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A kind of microcellular foamed long carbon fiber reinforced pa11 material and preparation method thereof

A technology of long carbon fiber and microporous foaming, which is applied in the field of microporous foamed long carbon fiber reinforced PA11 material and its preparation, which can solve the problem of material weight reduction, lack of antistatic performance and low temperature resistance, and lack of biological sustainability and other issues, to achieve the effect of improving processing performance, good antistatic and heat insulation performance, and reducing material cost

Active Publication Date: 2022-03-25
余姚中国塑料城塑料研究院
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high-temperature micro-foamed glass fiber-reinforced nylon composite material provided by this patent can reduce the weight of the material under the premise that the tensile and bending properties are basically stable, which is beneficial to the lightweight of the car, and the impact strength is greatly improved. The glass fibers used are all on the market. The surface-treated glass fiber does not need further treatment, but the material does not have antistatic properties and low temperature resistance, nor is it biologically sustainable

Method used

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  • A kind of microcellular foamed long carbon fiber reinforced pa11 material and preparation method thereof

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Effect test

Embodiment 1

[0044]A kind of microcellular foaming long carbon fiber reinforced PA11 material, said material is made up of following components: viscosity is 75 parts of PA11 resins of 2.7, the maleic anhydride grafted EPDM of graft ratio 1.0% and graft ratio 1.0% 10 parts of composite toughening agent compounded by 0.7% maleic anhydride grafted POE at a ratio of 1:1, with a carbon content of 98%, a single filament diameter of 8 μm, a tensile strength of ≥3500 MPa, and a length of 10 to 15 mm 10 parts of long carbon fibers, 5 parts of composite wear-resistant lubricants formed by 1:1:1 combination of 200 mesh hollow silicon dioxide, 400 mesh calcium carbonate, and 800 mesh polytetrafluoroethylene, and the total processing weight is 5kg.

[0045] According to the total amount of processing, the mass of each component required is accurately weighed in proportion. First, PA11 resin is dried at 120°C for 4 hours, then PA11, toughener, and wear-resistant lubricant are put into a high-speed mixer...

Embodiment 2

[0047] A kind of microporous foam long carbon fiber reinforced PA11 material, said material is made up of following components: viscosity is 70 parts of PA11 resins of 2.45, the maleic anhydride grafted EPDM of graft rate 0.9% and graft rate 0.8% 10 parts of a composite toughening agent compounded by maleic anhydride grafted POE at a ratio of 1:1, long carbon fibers with a carbon content of 95%, a single filament diameter of 6 μm, a tensile strength ≥ 3500 MPa, and a length of 10 to 15 mm 15 parts, 5 parts of the composite wear-resistant lubricant that 200 purpose hollow silicon dioxide, 400 purpose calcium carbonate, 800 purpose polytetrafluoroethylene are combined by 1: 1: 1, processing total weight is 5kg.

[0048] According to the total amount of processing, the mass of each component required is accurately weighed in proportion. First, PA11 resin is dried at 120°C for 4 hours, then PA11, toughener, and wear-resistant lubricant are put into a high-speed mixer and mixed for ...

Embodiment 3

[0050] A kind of microporous foam long carbon fiber reinforced PA11 material, said material is made up of following components: viscosity is 80 parts of PA11 resins of 2.8, the maleic anhydride grafted EPDM of graft rate 1.2% and graft rate 1.0% 5 parts of composite toughening agent compounded by maleic anhydride grafted POE at a ratio of 1:1, long carbon fiber with a carbon content of 96%, a single filament diameter of 8 μm, a tensile strength ≥ 3500 MPa, and a length of 10 to 15 mm 12 parts, 3 parts of the composite wear-resistant lubricant that 200 purpose hollow silicon dioxide, 400 purpose calcium carbonate, 800 purpose polytetrafluoroethylene are combined by 1: 1: 1, processing total weight is 5kg.

[0051] According to the total amount of processing, the mass of each component required is accurately weighed in proportion. First, PA11 resin is dried at 120°C for 4 hours, then PA11, toughener, and wear-resistant lubricant are put into a high-speed mixer and mixed for 4 min...

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Abstract

The invention discloses a microporous foamed long carbon fiber reinforced PA11 material and a preparation method thereof. The PA11 material comprises the following raw materials in parts by weight: 70 to 80 parts of PA11 resin, 5 to 10 parts of toughening agent, and 5 to 10 parts of long carbon fiber. 15 parts, 1-5 parts of wear-resistant lubricant, 0.01-0.5 parts of foaming agent. The PA11 material of the present invention has the characteristics of low water absorption, low density, high and low temperature resistance, good dimensional stability, antistatic, good fluidity, etc., and is especially suitable for forming thin-walled shells of 0.3-1 mm, such as polymer shells for shotguns etc.; Simultaneously, since the synthetic monomer of the PA11 material of the present invention is derived from castor oil, the material has characteristics such as environmental protection and biological sustainability; in addition, since my country is the second largest producer of castor oil in the world, the raw material of the present invention The source is guaranteed, and the application of the present invention can greatly promote the development of castor planting and castor oil processing in China, and has significant industrial application value.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a microporous foamed long carbon fiber reinforced PA11 material and a preparation method thereof. Background technique [0002] Microcellular foamed materials generally refer to the number of cells in the material per cubic centimeter greater than 10 9 A porous foam material with a cell diameter of less than 10 μm. Microcellular foam materials can significantly reduce product weight while maintaining the necessary mechanical properties of the material. At the same time, the higher cell density and smaller cell shape also endow microcellular foamed materials with many excellent properties that traditional foamed materials cannot match, such as high impact strength, low density, heat insulation, etc. Due to the above-mentioned excellent properties of microporous microporous foaming materials, it has a wide range of applications, such as packaging materials, sound insula...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/02C08L51/04C08L51/06C08L27/18C08K7/06C08K3/26C08K7/26C08J9/12C08J5/04
CPCC08J9/122C08J9/0085C08J9/0066C08J9/0095C08J9/0061C08J5/042C08J2203/06C08J2203/08C08J2377/02C08J2451/04C08J2451/06C08J2427/18Y02P20/54
Inventor 王承刚佘进娟刘苏芹何杰吴炅张学锋任业伟
Owner 余姚中国塑料城塑料研究院