer, the laser power of each layer is set to 92% of the previous layer, and the laser scanning rate 5mm / s, the laser spot diameter is 0.1mm, the offset is 0.16mm, the defocus is 5mm, and the shielding gas flow rate is 6L / min. The final coating structure is Fe 2 B and Fe, the coating has a good metallurgical bond with the substrate. After micro Vickers hardness t...

Embodiment 3

[0024] The mixed powder of Fe-B alloy: 75% by mass and Fe: 25% by mass is used as the raw material of the coating, and the powder particle size is 48-80 μm. Synchronous powder feeding laser cladding is used to prepare 5-layer cladding coatings: (1) The surface of the substrate to be cladding is polished and smooth, and the oil and rust on the surface are removed, and stored in a dry state; (2) The fiber laser is used for cladding and melting Argon gas is used for protection during the cladding process. The specific process parameters of the cladding: the laser power of the first layer is set to 180W, starting from the second layer, the laser power of each layer is set to 90% of the previous layer, and the laser scanning rate 6mm / s, laser spot diameter is 0.1mm, offset is 0.16mm, defocus is 5mm, and shielding gas flow rate is 6L / min. The final coating structure is Fe 2 B and Fe, the coating has a good metallurgical bond with the substrate. . After micro Vickers hardness test a...

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Abstract

The invention discloses a preparation method of a Fe2B intermetallic compound wear-resistant coating. The preparation method of the Fe2B intermetallic compound wear-resistant coating comprises the steps of preparing Fe-B alloy and Fe mixed powder or Fe2B and B mixed powder as a raw material, wherein the raw material is prepared from the elements including, by mass,9 percent to 15 percent of B, andthe balance Fe; and adopting synchronous powder feeding laser cladding for preparing the coating. During the cladding process, a gradual layer-by-layer laser power decreasing process is adopted for avoiding energy accumulation caused by layer-by-layer cladding, so that the laser cladding coating structure is controlled to be Fe2B and Fe. According to the coating provided by the invention, the substrate surface friction and wear properties are improved, and the coating and a substrate have favorable metallurgical bonding; and meanwhile, a cladding material only contains Fe and B which are twoelements wide in source and low in price so as to have the potential in technological and economic benefits.

Description

Technical field [0001] The invention relates to a surface coating and a preparation method thereof, more specifically, to a Fe 2 B. Intermetallic compound wear-resistant coating and its preparation method. Background technique [0002] The high wear resistance of Fe-B alloy coating is mainly due to the boride (Fe 2 B+FeB) exists. With Fe 2 Compared with B phase, FeB phase has higher hardness, 2 Phase B is more brittle. Therefore, Fe 2 B is a more ideal reinforcing phase in Fe-B alloys. Fe 2 B is a typical intermetallic compound, which has the advantages of high hardness, good thermal stability, strong wear and corrosion resistance and relatively small brittleness. It only contains Fe and B, which are widely sourced and cheap elements, but With high chromium carbide Cr 7 C 3 Equivalent hardness, showing high cost performance, is a low-cost, high-performance wear-resistant material with great development potential. [0003] Boronizing is the most widely used technique for preparin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/10
CPCC23C24/103
Inventor 陈志国王一澎汪力
Owner HUNAN UNIV OF HUMANITIES SCI & TECH
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