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Preparation method of oriented conductive hydrogel fiber material

A technology of conductive hydrogel and fiber materials, applied in the direction of conductive/antistatic filament manufacturing, fiber treatment, fiber chemical characteristics, etc., can solve the problems affecting the sensitivity and limitations of conductive materials, and achieve increased conductivity and tensile strength Elongation and the effect of expanding the application range

Active Publication Date: 2019-05-14
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the fact that traditional hydrogel materials cannot effectively guide the distribution of conductive particles on the macro scale, which affects the sensitivity of conductive materials, the application is also greatly limited.

Method used

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  • Preparation method of oriented conductive hydrogel fiber material
  • Preparation method of oriented conductive hydrogel fiber material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1: Sodium alginate-carbon nanotube composite oriented conductive hydrogel fiber

[0019] Add different masses of carbon nanotubes and 5% carbon nanotubes of Pluronic F-127 into deionized water for magnetic stirring, then put them in an ice bath for ultrasonic dispersion, the dispersion power is 300W, and the dispersion time is 30-120min. A 0.2mg / ml-5mg / ml carbon nanotube dispersion is obtained. Mix 1% sodium alginate and 0.2% PEO with the above dispersion, and perform magnetic stirring for 1 h to obtain an electrospinning precursor. Inhale the precursor solution into a 1ml electrospinning syringe and fix it on the propulsion pump, set the propulsion speed to 1-2ml / h, connect the positive pole of the high voltage power supply to the spinning nozzle, and the negative pole to the receiving tray, adjust the electrospinning The distance between the needle and the receiving plate is 5-8cm; 50ml 0.5mol / l CaCl 2 The solution is evenly placed in the rotating liquid rec...

Embodiment 2

[0020] Example 2: Sodium alginate-polythiophene (PEDOT) composite oriented conductive hydrogel fiber

[0021] Add different qualities of polythiophene (PEDOT) into deionized water for magnetic stirring and then ultrasonically disperse them. The dispersion power is 300W and the dispersion time is 30-120min to obtain 0.2mg / ml-5mg / ml PEDOT dispersion. 1% sodium alginate and 0.2% PEO were mixed with the above dispersion, and magnetically stirred for 1 h to obtain the electrospinning precursor. Inhale the precursor solution into a 1ml electrospinning syringe and fix it on the propulsion pump, set the propulsion speed to 1-2ml / h, connect the positive pole of the high voltage power supply to the spinning nozzle, and the negative pole to the receiving tray, adjust the electrospinning The distance between the needle and the receiving plate is 5-8cm; 50ml 0.5mol / l CaCl 2 The solution is evenly placed in the rotating liquid receiving tray, and the rotating speed of the receiving tray is...

Embodiment 3

[0022] Example 3: Chitosan-Graphene Composite Oriented Conductive Hydrogel Fiber

[0023] The graphene of different quality and the SDS (sodium dodecyl sulfate) of graphene quality 5% are joined in deionized water and carry out magnetic stirring, then it is placed in ice bath and carry out ultrasonic dispersion, dispersion power is 200W, dispersion time is 30-120min, get 0.2mg / ml-5mg / ml graphene dispersion. Mix 5% chitosan and 0.2% PEO with the above dispersion liquid, carry out magnetic stirring, and obtain electrospinning precursor liquid after dissolution. Inhale the precursor solution into a 1ml electrospinning syringe and fix it on the propulsion pump, set the propulsion speed to 1-2ml / h, connect the positive pole of the high voltage power supply to the spinning nozzle, and the negative pole to the receiving tray, adjust the electrospinning The distance between the needle and the receiving plate is 5-8 cm; 15% NaOH-30% absolute ethanol is evenly placed in the rotating li...

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Abstract

The invention discloses an oriented conductive hydrogel fiber material and a preparation method thereof. The preparation method comprises the steps: firstly, conductive particle dispersion solutions with different concentrations are obtained through an ultrasonic dispersion method, and dispersed conductive particles are turned into an evenly dispersed state from a mutually agglomerated or wound state so as to meet the subsequent requirements of enhancing the matrix strength and conductivity; then the conductive particles are composited into an organic polymer solution capable of being gelifiedto form a composite electrospinning precursor solution meeting the electrospinning concentration and viscosity; and electrospinning is conducted through a liquid rotary receiving disc, and a polymercomposite conductive particle hydrogel fiber with an oriented micro-nanofiber structure is prepared. Different from the traditional design of hydrogel single physical factor introduction, the orientedmicro-nanofiber structure, sensitive variable conductivity and mechanical strength are simultaneously introduced into a hydrogel system, the hydrogel fiber material with excellent performance is prepared, and a new preparation technique is provided for material preparation of the fields such as biomedical stent materials, flexible electrode materials and biosensors.

Description

technical field [0001] The invention belongs to the field of materials, and particularly provides a method for preparing oriented conductive hydrogel fiber materials. Background technique [0002] Hydrogel materials have the characteristics of excellent biocompatibility, degradability, bendability and flexibility, and are widely used in the fields of biomedical scaffold materials, flexible electrodes or biosensors. In terms of the design of biomedical scaffold materials, it is often inclined to design and prepare scaffold materials with structural characteristics similar to human tissue. Such a scaffold material can well match with human tissue in terms of mechanical properties and meet the requirements of implantation. At the same time, the design and preparation of scaffold materials also take into account the functional characteristics of corresponding tissues to the greatest extent, such as the electrical conductivity of nerve tissue and muscle tissue. Therefore, the d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F9/04D01F1/09D01F1/10D01D5/00
Inventor 姚生莲王鲁宁陈颖芝宋欣
Owner UNIV OF SCI & TECH BEIJING
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