Waste rubber/plastic regenerated product set and preparation method thereof

A technology of waste rubber and waste plastics, which is applied in the direction of product, plastic recycling, and liquid hydrocarbon mixture preparation, etc., which can solve the problems of white ash not being used as resources, dispersion, and unimpeded connection, and meet supply and demand/market price effect of change

Inactive Publication Date: 2019-05-14
胡嘉庆 +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] But CN99114968.8 described "distillation range components below 120 DEG C are used as softening agent in rubber industry", through practical application, it is found that there is a serious odor defect: because when the rubber industry uses this softening agent to produce rubber products, when rubber products In the thermal vulcanization process, it will always be molded into the mold with a heating range of 140°C to 180°C, then this kind of softener, which is a distillation range component below 120°C, will overflow from the blended product, resulting in thermal vulcanization in rubber product companies. The workshop and the surrounding environment are filled with unpleasant odors
[0016] Although the above-mentioned new methods have opened up a new field of combined methods for waste rubber / plastic regeneration, these works are only analyzed from a technical level, and there are still many deficiencies: First, as a sub-path in the combined method—pyrolysis , the cleanliness and high-quality and high-value of the oil obtained are thermally regenerated and finely crushed at room temperature, which are also sub-paths in the combination method. The joints have not yet been opened; The pyrolysis slag that is not sold well in the market is usually incinerated as fuel to recover heat, but the large amount of white ash after burning is not used as a resource; third, waste rubber / plastic regeneration is a high energy-consuming recycling industry. However, the thermal cracking sub-process in the combined method is an energy-gaining approach, and at present this energy-gaining approach has not yet been unimpededly connected to the high energy-consuming sub-path in the combined method; There is no literature report on how polycyclic aromatic hydrocarbons contained in oil and pyrolysis slag products can adapt to the market demand of low content; fifth, the steric barrier effect of rubber powder, especially ultrafine rubber powder, at least in graphene, Carbon nanotubes have not been reported on the application of synergistic applications in the field of rubber products

Method used

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  • Waste rubber/plastic regenerated product set and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0133] A collection of waste rubber / plastic regenerated products and its production method, the collection is characterized by: a subset A of waste rubber or / and waste plastics obtained by thermal cracking, or / and a product obtained by non-thermal cracking Product subset B; said B, including blending A, or / and using the conversion energy of A, and then processing through a known combination method, the obtained recycled rubber / plastic product subset B; or / and in said B , also comprising a core / shell of recycled rubber or / and plastic;

[0134] The subset A, which at least comprises A1 or / and A6 or / and A7 or / and A8 or / and A9, or a combination with any or more of A2, A3, A4, A5, A10:

[0135] A1——waste rubber / plastic pyrolysis heavy oil that can be used as rubber / plastic softener or tackifier, A2——waste rubber / waste plastic pyrolysis heavy oil that can be used as rubber / plastic tackifier, A3——can be Depurified light oil as fuel, A4—combustible gas that can be used as fuel, A5—py...

Embodiment 2

[0176] The preparation method of "subset A" described in Example 1 is characterized in that: the raw materials of subset A are prepared by any one or a combination of the above materials as follows:

[0177] Discarded tires from motor vehicles or non-motor vehicles, plastic turf used in sports fields, plastic runways used in sports fields, plastic films discarded from recycled pulp production, rubber or / and plastic waste scraps discarded by shoe manufacturers, Waste trim or / and scorched materials or / and defective products discarded by rubber product enterprises;

[0178] Adopt commercially available / self-made thermal cracking equipment for the raw material to carry out heating and dry distillation, in order to obtain the A1 described in Example 1, its preparation method is characterized in that: carry out the following 2-1 or and 2-2 to 2-5 to the distillate gas Any or a combination of the above:

[0179] 2-1. For the pyrolysis dry distillation gas, use distillation or rectif...

Embodiment 3

[0215] The method for preparing sub-set B described in Example 1 is characterized in that: the raw materials of sub-set B are obtained by making any one or a combination of the above materials as follows:

[0216] Discarded tires from motor vehicles or non-motor vehicles, plastic turf used in sports fields, plastic runways used in sports fields, plastic films discarded from recycled pulp production, rubber or / and plastic waste scraps discarded by shoe manufacturers, Waste trim or / and scorched materials or / and defective products discarded by rubber product enterprises;

[0217] The raw materials are processed by a known combined process, but the softener or tackifier in the formulations involved in B1 to B10 is partially or entirely used in A1 described in Example 1; or / and, in B1 to B10 The filler composition in the formula involved part or all uses the combination of A6 or / and A7 or / and A8 described in Example 1; or / and, the energy source of electricity / heat / steam used in B1 ...

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Abstract

The invention provides a waste rubber/plastic regenerated product set and a preparation method thereof. The set comprises a product subset A or/and a product subset B, wherein the product subset A isacquired by thermal cracking of waste rubber or/and waste plastics, and the product subset B is acquired by non-thermal cracking. The B comprises conversion energy for blending or/and using the A, theregenerated rubber/plastic product subset B is acquired by a combination method, or/and the B further comprises core/shell-shaped regenerated rubber or/and plastics, the A at least comprises A1 or/and A6 or/and A7 or/and A8 or/and A9, the A1 is waste rubber/waste plastic thermal cracking heavy oil capable of serving as a rubber/plastic softening agent or/and thickening agent, the A6 is a crushedor recycled particle capable of serving as a rubber/plastic fine grinding promoting agent or/and a reinforcing/filling auxiliary material, cracking residues are grinded, sieved by a 200-mesh screen and subjected to PAH (polycyclic aromatic hydrocarbons) removal treatment to obtain the particle, the A7 is cracking residue burning ash capable of replacing or partially replacing slaked lime and serving as a burning tail gas absorbent, and the dampening pH (potential of hydrogen) of the cracking residue burning ash is larger than 8.

Description

technical field [0001] The present invention proposes a collection of waste rubber / plastic regenerated products and its manufacturing method, which involves the innovation of waste rubber / waste plastic through thermal cracking process and its product approach; it belongs to the combination method of waste rubber / waste plastic resource recycling or Coupled with the technical scope of the business model. technical background [0002] Traditional and classic waste rubber recycling products mainly come from three mainstream processes, namely: thermal reclaimed rubber, freezing or normal temperature fine rubber powder, and thermal cracking method to extract oil; traditional and classic waste plastic recycling products are also It is mainly obtained through three mainstream processes, namely: thermal extrusion granulation, normal temperature crushing granulation, and thermal cracking method for oil extraction. [0003] But the product that obtains by above-mentioned traditional c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10B53/07C10G1/10C08L91/00C08J11/10
CPCY02P20/143Y02W30/62
Inventor 胡嘉庆陈汇宏沙良宝陈汇宁
Owner 胡嘉庆
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