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Method for removing refractory organic matters from concentrate of leachate membrane of incineration power plant

A technology for refractory organic matter and leachate, applied in the field of organic matter degradation, can solve the problems of poor removal rate of refractory organic matter, lack of systematic research on leachate membrane concentrate treatment, low biochemical properties, etc., and achieve great practicality Value, low technical operation difficulty, and low processing cost

Inactive Publication Date: 2019-06-07
任旭
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] However, previous studies focused on the treatment of leachate membrane concentrates in landfills, but there was a lack of systematic research on the treatment of different types of leachate membrane concentrates in incineration power plants
Due to the high content of organic matter in the leachate membrane concentrate, extremely low biochemical properties, a large amount of heavy metals and Cl - , SO 4 2- Plasma is enriched in the concentrated solution, and the concentrated solution contains a large amount of dissolved organic matter DOM with a high degree of humification and refractory substances. With the existing methods, the removal rate of refractory organic matter is not good and it is difficult to achieve High removal rate of degraded organic matter, high requirements for equipment and technology

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  • Method for removing refractory organic matters from concentrate of leachate membrane of incineration power plant
  • Method for removing refractory organic matters from concentrate of leachate membrane of incineration power plant
  • Method for removing refractory organic matters from concentrate of leachate membrane of incineration power plant

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Embodiment 1

[0029] A method for removing refractory organic matter in the leachate membrane concentrate of an incineration power plant, comprising the following steps:

[0030] A. After adjusting the pH value of the leachate membrane concentrate, put it into the reaction coagulation tank;

[0031] B. Control the stirring speed to 310r / min~500r / min, add polyaluminum iron silicate to the reaction coagulation tank, add coagulant after 20s~40s, and adjust the stirring speed to 60r / min~100r after stirring for 30s~40s / min, continue to stir for 25min~35min, then send it to the air flotation tank or sedimentation tank for mud-water separation;

[0032] C. Dehydrate the separated sludge and transfer it to the incinerator for incineration; the separated sewage flows into the regulating tank to adjust the pH value and then flows into the electrochemical oxidation + photocatalytic reactor for advanced oxidation. After the electrolysis is completed, remove Precipitation; specifically, various method...

Embodiment 2

[0036] According to the principles of the foregoing embodiments, this embodiment discloses a set of specific implementation manners.

[0037] Taking the 100mL nanofiltration membrane concentrate produced by a municipal solid waste incineration power plant as an example, the nanofiltration membrane concentrates COD Cr 5000±700mg / L, BOD5 25.33 mg / L, UV 254 It is 48.10, the color is 1800 degrees, and the pH is 6.88.

[0038] A, the concentrated solution of the nanofiltration membrane is sent into the adjustment tank, and the pH value is adjusted to 3 in the adjustment tank and then put into the reaction coagulation tank;

[0039] B. Control the stirring speed to 310r / min; after starting stirring, immediately add polyaluminum ferric silicate PSAF into the reaction coagulation tank according to the concentration of 35g / L; add 7mg coagulant polyacrylamide PAM after 30s; stir for 30s Finally, adjust the stirring speed to 60r / min; continue to stir for 30min; stand still for 30min af...

Embodiment 3

[0042] Based on the principle of Embodiment 1, this embodiment takes the 100mL reverse osmosis membrane concentrate produced by a municipal solid waste incineration power plant as an example. The reverse osmosis membrane concentrate COD Cr 2000±500mg / L, BOD 5 120.90mg / L, UV 254 It is 39.95, the color is 1200 degrees, and the pH is 8.53.

[0043] A, the nanofiltration membrane concentrate is sent into the adjustment tank, and the pH value is adjusted to 6 in the adjustment tank and then put into the reaction coagulation tank;

[0044] B. Control the stirring speed to 400r / min; add 5g polyaluminum iron silicate PSAF to the reaction coagulation tank immediately after starting stirring; add 6mg coagulant polyacrylamide PAM after 60s; adjust the stirring speed to 60r / min after stirring for 30s min; continue to stir for 30 min; after the stirring is completed, let it stand for 30 min, and the sludge volume is 27-35 mL; BOD / COD is significantly increased;

[0045] C. Separation of...

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Abstract

The invention discloses a method for removing refractory organic matters from concentrate of a leachate membrane of an incineration power plant. The method comprises the following steps: adjusting a pH value of the concentrate of the leachate membrane, and then, placing the concentrate into a reaction coagulation tank; controlling a stirring rate to 310r / min to 500r / min, adding polysilicate aluminum ferric, adding a coagulant aid 20s-40s later, carrying out stirring for 30s-40s, then, adjusting a stirring rate to 60r / min to 100r / min, continuing to carry out stirring for 25min to 35min, and then, carrying out sludge-water separation in an air flotation tank or sedimentation tank; subjecting the separated sludge to dewatering treatment, and then, incinerating the sludge in an incinerator; and enabling the separated sewage to flow into a regulation tank, adjusting a pH value, then, enabling the sewage to flow into an electrochemical oxidation and photocatalytic reactor for advanced oxidation, carrying out electrolysis, and then, removing precipitates. According to the method, by adopting a coagulation and advanced oxidation combined manner, the biodegradability of the concentrate canbe obviously improved, the rate of removal of the refractory organic matters from the concentrate is increased, the difficulty of technical operation is low, the equipment is simple and easy to maintain, the treatment cost is low, and thus, the method has a relatively high practical value.

Description

technical field [0001] The invention relates to the technical field of organic matter degradation, in particular to a method for removing refractory organic matter in leachate membrane concentrate of an incineration power plant. Background technique [0002] Compared with landfill treatment, incineration technology is gradually becoming the main way of urban domestic waste treatment because of its reduction, harmlessness, and resource recovery effects. The water content of garbage in our country is high, and the leachate output of incineration plants is large. At present, membrane treatment technology is the core technology for leachate treatment in incineration power plants. Membrane treatment technology will produce a by-product concentrate, which has a high concentration of pollutants and is difficult to treat. Potential environmental hazards are great. [0003] The waste incineration method has the advantages of small footprint, large processing capacity, short cycle, s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/08C02F101/30
Inventor 任旭宋凯肖玉吴子涵白雪刘丹
Owner 任旭