The invention discloses a ZIF-67@LDHs electrode material applied to a supercapacitor and a preparation method thereof. The electrode material has a core-shell structure, the core structure is a metal organic framework material, and the shell structure is layered double hydroxides LDHs. The method comprises the following steps: adding trivalent metal ions M<3+> and divalent metal ions M<2+> into deionized water, carrying out ultrasonic dissolution, adding urea and ammonium fluoride (NH4F), stirring to obtain a precursor solution, transferring the precursor solution into a high-pressure reaction kettle, reacting at 120-140 DEG C, cooling, carrying out ultrasonic treatment, filtering, washing with deionized water, adding into deionized water again, carrying out ultrasonic treatment, filtering, drying to obtain an LDHs material; adding an LDHs material into a methanol solution, carrying out ultrasonic treatment for 40-60 minutes to obtain a mixed solution I, adding 2-methylimidazole into the methanol solution, carrying out ultrasonic dissolution to obtain a solution II, adding the solution II into the mixed solution I, carrying out magnetic stirring for 5-8 hours, centrifuging, filtering, and respectively washing with methanol and deionized water to obtain the ZIF-67@LDHs material.